Facile fabrication of bismuth vanadate grafted carbon nanotubes composite for enhanced oxygen evolution reaction

  • Razan A. Alshgari
  • , Syed Imran Abbas Shah
  • , Nosheen Blouch
  • , Sumaira Manzoor*
  • , Mehar Un Nisa
  • , Muhammad Faheem Ashiq
  • , Muhammad Yousaf Ur Rehman
  • , Saikh Mohammad
  • , Muhammad Fahad Ehsan
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

The increasing demand of maintainable energy boosts researchers to develop reliable electrocatalysts for enhanced water splitting mechanisms. All the synthesized materials, including CNTs, BiVO4, and BiVO4/CNTs, were characterized utilizing a variety of methodologies to assist the structural, configurational, morphological, and topographical investigations. This work aims to create unique BiVO4/CNTs nanocomposite, which may have higher electrocatalytic activity then previous materials (81 mV dec−1 tafel slope and overpotential of 237 mV at 10 mAcm−2). The composite exhibits notable qualities, including extended stability lasting up to 100 h, a substantial electrochemically active surface area (ECSA) of 586.5 cm2, minimal charge transfer resistance (Rct) of 1.3 Ω, a low onset potential, a reasonably reduced overpotential, and a relatively modest Tafel slope. The synergistic interaction between CNTs and BiVO4 is responsible for electrocatalyst's exceptional catalytic efficiency and unique stability for 100-hour retaining both morphological and structural features, showcasing structural integrity of BiVO4/CNTs nano-composite. The objective of this research is to split water into its component molecules using a nano-composite made, and may also useful for future applications.

Original languageEnglish
Article number118025
JournalJournal of Electroanalytical Chemistry
Volume954
DOIs
StatePublished - 1 Feb 2024
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2024 Elsevier B.V.

Keywords

  • Bismuth vanadate
  • Carbon Support
  • Carbon nanotubes
  • Multimetal oxide
  • Oxygen evolution reaction

ASJC Scopus subject areas

  • Analytical Chemistry
  • General Chemical Engineering
  • Electrochemistry

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