Evaluation of 1-Butyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide-Alkanolamine Sulfolane-Based System as Solvent for Absorption of Carbon Dioxide

Mohd Azlan Kassim; Nor Asrina Sairi; Rozita Yusoff; Yatimah Alias; Mohamed Kheireddine Aroua

doi:10.1021/acs.iecr.5b04376

Evaluation of 1-Butyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide-Alkanolamine Sulfolane-Based System as Solvent for Absorption of Carbon Dioxide

Mohd Azlan Kassim
, Nor Asrina Sairi^*
, Rozita Yusoff
, Yatimah Alias
, Mohamed Kheireddine Aroua

^*Corresponding author for this work

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

A mixture of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BMIM][NTf₂]) and monoethanolamine (MEA) were added into a dipolar aprotic solvent, sulfolane to form a nonaqueous physical-chemical absorbent for CO₂ absorption. The CO₂ solubility achieved highest value of 2.861 mol/kg in mixture of 30 wt % MEA + 70 wt % sulfolane (0B30M) at 303.15 K and 2004 kPa. Comprehensive data on effect of temperature, pressure, and composition on the multicomponent were measured and correlated with maximum average absolute relative deviation of 4.89%. Formation of biphasic layer was observed and it was analyzed using nuclear magnetic resonance (NMR).

Original language	English
Pages (from-to)	7992-8001
Number of pages	10
Journal	Industrial and Engineering Chemistry Research
Volume	55
Issue number	29
DOIs	https://doi.org/10.1021/acs.iecr.5b04376
State	Published - 27 Jul 2016

Bibliographical note

Publisher Copyright:
© 2016 American Chemical Society.

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

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10.1021/acs.iecr.5b04376

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title = "Evaluation of 1-Butyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide-Alkanolamine Sulfolane-Based System as Solvent for Absorption of Carbon Dioxide",

abstract = "A mixture of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BMIM][NTf2]) and monoethanolamine (MEA) were added into a dipolar aprotic solvent, sulfolane to form a nonaqueous physical-chemical absorbent for CO2 absorption. The CO2 solubility achieved highest value of 2.861 mol/kg in mixture of 30 wt \% MEA + 70 wt \% sulfolane (0B30M) at 303.15 K and 2004 kPa. Comprehensive data on effect of temperature, pressure, and composition on the multicomponent were measured and correlated with maximum average absolute relative deviation of 4.89\%. Formation of biphasic layer was observed and it was analyzed using nuclear magnetic resonance (NMR).",

author = "Kassim, \{Mohd Azlan\} and Sairi, \{Nor Asrina\} and Rozita Yusoff and Yatimah Alias and Aroua, \{Mohamed Kheireddine\}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = jul,

day = "27",

doi = "10.1021/acs.iecr.5b04376",

language = "English",

volume = "55",

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journal = "Industrial and Engineering Chemistry Research",

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publisher = "American Chemical Society",

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Evaluation of 1-Butyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide-Alkanolamine Sulfolane-Based System as Solvent for Absorption of Carbon Dioxide. / Kassim, Mohd Azlan; Sairi, Nor Asrina; Yusoff, Rozita et al.
In: Industrial and Engineering Chemistry Research, Vol. 55, No. 29, 27.07.2016, p. 7992-8001.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Evaluation of 1-Butyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide-Alkanolamine Sulfolane-Based System as Solvent for Absorption of Carbon Dioxide

AU - Kassim, Mohd Azlan

AU - Sairi, Nor Asrina

AU - Yusoff, Rozita

AU - Alias, Yatimah

AU - Aroua, Mohamed Kheireddine

PY - 2016/7/27

Y1 - 2016/7/27

N2 - A mixture of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BMIM][NTf2]) and monoethanolamine (MEA) were added into a dipolar aprotic solvent, sulfolane to form a nonaqueous physical-chemical absorbent for CO2 absorption. The CO2 solubility achieved highest value of 2.861 mol/kg in mixture of 30 wt % MEA + 70 wt % sulfolane (0B30M) at 303.15 K and 2004 kPa. Comprehensive data on effect of temperature, pressure, and composition on the multicomponent were measured and correlated with maximum average absolute relative deviation of 4.89%. Formation of biphasic layer was observed and it was analyzed using nuclear magnetic resonance (NMR).

AB - A mixture of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BMIM][NTf2]) and monoethanolamine (MEA) were added into a dipolar aprotic solvent, sulfolane to form a nonaqueous physical-chemical absorbent for CO2 absorption. The CO2 solubility achieved highest value of 2.861 mol/kg in mixture of 30 wt % MEA + 70 wt % sulfolane (0B30M) at 303.15 K and 2004 kPa. Comprehensive data on effect of temperature, pressure, and composition on the multicomponent were measured and correlated with maximum average absolute relative deviation of 4.89%. Formation of biphasic layer was observed and it was analyzed using nuclear magnetic resonance (NMR).

UR - https://www.scopus.com/pages/publications/84979779218

U2 - 10.1021/acs.iecr.5b04376

DO - 10.1021/acs.iecr.5b04376

M3 - Article

AN - SCOPUS:84979779218

SN - 0888-5885

VL - 55

SP - 7992

EP - 8001

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 29

ER -

Evaluation of 1-Butyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide-Alkanolamine Sulfolane-Based System as Solvent for Absorption of Carbon Dioxide

Abstract

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ASJC Scopus subject areas

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