Facile fabrication of CuO/Ag2Se nanosized composite via hydrothermal approach for the electrochemical energy conversion system

  • Muhammad Abdullah
  • , Peter John*
  • , Sumaira Manzoor
  • , Muhammad Ishfaq Ghouri
  • , H. H. Hegazy
  • , Adeel Hussain Chugtai
  • , Salma Aman
  • , Ahmed M. Shawky
  • , Muhammad Naeem Ashiq
  • , T. A. Taha
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

110 Scopus citations

Abstract

The composite electrodes are sustainable way of generating high-performance supercapacitor materials, and are easily synthesized via cost effective methods. Here, we state the synthesis of CuO, Ag2Se, CuO/Ag2Se (COAS) nanocomposites via a hydrothermal method specifically for energy conversion devices. The structural, morphological and textural properties of fabricated material are evaluated with scanning electron microscopy (SEM), x-ray diffraction (XRD), Brunauer Teller Emmett analyses (BET). The electrochemical efficiency of the generated materials is further determined using galvanostatic charge discharge (GCD), electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), electrochemical active surface area (ECSA), electrochemical impedance spectroscopy (EIS), and chronoamperometry (CA) using Ni foam as conductive substrate under 2.0 M KOH electrolyte. Electrochemical results revealed about CuO/Ag2Se heterostructure displays specific capacitance (Cs) of 1543.42 F g−1 at 1 A g−1. COAS electrode has higher cycle stability, along with the capacitance of 97 % retained up to 2000 cycles at 1.5 A g−1. In addition, COAS pseudocapacitor exhibited an energy density (Ed) of 34.81 Wh Kg−1 and a power density (Pd) of 201.5 W Kg−1. This study not only highlighted huge potential related to electrode material CuO/Ag2Se, as well as revolutionary approach for manufacturing affordable, multi element composite materials with high performance that may be applicable in an inclusive variety of applications in future era.

Original languageEnglish
Article number105929
JournalJournal of Energy Storage
Volume56
DOIs
StatePublished - 1 Dec 2022
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2022

Keywords

  • CuO/AgSe
  • Energy storage devices
  • Hydrothermal approach
  • Pseudocapacitor

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Electrical and Electronic Engineering

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