Abstract
Electrocatalytic water splitting is an essential hydrogen production method for resolving present energy shortage and progress toward more efficient technologies. For this purpose, a versatile and cheap electrocatalysts are the main challenge along the way. In this report, we synthesized vanadium telluride and carbon nanotube (VTe–CNT)-based nanocomposite via facile hydrothermal route. The VTe–CNTs are characterized by X-ray diffraction analysis, scanning electron microscopy, energy-dispersive spectroscopy, Fourier transform infrared spectroscopy, and Brunauer–Emmett–Teller. These characterizations depict nanosphere structures, morphology, and high surface area that maintains high porosity, which are essential for inclusive water-splitting phenomena in 1.0 M solution of KOH. Additionally, the electrochemical performance of VTe–CNTs has shown best O2 evolution reactions activity with of onset potential of 1.42 V versus reversible hydrogen electrode and required 10 mA/cm2 of current density at 278 mV overpotential, which is excellent among other electrocatalysts, VTe (342 mV@10 mA/cm−2) and CNTs (365 mV@10mA/cm−2). Moreover, VTe–CNT exhibits remarkable stability for almost 20 h. It also requires a low onset potential of 0.05 V with a small Tafel slope of 47 mV/dec for H2 evolution reactions. Hence, this research might facilitate the easy transportation of electrons and open up the new era, serving as an excellent replacement for noble metal–derived materials.
| Original language | English |
|---|---|
| Pages (from-to) | 4027-4041 |
| Number of pages | 15 |
| Journal | Journal of the American Ceramic Society |
| Volume | 107 |
| Issue number | 6 |
| DOIs | |
| State | Published - Jun 2024 |
| Externally published | Yes |
Bibliographical note
Publisher Copyright:© 2024 The American Ceramic Society.
Keywords
- HER
- OER
- Tafel slope
- VTe–CNTs
- hydrothermal method
- nanocomposite
ASJC Scopus subject areas
- Ceramics and Composites
- Materials Chemistry