Fabrication of Ni–MOF-derived composite material for efficient electrocatalytic OER

Muhammad Yousaf ur Rehman; Dilshad Hussain; Sajid Abbas; Ashfaq Mahmood Qureshi; Adeel Hussain Chughtai; Muhammad Najam-Ul-Haq; Abdullah Saad Alsubaie; Sumaira Manzoor; Khaled H. Mahmoud; Muhammad Naeem Ashiq

doi:10.1080/16583655.2021.1996944

Fabrication of Ni–MOF-derived composite material for efficient electrocatalytic OER

Muhammad Yousaf ur Rehman
, Dilshad Hussain
, Sajid Abbas
, Ashfaq Mahmood Qureshi
, Adeel Hussain Chughtai^*
, Muhammad Najam-Ul-Haq
, Abdullah Saad Alsubaie
, Sumaira Manzoor
, Khaled H. Mahmoud
, Muhammad Naeem Ashiq^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The poverty-stricken population cannot withstand the shocks of global warming and can hardly pay the soaring expenditure of fossil fuels whose reservoirs are already approaching the threshold limit. These adventures guided the researchers towards water oxidation as a source of energy. In this study, a metal-organic framework (MOF)-based material was fabricated and catalyzed the lethargic oxygen evolution reaction (OER). The synthesized material is characterized with different analytical techniques to confirm structural, morphological and textural properties. Its huge surface area (87 m²/g) rendered it a promising material to carry the OER. It exhibited shallow onset potential that is, 1.40 V vs. RHE and displayed an exceptionally low overpotential of 1.42 V vs. RHE to reach the benchmark current density (10 mA/cm²) with remarkably small Tafel slope that is, 34 mV/dec. It surpassed the state of the art electrocatalyst for OER, that is, IrO₂ and RuO₂ in efficiency as well as in stability.

Original language	English
Pages (from-to)	637-648
Number of pages	12
Journal	Journal of Taibah University for Science
Volume	15
Issue number	1
DOIs	https://doi.org/10.1080/16583655.2021.1996944
State	Published - 2021
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2021 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 13 Climate Action

Keywords

Carbon dots
Ni–MOF-derived composite
catalytic sites
electrochemical characterizations
oxygen evolution reaction

ASJC Scopus subject areas

General Chemistry
General Mathematics
General Biochemistry, Genetics and Molecular Biology
General Environmental Science
General Agricultural and Biological Sciences
General Physics and Astronomy
General Earth and Planetary Sciences

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10.1080/16583655.2021.1996944

Cite this

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title = "Fabrication of Ni–MOF-derived composite material for efficient electrocatalytic OER",

abstract = "The poverty-stricken population cannot withstand the shocks of global warming and can hardly pay the soaring expenditure of fossil fuels whose reservoirs are already approaching the threshold limit. These adventures guided the researchers towards water oxidation as a source of energy. In this study, a metal-organic framework (MOF)-based material was fabricated and catalyzed the lethargic oxygen evolution reaction (OER). The synthesized material is characterized with different analytical techniques to confirm structural, morphological and textural properties. Its huge surface area (87 m2/g) rendered it a promising material to carry the OER. It exhibited shallow onset potential that is, 1.40 V vs. RHE and displayed an exceptionally low overpotential of 1.42 V vs. RHE to reach the benchmark current density (10 mA/cm2) with remarkably small Tafel slope that is, 34 mV/dec. It surpassed the state of the art electrocatalyst for OER, that is, IrO2 and RuO2 in efficiency as well as in stability.",

keywords = "Carbon dots, Ni–MOF-derived composite, catalytic sites, electrochemical characterizations, oxygen evolution reaction",

author = "\{Yousaf ur Rehman\}, Muhammad and Dilshad Hussain and Sajid Abbas and Qureshi, \{Ashfaq Mahmood\} and Chughtai, \{Adeel Hussain\} and Muhammad Najam-Ul-Haq and Alsubaie, \{Abdullah Saad\} and Sumaira Manzoor and Mahmoud, \{Khaled H.\} and Ashiq, \{Muhammad Naeem\}",

note = "Publisher Copyright: {\textcopyright} 2021 The Author(s). Published by Informa UK Limited, trading as Taylor \& Francis Group.",

year = "2021",

doi = "10.1080/16583655.2021.1996944",

language = "English",

volume = "15",

pages = "637--648",

journal = "Journal of Taibah University for Science",

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AU - Yousaf ur Rehman, Muhammad

AU - Hussain, Dilshad

AU - Abbas, Sajid

AU - Qureshi, Ashfaq Mahmood

AU - Chughtai, Adeel Hussain

AU - Najam-Ul-Haq, Muhammad

AU - Alsubaie, Abdullah Saad

AU - Manzoor, Sumaira

AU - Mahmoud, Khaled H.

AU - Ashiq, Muhammad Naeem

PY - 2021

Y1 - 2021

N2 - The poverty-stricken population cannot withstand the shocks of global warming and can hardly pay the soaring expenditure of fossil fuels whose reservoirs are already approaching the threshold limit. These adventures guided the researchers towards water oxidation as a source of energy. In this study, a metal-organic framework (MOF)-based material was fabricated and catalyzed the lethargic oxygen evolution reaction (OER). The synthesized material is characterized with different analytical techniques to confirm structural, morphological and textural properties. Its huge surface area (87 m2/g) rendered it a promising material to carry the OER. It exhibited shallow onset potential that is, 1.40 V vs. RHE and displayed an exceptionally low overpotential of 1.42 V vs. RHE to reach the benchmark current density (10 mA/cm2) with remarkably small Tafel slope that is, 34 mV/dec. It surpassed the state of the art electrocatalyst for OER, that is, IrO2 and RuO2 in efficiency as well as in stability.

AB - The poverty-stricken population cannot withstand the shocks of global warming and can hardly pay the soaring expenditure of fossil fuels whose reservoirs are already approaching the threshold limit. These adventures guided the researchers towards water oxidation as a source of energy. In this study, a metal-organic framework (MOF)-based material was fabricated and catalyzed the lethargic oxygen evolution reaction (OER). The synthesized material is characterized with different analytical techniques to confirm structural, morphological and textural properties. Its huge surface area (87 m2/g) rendered it a promising material to carry the OER. It exhibited shallow onset potential that is, 1.40 V vs. RHE and displayed an exceptionally low overpotential of 1.42 V vs. RHE to reach the benchmark current density (10 mA/cm2) with remarkably small Tafel slope that is, 34 mV/dec. It surpassed the state of the art electrocatalyst for OER, that is, IrO2 and RuO2 in efficiency as well as in stability.

KW - Carbon dots

KW - Ni–MOF-derived composite

KW - catalytic sites

KW - electrochemical characterizations

KW - oxygen evolution reaction

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M3 - Article

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SN - 1658-3655

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EP - 648

JO - Journal of Taibah University for Science

JF - Journal of Taibah University for Science

IS - 1

ER -

Fabrication of Ni–MOF-derived composite material for efficient electrocatalytic OER

Abstract

Bibliographical note

UN SDGs

Keywords

ASJC Scopus subject areas

Access to Document

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Cite this