Dichlorobis(1,3-imidazolidine-2-thione-S)-cadmium(II)

A. R. Al-Arfaj; J. H. Reibenspies; A. A. Isab; M. Sakhawat Hussain

doi:10.1107/S0108270197012092

Dichlorobis(1,3-imidazolidine-2-thione-S)-cadmium(II)

A. R. Al-Arfaj^*, J. H. Reibenspies, A. A. Isab, M. Sakhawat Hussain

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The redetermination of the crystal structure of a cadmium(II) complex of 1,3-imidazolidine-2-thione (Imt) coordinated with two molecules of Imt and two Cl^- ions, [CdCl₂(C₃H₆N₂S)₂], has been performed in order to obtain accurate parameters and to study the effects of the metal coordination on the metal-S and C - S bonds in Imt complexes. The Cd^I - S distances of 2.525 (2) and 2.535 (2) Å in the present tetrahedral complex are significantly longer than the corresponding distances in the Au^I and Cu^II complexes of Imt, but there is no significant difference in the C - S distances of 1.721 (6) and 1.710 (6) Å from that in Au^I and Cu^II complexes. This work represents a significant increase in the quality of the structure of the title compound over the earlier work.

Original language	English
Pages (from-to)	51-53
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	1
DOIs	https://doi.org/10.1107/S0108270197012092
State	Published - 1998

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology

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title = "Dichlorobis(1,3-imidazolidine-2-thione-S)-cadmium(II)",

abstract = "The redetermination of the crystal structure of a cadmium(II) complex of 1,3-imidazolidine-2-thione (Imt) coordinated with two molecules of Imt and two Cl- ions, [CdCl2(C3H6N2S)2], has been performed in order to obtain accurate parameters and to study the effects of the metal coordination on the metal-S and C - S bonds in Imt complexes. The CdI - S distances of 2.525 (2) and 2.535 (2) {\AA} in the present tetrahedral complex are significantly longer than the corresponding distances in the AuI and CuII complexes of Imt, but there is no significant difference in the C - S distances of 1.721 (6) and 1.710 (6) {\AA} from that in AuI and CuII complexes. This work represents a significant increase in the quality of the structure of the title compound over the earlier work.",

author = "Al-Arfaj, \{A. R.\} and Reibenspies, \{J. H.\} and Isab, \{A. A.\} and Hussain, \{M. Sakhawat\}",

year = "1998",

doi = "10.1107/S0108270197012092",

language = "English",

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pages = "51--53",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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TY - JOUR

T1 - Dichlorobis(1,3-imidazolidine-2-thione-S)-cadmium(II)

AU - Al-Arfaj, A. R.

AU - Reibenspies, J. H.

AU - Isab, A. A.

AU - Hussain, M. Sakhawat

PY - 1998

Y1 - 1998

N2 - The redetermination of the crystal structure of a cadmium(II) complex of 1,3-imidazolidine-2-thione (Imt) coordinated with two molecules of Imt and two Cl- ions, [CdCl2(C3H6N2S)2], has been performed in order to obtain accurate parameters and to study the effects of the metal coordination on the metal-S and C - S bonds in Imt complexes. The CdI - S distances of 2.525 (2) and 2.535 (2) Å in the present tetrahedral complex are significantly longer than the corresponding distances in the AuI and CuII complexes of Imt, but there is no significant difference in the C - S distances of 1.721 (6) and 1.710 (6) Å from that in AuI and CuII complexes. This work represents a significant increase in the quality of the structure of the title compound over the earlier work.

AB - The redetermination of the crystal structure of a cadmium(II) complex of 1,3-imidazolidine-2-thione (Imt) coordinated with two molecules of Imt and two Cl- ions, [CdCl2(C3H6N2S)2], has been performed in order to obtain accurate parameters and to study the effects of the metal coordination on the metal-S and C - S bonds in Imt complexes. The CdI - S distances of 2.525 (2) and 2.535 (2) Å in the present tetrahedral complex are significantly longer than the corresponding distances in the AuI and CuII complexes of Imt, but there is no significant difference in the C - S distances of 1.721 (6) and 1.710 (6) Å from that in AuI and CuII complexes. This work represents a significant increase in the quality of the structure of the title compound over the earlier work.

UR - https://www.scopus.com/pages/publications/0031672679

U2 - 10.1107/S0108270197012092

DO - 10.1107/S0108270197012092

M3 - Article

AN - SCOPUS:0031672679

SN - 0108-2701

VL - 54

SP - 51

EP - 53

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 1

ER -

Dichlorobis(1,3-imidazolidine-2-thione-S)-cadmium(II)

Abstract

ASJC Scopus subject areas

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