Electrically conductive membrane of polyaniline-titanium(IV)phosphate cation exchange nanocomposite: Applicable for detection of Pb(II) using its ion-selective electrode

Asif Ali Khan; Umair Baig

doi:10.1016/j.jiec.2012.05.008

Electrically conductive membrane of polyaniline-titanium(IV)phosphate cation exchange nanocomposite: Applicable for detection of Pb(II) using its ion-selective electrode

Asif Ali Khan^*
, Umair Baig

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

PVC supported membranes of polyaniline-titanium(IV)phosphate (PANI-TiP) cation exchange nanocomposite were prepared by solution casting method in different stoichiometric ratios of PVC and PANI-TiP. The structure and morphology of the prepared membrane were ascertained by FTIR, SEM and TGA-DTA. The membrane having a composition 1:1 (PVC:PANI-TiP) shows best results for electrical conductivity, water content, porosity, thickness and swelling. The Pb(II) selective electrode was developed by using this membrane for the determination of lead in solutions. The membrane electrode was mechanically stable, having wide dynamic range, with quick response time and could be operated for at least 5 months.

Original language	English
Pages (from-to)	1937-1944
Number of pages	8
Journal	Journal of Industrial and Engineering Chemistry
Volume	18
Issue number	6
DOIs	https://doi.org/10.1016/j.jiec.2012.05.008
State	Published - 25 Nov 2012
Externally published	Yes

Bibliographical note

Funding Information:
The authors gratefully acknowledge to the Department of Applied Chemistry, Z.H. College of Engineering and Technology, A.M.U., (Aligarh) for providing research facilities. They are also thankful to Ministry of Environment & Forest , Government of India, for the financial support.

Keywords

Cation exchanger
Nanocomposite membranes
Pb(II) selective membrane electrode

ASJC Scopus subject areas

General Chemical Engineering

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10.1016/j.jiec.2012.05.008

Cite this

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title = "Electrically conductive membrane of polyaniline-titanium(IV)phosphate cation exchange nanocomposite: Applicable for detection of Pb(II) using its ion-selective electrode",

abstract = "PVC supported membranes of polyaniline-titanium(IV)phosphate (PANI-TiP) cation exchange nanocomposite were prepared by solution casting method in different stoichiometric ratios of PVC and PANI-TiP. The structure and morphology of the prepared membrane were ascertained by FTIR, SEM and TGA-DTA. The membrane having a composition 1:1 (PVC:PANI-TiP) shows best results for electrical conductivity, water content, porosity, thickness and swelling. The Pb(II) selective electrode was developed by using this membrane for the determination of lead in solutions. The membrane electrode was mechanically stable, having wide dynamic range, with quick response time and could be operated for at least 5 months.",

keywords = "Cation exchanger, Nanocomposite membranes, Pb(II) selective membrane electrode",

author = "Khan, \{Asif Ali\} and Umair Baig",

note = "Funding Information: The authors gratefully acknowledge to the Department of Applied Chemistry, Z.H. College of Engineering and Technology, A.M.U., (Aligarh) for providing research facilities. They are also thankful to Ministry of Environment \& Forest , Government of India, for the financial support. ",

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doi = "10.1016/j.jiec.2012.05.008",

language = "English",

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pages = "1937--1944",

journal = "Journal of Industrial and Engineering Chemistry",

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publisher = "Korean Society of Industrial Engineering Chemistry",

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T2 - Applicable for detection of Pb(II) using its ion-selective electrode

AU - Khan, Asif Ali

AU - Baig, Umair

N1 - Funding Information: The authors gratefully acknowledge to the Department of Applied Chemistry, Z.H. College of Engineering and Technology, A.M.U., (Aligarh) for providing research facilities. They are also thankful to Ministry of Environment & Forest , Government of India, for the financial support.

PY - 2012/11/25

Y1 - 2012/11/25

N2 - PVC supported membranes of polyaniline-titanium(IV)phosphate (PANI-TiP) cation exchange nanocomposite were prepared by solution casting method in different stoichiometric ratios of PVC and PANI-TiP. The structure and morphology of the prepared membrane were ascertained by FTIR, SEM and TGA-DTA. The membrane having a composition 1:1 (PVC:PANI-TiP) shows best results for electrical conductivity, water content, porosity, thickness and swelling. The Pb(II) selective electrode was developed by using this membrane for the determination of lead in solutions. The membrane electrode was mechanically stable, having wide dynamic range, with quick response time and could be operated for at least 5 months.

AB - PVC supported membranes of polyaniline-titanium(IV)phosphate (PANI-TiP) cation exchange nanocomposite were prepared by solution casting method in different stoichiometric ratios of PVC and PANI-TiP. The structure and morphology of the prepared membrane were ascertained by FTIR, SEM and TGA-DTA. The membrane having a composition 1:1 (PVC:PANI-TiP) shows best results for electrical conductivity, water content, porosity, thickness and swelling. The Pb(II) selective electrode was developed by using this membrane for the determination of lead in solutions. The membrane electrode was mechanically stable, having wide dynamic range, with quick response time and could be operated for at least 5 months.

KW - Cation exchanger

KW - Nanocomposite membranes

KW - Pb(II) selective membrane electrode

UR - https://www.scopus.com/pages/publications/84867646890

U2 - 10.1016/j.jiec.2012.05.008

DO - 10.1016/j.jiec.2012.05.008

M3 - Article

AN - SCOPUS:84867646890

SN - 1226-086X

VL - 18

SP - 1937

EP - 1944

JO - Journal of Industrial and Engineering Chemistry

JF - Journal of Industrial and Engineering Chemistry

IS - 6

ER -

Electrically conductive membrane of polyaniline-titanium(IV)phosphate cation exchange nanocomposite: Applicable for detection of Pb(II) using its ion-selective electrode

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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