Elucidation of the Reaction Network for the Oxidative Dehydrogenation of Butane to Butadiene

Gazali Tanimu; Sulaiman S. Al-Khattaf; Michael T. Klein

doi:10.1021/acs.energyfuels.8b04125

Elucidation of the Reaction Network for the Oxidative Dehydrogenation of Butane to Butadiene

Gazali Tanimu^*
, Sulaiman S. Al-Khattaf
, Michael T. Klein

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The reaction network for the oxidative dehydrogenation of n-butane to butadiene was examined. Delplots for experiments with n-butane, 1-butene, and 2-butene feeds were constructed. These analyses revealed that butadiene formed from both 1-butene and 2-butene. The experimental ratio of 2-butene and 1-butene was far from the equilibrium value, suggesting that the 2-butene to 1-butene equilibrium was not established, supporting the existence of the direct reaction of 2-butene to butadiene.

Original language	English
Pages (from-to)	1473-1478
Number of pages	6
Journal	Energy and Fuels
Volume	33
Issue number	2
DOIs	https://doi.org/10.1021/acs.energyfuels.8b04125
State	Published - 21 Feb 2019

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Publisher Copyright:
Copyright © 2019 American Chemical Society.

ASJC Scopus subject areas

General Chemical Engineering
Fuel Technology
Energy Engineering and Power Technology

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10.1021/acs.energyfuels.8b04125

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title = "Elucidation of the Reaction Network for the Oxidative Dehydrogenation of Butane to Butadiene",

abstract = "The reaction network for the oxidative dehydrogenation of n-butane to butadiene was examined. Delplots for experiments with n-butane, 1-butene, and 2-butene feeds were constructed. These analyses revealed that butadiene formed from both 1-butene and 2-butene. The experimental ratio of 2-butene and 1-butene was far from the equilibrium value, suggesting that the 2-butene to 1-butene equilibrium was not established, supporting the existence of the direct reaction of 2-butene to butadiene.",

author = "Gazali Tanimu and Al-Khattaf, \{Sulaiman S.\} and Klein, \{Michael T.\}",

note = "Publisher Copyright: Copyright {\textcopyright} 2019 American Chemical Society.",

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doi = "10.1021/acs.energyfuels.8b04125",

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AU - Tanimu, Gazali

AU - Al-Khattaf, Sulaiman S.

AU - Klein, Michael T.

PY - 2019/2/21

Y1 - 2019/2/21

N2 - The reaction network for the oxidative dehydrogenation of n-butane to butadiene was examined. Delplots for experiments with n-butane, 1-butene, and 2-butene feeds were constructed. These analyses revealed that butadiene formed from both 1-butene and 2-butene. The experimental ratio of 2-butene and 1-butene was far from the equilibrium value, suggesting that the 2-butene to 1-butene equilibrium was not established, supporting the existence of the direct reaction of 2-butene to butadiene.

AB - The reaction network for the oxidative dehydrogenation of n-butane to butadiene was examined. Delplots for experiments with n-butane, 1-butene, and 2-butene feeds were constructed. These analyses revealed that butadiene formed from both 1-butene and 2-butene. The experimental ratio of 2-butene and 1-butene was far from the equilibrium value, suggesting that the 2-butene to 1-butene equilibrium was not established, supporting the existence of the direct reaction of 2-butene to butadiene.

UR - https://www.scopus.com/pages/publications/85062179353

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DO - 10.1021/acs.energyfuels.8b04125

M3 - Article

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SN - 0887-0624

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JO - Energy and Fuels

JF - Energy and Fuels

IS - 2

ER -

Elucidation of the Reaction Network for the Oxidative Dehydrogenation of Butane to Butadiene

Abstract

Bibliographical note

ASJC Scopus subject areas

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