Effect of transition metals (Mo, Mn and Co) on mesoporous ZSM-5 catalyst activity in carbon dioxide reforming of methane

H. U. Hambali; A. A. Jalil; A. A. Abdulrasheed; T. J. Siang; N. A.A. Fatah; A. F.A. Rahman; M. A.H. Aziz; I. Hussain

doi:10.1088/1757-899X/808/1/012005

Effect of transition metals (Mo, Mn and Co) on mesoporous ZSM-5 catalyst activity in carbon dioxide reforming of methane

H. U. Hambali^*
, A. A. Jalil
, A. A. Abdulrasheed
, T. J. Siang
, N. A.A. Fatah
, A. F.A. Rahman
, M. A.H. Aziz
, I. Hussain

^*Corresponding author for this work

Research output: Contribution to journal › Conference article › peer-review

4 Scopus citations

Abstract

This paper investigates the effect of transition metals (Mo, Mn and Co) on mesoporous ZSM-5 support in carbon dioxide reforming of methane reaction. The mesoporous ZSM-5 support was synthesized by micro emulsion technique and the metals were loaded by wet impregnation method. It was observed that ZSM-5 supported Co catalyst had higher surface area in comparison to other catalysts, which could favour well dispersion and wider utilization of active component. In addition, the ZSM-5 supported Co catalyst exhibited the highest methane and carbon dioxide conversions of 69 % and 65 % respectively at 850°C. The Co species were more active to decompose methane and carbon dioxide compared to Mo and Mn loaded catalysts. Hence, loading Co on mesoporous ZSM-5 produce an active catalyst in carbon dioxide reforming methane reaction.

Original language	English
Article number	012005
Journal	IOP Conference Series: Materials Science and Engineering
Volume	808
Issue number	1
DOIs	https://doi.org/10.1088/1757-899X/808/1/012005
State	Published - 31 Mar 2020
Externally published	Yes
Event	8th Conference on Emerging Energy and Process Technology 2019, CONCEPT 2019 - Kuala Lumpur, Malaysia Duration: 27 Nov 2019 → 28 Nov 2019

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Publisher Copyright:
© Published under licence by IOP Publishing Ltd.

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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ASJC Scopus subject areas

General Materials Science
General Engineering

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10.1088/1757-899X/808/1/012005

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Hambali, H. U., Jalil, A. A., Abdulrasheed, A. A., Siang, T. J., Fatah, N. A. A., Rahman, A. F. A., Aziz, M. A. H., & Hussain, I. (2020). Effect of transition metals (Mo, Mn and Co) on mesoporous ZSM-5 catalyst activity in carbon dioxide reforming of methane. IOP Conference Series: Materials Science and Engineering, 808(1), Article 012005. https://doi.org/10.1088/1757-899X/808/1/012005

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title = "Effect of transition metals (Mo, Mn and Co) on mesoporous ZSM-5 catalyst activity in carbon dioxide reforming of methane",

abstract = "This paper investigates the effect of transition metals (Mo, Mn and Co) on mesoporous ZSM-5 support in carbon dioxide reforming of methane reaction. The mesoporous ZSM-5 support was synthesized by micro emulsion technique and the metals were loaded by wet impregnation method. It was observed that ZSM-5 supported Co catalyst had higher surface area in comparison to other catalysts, which could favour well dispersion and wider utilization of active component. In addition, the ZSM-5 supported Co catalyst exhibited the highest methane and carbon dioxide conversions of 69 \% and 65 \% respectively at 850°C. The Co species were more active to decompose methane and carbon dioxide compared to Mo and Mn loaded catalysts. Hence, loading Co on mesoporous ZSM-5 produce an active catalyst in carbon dioxide reforming methane reaction.",

author = "Hambali, \{H. U.\} and Jalil, \{A. A.\} and Abdulrasheed, \{A. A.\} and Siang, \{T. J.\} and Fatah, \{N. A.A.\} and Rahman, \{A. F.A.\} and Aziz, \{M. A.H.\} and I. Hussain",

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year = "2020",

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doi = "10.1088/1757-899X/808/1/012005",

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T1 - Effect of transition metals (Mo, Mn and Co) on mesoporous ZSM-5 catalyst activity in carbon dioxide reforming of methane

AU - Hambali, H. U.

AU - Jalil, A. A.

AU - Abdulrasheed, A. A.

AU - Siang, T. J.

AU - Fatah, N. A.A.

AU - Rahman, A. F.A.

AU - Aziz, M. A.H.

AU - Hussain, I.

PY - 2020/3/31

Y1 - 2020/3/31

N2 - This paper investigates the effect of transition metals (Mo, Mn and Co) on mesoporous ZSM-5 support in carbon dioxide reforming of methane reaction. The mesoporous ZSM-5 support was synthesized by micro emulsion technique and the metals were loaded by wet impregnation method. It was observed that ZSM-5 supported Co catalyst had higher surface area in comparison to other catalysts, which could favour well dispersion and wider utilization of active component. In addition, the ZSM-5 supported Co catalyst exhibited the highest methane and carbon dioxide conversions of 69 % and 65 % respectively at 850°C. The Co species were more active to decompose methane and carbon dioxide compared to Mo and Mn loaded catalysts. Hence, loading Co on mesoporous ZSM-5 produce an active catalyst in carbon dioxide reforming methane reaction.

AB - This paper investigates the effect of transition metals (Mo, Mn and Co) on mesoporous ZSM-5 support in carbon dioxide reforming of methane reaction. The mesoporous ZSM-5 support was synthesized by micro emulsion technique and the metals were loaded by wet impregnation method. It was observed that ZSM-5 supported Co catalyst had higher surface area in comparison to other catalysts, which could favour well dispersion and wider utilization of active component. In addition, the ZSM-5 supported Co catalyst exhibited the highest methane and carbon dioxide conversions of 69 % and 65 % respectively at 850°C. The Co species were more active to decompose methane and carbon dioxide compared to Mo and Mn loaded catalysts. Hence, loading Co on mesoporous ZSM-5 produce an active catalyst in carbon dioxide reforming methane reaction.

UR - https://www.scopus.com/pages/publications/85083043104

U2 - 10.1088/1757-899X/808/1/012005

DO - 10.1088/1757-899X/808/1/012005

M3 - Conference article

AN - SCOPUS:85083043104

SN - 1757-8981

VL - 808

JO - IOP Conference Series: Materials Science and Engineering

JF - IOP Conference Series: Materials Science and Engineering

IS - 1

M1 - 012005

T2 - 8th Conference on Emerging Energy and Process Technology 2019, CONCEPT 2019

Y2 - 27 November 2019 through 28 November 2019

ER -

Effect of transition metals (Mo, Mn and Co) on mesoporous ZSM-5 catalyst activity in carbon dioxide reforming of methane

Abstract

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