Fabrication of deodorizing fabric by grafting of metal phthalocyanine derivative onto nonwoven polypropylene fabric

G. O. Yahaya; B. J. Brisdon; M. Maxwell; R. England

doi:10.1002/app.1915

Fabrication of deodorizing fabric by grafting of metal phthalocyanine derivative onto nonwoven polypropylene fabric

G. O. Yahaya, B. J. Brisdon, M. Maxwell, R. England

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Fabrication of deodorizing fabric was tried by grafting metal phthalocyanine derivative, a catalytic deodorant, onto polypropylene (PP) nonwoven fabric. Fe(III)-4,4′,4″,4‴-tetra carboxamide phthalocyanine (Fe-TCMP) was synthesized. The Fe-TCMP showed high-deodorizing performance when tested for the elimination of 2-mercaptoethanol, an index material for bad-smelling compounds. The Fe-TCMP was converted to Fe(III)-4,4′,4″,4‴-tetracarboxylic acid phthalocyanine (Fe-TCAP) by hydrolysis to have carboxyl groups. It was chemically grafted on the surface of PP nonwoven fabric, which was surface modified to have amine groups with diaminocyclohexane (DACH) plasma. Such fabricated deodorizing fabric showed high-deodorizing performance for 2-mercaptoethanol.

Original language	English
Pages (from-to)	839-846
Number of pages	8
Journal	Journal of Applied Polymer Science
Volume	82
Issue number	4
DOIs	https://doi.org/10.1002/app.1915
State	Published - 24 Oct 2001

Keywords

Deodorizing fabric
Grafting
Low-temperature plasma process
Metal phthalocyanine derivative

ASJC Scopus subject areas

General Chemistry
Surfaces, Coatings and Films
Polymers and Plastics
Materials Chemistry

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10.1002/app.1915

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@article{2d437143906b41f484d2538bb3da2324,

title = "Fabrication of deodorizing fabric by grafting of metal phthalocyanine derivative onto nonwoven polypropylene fabric",

abstract = "Fabrication of deodorizing fabric was tried by grafting metal phthalocyanine derivative, a catalytic deodorant, onto polypropylene (PP) nonwoven fabric. Fe(III)-4,4′,4″,4‴-tetra carboxamide phthalocyanine (Fe-TCMP) was synthesized. The Fe-TCMP showed high-deodorizing performance when tested for the elimination of 2-mercaptoethanol, an index material for bad-smelling compounds. The Fe-TCMP was converted to Fe(III)-4,4′,4″,4‴-tetracarboxylic acid phthalocyanine (Fe-TCAP) by hydrolysis to have carboxyl groups. It was chemically grafted on the surface of PP nonwoven fabric, which was surface modified to have amine groups with diaminocyclohexane (DACH) plasma. Such fabricated deodorizing fabric showed high-deodorizing performance for 2-mercaptoethanol.",

keywords = "Deodorizing fabric, Grafting, Low-temperature plasma process, Metal phthalocyanine derivative",

author = "Yahaya, \{G. O.\} and Brisdon, \{B. J.\} and M. Maxwell and R. England",

year = "2001",

month = oct,

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doi = "10.1002/app.1915",

language = "English",

volume = "82",

pages = "839--846",

journal = "Journal of Applied Polymer Science",

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T1 - Fabrication of deodorizing fabric by grafting of metal phthalocyanine derivative onto nonwoven polypropylene fabric

AU - Yahaya, G. O.

AU - Brisdon, B. J.

AU - Maxwell, M.

AU - England, R.

PY - 2001/10/24

Y1 - 2001/10/24

N2 - Fabrication of deodorizing fabric was tried by grafting metal phthalocyanine derivative, a catalytic deodorant, onto polypropylene (PP) nonwoven fabric. Fe(III)-4,4′,4″,4‴-tetra carboxamide phthalocyanine (Fe-TCMP) was synthesized. The Fe-TCMP showed high-deodorizing performance when tested for the elimination of 2-mercaptoethanol, an index material for bad-smelling compounds. The Fe-TCMP was converted to Fe(III)-4,4′,4″,4‴-tetracarboxylic acid phthalocyanine (Fe-TCAP) by hydrolysis to have carboxyl groups. It was chemically grafted on the surface of PP nonwoven fabric, which was surface modified to have amine groups with diaminocyclohexane (DACH) plasma. Such fabricated deodorizing fabric showed high-deodorizing performance for 2-mercaptoethanol.

AB - Fabrication of deodorizing fabric was tried by grafting metal phthalocyanine derivative, a catalytic deodorant, onto polypropylene (PP) nonwoven fabric. Fe(III)-4,4′,4″,4‴-tetra carboxamide phthalocyanine (Fe-TCMP) was synthesized. The Fe-TCMP showed high-deodorizing performance when tested for the elimination of 2-mercaptoethanol, an index material for bad-smelling compounds. The Fe-TCMP was converted to Fe(III)-4,4′,4″,4‴-tetracarboxylic acid phthalocyanine (Fe-TCAP) by hydrolysis to have carboxyl groups. It was chemically grafted on the surface of PP nonwoven fabric, which was surface modified to have amine groups with diaminocyclohexane (DACH) plasma. Such fabricated deodorizing fabric showed high-deodorizing performance for 2-mercaptoethanol.

KW - Deodorizing fabric

KW - Grafting

KW - Low-temperature plasma process

KW - Metal phthalocyanine derivative

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DO - 10.1002/app.1915

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SN - 0021-8995

VL - 82

SP - 839

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JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 4

ER -

Fabrication of deodorizing fabric by grafting of metal phthalocyanine derivative onto nonwoven polypropylene fabric

Abstract

Keywords

ASJC Scopus subject areas

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