Fabrication of zirconium ditelluride/graphene oxide nanocomposite array for oxygen evolution and hydrogen evolution reactions

Asma A. Alothman, Abdul Ghafoor Abid, Lubna Rasheed, Karam Jabbour, Mohammad Numair Ansari, Muhammad Faheem Ashiq, Abdul Rasheed Rashid, Muhammad Fahad Ehsan, Sumaira Manzoor*, Muhammad Naeem Ashiq*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

Future commercial energy conversion and storage requisitions may involve using two-dimensional (2D) materials that retain their structure and are feasible for water electrolysis. In this study, we advance in tuning the electronic arrangement of 2D materials like ZrTe2/graphene oxide for electrocatalytic energy conversions such as oxygen evolution reaction (OER) as well as hydrogen evolution reaction (HER). The fabricated materials characterize via X-rays diffraction analysis (XRD), Scanning electron microscopy (SEM), and Brunauer Emmett Teller (BET) adsorption-desorption isotherm to confirm their structure, shape, size and porosity. Subsequently, the fabricated nanocomposite employs for the electrochemical characterization, and the resultant composite shows a meager overpotential of 208 mV with a minimal Tafel slope of 31 mV/dec at a current density of the 10 mA/cm2 for the oxygen evolution process and represents the overpotential of 242 mV@-10 mA/cm2 for hydrogen evolution process. The fabricated ZrTe2/GO nanocomposite also shows the high stability of 40 h compared to the individual materials. This strategy provides a novel approach to designing tellurium-based nanomaterials for various applications.

Original languageEnglish
Pages (from-to)525-533
Number of pages9
JournalInternational Journal of Hydrogen Energy
Volume56
DOIs
StatePublished - 22 Feb 2024
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2023 Hydrogen Energy Publications LLC

Keywords

  • Alkaline media
  • Bifunctional
  • HER
  • OER
  • ZrTe/Graphene oxide

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

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