ESR Spin radical trapping in dehydrohalogenation of alkyl halides catalyzed by molybdenum hexacarbonyl

James S. Hwang; Christos P. Tsonis

doi:10.1016/0304-5102(88)80036-1

ESR Spin radical trapping in dehydrohalogenation of alkyl halides catalyzed by molybdenum hexacarbonyl

James S. Hwang^*
, Christos P. Tsonis

^*Corresponding author for this work

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The dehydrohalogenation of some aliphatic alkyl halides catalyzed by molybdenum hexacarbonyl produces organic free radicals in solution. These transient radical species were trapped by using spin-trapping techniques and formed stable organic compounds whose structures were elucidated. Based on the structures of these spin-radical adducts, a dehydrohalogenation mechanism was proposed for each reaction system.

Original language	English
Pages (from-to)	259-267
Number of pages	9
Journal	Journal of Molecular Catalysis
Volume	44
Issue number	2
DOIs	https://doi.org/10.1016/0304-5102(88)80036-1
State	Published - 29 Feb 1988

Bibliographical note

Funding Information:
The authors are grateful to King Fahd University of Petroleum and Minerals for support of this research work and to Mr. M. M. Saleem for technical assistance.

ASJC Scopus subject areas

General Engineering

Access to Document

10.1016/0304-5102(88)80036-1

Cite this

@article{9f22055dc00545a0b3fbfd267035215b,

title = "ESR Spin radical trapping in dehydrohalogenation of alkyl halides catalyzed by molybdenum hexacarbonyl",

abstract = "The dehydrohalogenation of some aliphatic alkyl halides catalyzed by molybdenum hexacarbonyl produces organic free radicals in solution. These transient radical species were trapped by using spin-trapping techniques and formed stable organic compounds whose structures were elucidated. Based on the structures of these spin-radical adducts, a dehydrohalogenation mechanism was proposed for each reaction system.",

author = "Hwang, \{James S.\} and Tsonis, \{Christos P.\}",

note = "Funding Information: The authors are grateful to King Fahd University of Petroleum and Minerals for support of this research work and to Mr. M. M. Saleem for technical assistance.",

year = "1988",

month = feb,

day = "29",

doi = "10.1016/0304-5102(88)80036-1",

language = "English",

volume = "44",

pages = "259--267",

journal = "Journal of Molecular Catalysis",

issn = "0304-5102",

publisher = "Elsevier BV",

number = "2",

}

TY - JOUR

T1 - ESR Spin radical trapping in dehydrohalogenation of alkyl halides catalyzed by molybdenum hexacarbonyl

AU - Hwang, James S.

AU - Tsonis, Christos P.

N1 - Funding Information: The authors are grateful to King Fahd University of Petroleum and Minerals for support of this research work and to Mr. M. M. Saleem for technical assistance.

PY - 1988/2/29

Y1 - 1988/2/29

N2 - The dehydrohalogenation of some aliphatic alkyl halides catalyzed by molybdenum hexacarbonyl produces organic free radicals in solution. These transient radical species were trapped by using spin-trapping techniques and formed stable organic compounds whose structures were elucidated. Based on the structures of these spin-radical adducts, a dehydrohalogenation mechanism was proposed for each reaction system.

AB - The dehydrohalogenation of some aliphatic alkyl halides catalyzed by molybdenum hexacarbonyl produces organic free radicals in solution. These transient radical species were trapped by using spin-trapping techniques and formed stable organic compounds whose structures were elucidated. Based on the structures of these spin-radical adducts, a dehydrohalogenation mechanism was proposed for each reaction system.

UR - https://www.scopus.com/pages/publications/0023963981

U2 - 10.1016/0304-5102(88)80036-1

DO - 10.1016/0304-5102(88)80036-1

M3 - Article

AN - SCOPUS:0023963981

SN - 0304-5102

VL - 44

SP - 259

EP - 267

JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

IS - 2

ER -

ESR Spin radical trapping in dehydrohalogenation of alkyl halides catalyzed by molybdenum hexacarbonyl

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this