Eco-Friendly Fabrication of a Highly Selective Amide-Based Polymer for CO2 Capture

Kehinde A. Fayemiwo; Nutchapon Chiarasumran; Seyed A. Nabavi; Konstantin N. Loponov; Vasilije Manović; Brahim Benyahia; Goran T. Vladisavljević

doi:10.1021/acs.iecr.9b02347

Eco-Friendly Fabrication of a Highly Selective Amide-Based Polymer for CO₂ Capture

Kehinde A. Fayemiwo
, Nutchapon Chiarasumran
, Seyed A. Nabavi
, Konstantin N. Loponov
, Vasilije Manović
, Brahim Benyahia^*
, Goran T. Vladisavljević

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Porous polymeric adsorbents for CO₂ capture (HCP-MAAMs) were fabricated by copolymerization of methacrylamide (MAAM) and ethylene glycol dimethacrylate using acetonitrile and azobisisobutyronitrile as a porogen and initiator, respectively. The X-ray photoelectron and Fourier transform infrared spectra revealed a high density of amide groups in the polymer matrix of HCP-MAAMs, which enabled high selectivity to CO₂. The polymer BET surface area and total pore volume was up to 277 m² g^-1 and 0.91 cm³ g^-1, respectively. The highest CO₂ uptake at 273 K and 1 bar CO₂ pressure was 1.45 mmol g^-1, and the heat of adsorption was 27-35 kJ mol^-1. The polymer with the lowest cross-linking density exhibited an unprecedented CO₂/N₂ selectivity of 394 at 273 K. Life cycle assessment revealed a lower environmental impact of HCP-MAAMs compared to molecularly imprinted polymers. HCP-MAAMs are eco-friendly CO₂ adsorbents owing to their low regeneration energy, environmentally benign fabrication process, and high selectivity.

Original language	English
Pages (from-to)	18160-18167
Number of pages	8
Journal	Industrial and Engineering Chemistry Research
Volume	58
Issue number	39
DOIs	https://doi.org/10.1021/acs.iecr.9b02347
State	Published - 2 Oct 2019
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2019 American Chemical Society.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 9 Industry, Innovation, and Infrastructure
SDG 12 Responsible Consumption and Production
SDG 13 Climate Action

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

Access to Document

10.1021/acs.iecr.9b02347

Cite this

@article{628b05fc65d4409fb132e59e1da9ed74,

title = "Eco-Friendly Fabrication of a Highly Selective Amide-Based Polymer for CO2 Capture",

abstract = "Porous polymeric adsorbents for CO2 capture (HCP-MAAMs) were fabricated by copolymerization of methacrylamide (MAAM) and ethylene glycol dimethacrylate using acetonitrile and azobisisobutyronitrile as a porogen and initiator, respectively. The X-ray photoelectron and Fourier transform infrared spectra revealed a high density of amide groups in the polymer matrix of HCP-MAAMs, which enabled high selectivity to CO2. The polymer BET surface area and total pore volume was up to 277 m2 g-1 and 0.91 cm3 g-1, respectively. The highest CO2 uptake at 273 K and 1 bar CO2 pressure was 1.45 mmol g-1, and the heat of adsorption was 27-35 kJ mol-1. The polymer with the lowest cross-linking density exhibited an unprecedented CO2/N2 selectivity of 394 at 273 K. Life cycle assessment revealed a lower environmental impact of HCP-MAAMs compared to molecularly imprinted polymers. HCP-MAAMs are eco-friendly CO2 adsorbents owing to their low regeneration energy, environmentally benign fabrication process, and high selectivity.",

author = "Fayemiwo, \{Kehinde A.\} and Nutchapon Chiarasumran and Nabavi, \{Seyed A.\} and Loponov, \{Konstantin N.\} and Vasilije Manovi{\'c} and Brahim Benyahia and Vladisavljevi{\'c}, \{Goran T.\}",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = oct,

day = "2",

doi = "10.1021/acs.iecr.9b02347",

language = "English",

volume = "58",

pages = "18160--18167",

journal = "Industrial and Engineering Chemistry Research",

issn = "0888-5885",

publisher = "American Chemical Society",

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}

TY - JOUR

T1 - Eco-Friendly Fabrication of a Highly Selective Amide-Based Polymer for CO2 Capture

AU - Fayemiwo, Kehinde A.

AU - Chiarasumran, Nutchapon

AU - Nabavi, Seyed A.

AU - Loponov, Konstantin N.

AU - Manović, Vasilije

AU - Benyahia, Brahim

AU - Vladisavljević, Goran T.

PY - 2019/10/2

Y1 - 2019/10/2

N2 - Porous polymeric adsorbents for CO2 capture (HCP-MAAMs) were fabricated by copolymerization of methacrylamide (MAAM) and ethylene glycol dimethacrylate using acetonitrile and azobisisobutyronitrile as a porogen and initiator, respectively. The X-ray photoelectron and Fourier transform infrared spectra revealed a high density of amide groups in the polymer matrix of HCP-MAAMs, which enabled high selectivity to CO2. The polymer BET surface area and total pore volume was up to 277 m2 g-1 and 0.91 cm3 g-1, respectively. The highest CO2 uptake at 273 K and 1 bar CO2 pressure was 1.45 mmol g-1, and the heat of adsorption was 27-35 kJ mol-1. The polymer with the lowest cross-linking density exhibited an unprecedented CO2/N2 selectivity of 394 at 273 K. Life cycle assessment revealed a lower environmental impact of HCP-MAAMs compared to molecularly imprinted polymers. HCP-MAAMs are eco-friendly CO2 adsorbents owing to their low regeneration energy, environmentally benign fabrication process, and high selectivity.

AB - Porous polymeric adsorbents for CO2 capture (HCP-MAAMs) were fabricated by copolymerization of methacrylamide (MAAM) and ethylene glycol dimethacrylate using acetonitrile and azobisisobutyronitrile as a porogen and initiator, respectively. The X-ray photoelectron and Fourier transform infrared spectra revealed a high density of amide groups in the polymer matrix of HCP-MAAMs, which enabled high selectivity to CO2. The polymer BET surface area and total pore volume was up to 277 m2 g-1 and 0.91 cm3 g-1, respectively. The highest CO2 uptake at 273 K and 1 bar CO2 pressure was 1.45 mmol g-1, and the heat of adsorption was 27-35 kJ mol-1. The polymer with the lowest cross-linking density exhibited an unprecedented CO2/N2 selectivity of 394 at 273 K. Life cycle assessment revealed a lower environmental impact of HCP-MAAMs compared to molecularly imprinted polymers. HCP-MAAMs are eco-friendly CO2 adsorbents owing to their low regeneration energy, environmentally benign fabrication process, and high selectivity.

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DO - 10.1021/acs.iecr.9b02347

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JO - Industrial and Engineering Chemistry Research

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