Development of high-performance oxygen evolution reaction electrocatalyst with quick kinetics: Based on ultrafine Cu nanoparticles encircled by N-doped carbon

Muhammad Suleman Waheed, Salma Aman, Gouadria Soumaya*, Norah Salem Alsaiari, Sumaira Manzoor, T. I. Zubar*, Daria I. Tishkevich, Sergei V. Trukhanov, M. S. Al-Buriahi, Alex V. Trukhanov

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

36 Scopus citations

Abstract

The oxygen evolution reactions (OER) in electrochemical water splitting are the chief catalytic processes to clean and sustainable energy technologies, such as water electrolysis or energy conversion system. This study presents a Mott-Schottky catalyst encircled copper nanoparticles, including the nitrogen doped carbon layers (Cu@NC). All the fabricated materials are analyzed via numerous complementary procedures and then employed under a potentiostat configured with a three-electrode system. The fabricated Cu@NC displays a lower overpotential of 101.0 mV to accomplish current density of 10.0 mA cm−2, lower Tafel slope of 42.0 mV dec−1, and extensive stability over 5000 cycles having exceptional oxygen evolution activity. The structural results reveal that adding Cu and N species in Cu@NC significantly enhances the numerous of active sites and improves electronic conductivity. Structural defects help to accelerate the oxygen evolution process and many other fields for future applications.

Original languageEnglish
Article number111173
JournalJournal of Physics and Chemistry of Solids
Volume175
DOIs
StatePublished - Apr 2023
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2022 Elsevier Ltd

Keywords

  • Copper/N-doped carbon
  • Cu@NC
  • Electrocatalyst
  • Mott Schottky catalyst
  • OER

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics

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