Development of a Sensitive Method for Cadmium Determination in Fish Tissue and Drinking Water Samples by FAAS Using SQT In Situ Atom Trapping

Hüseyin Karababa; Muhammet Atasoy; Dilek Yildiz; İbrahim Kula; Mustafa Tuzen

doi:10.1021/acsomega.2c07926

Development of a Sensitive Method for Cadmium Determination in Fish Tissue and Drinking Water Samples by FAAS Using SQT In Situ Atom Trapping

Hüseyin Karababa
, Muhammet Atasoy^*
, Dilek Yildiz
, İbrahim Kula
, Mustafa Tuzen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A sensitive and robust trap method was developed for the determination of cadmium (Cd) by using a slotted quartz tube. Using this method at a sample suction rate of 7.4 mL/min for 4.0 min collection, a 1467-fold increase in sensitivity was obtained compared to the flame atomic absorption spectrometry method. Under the optimized conditions, a limit of detection of 0.075 ng mL^-1 was obtained for the trap method. The interference effects of hydride-forming elements, transition metals, and some anions on the Cd signal were investigated. The developed method was evaluated by analyzing “Sewage Sludge-industrial origin (BCR no: 146R)”, “NIST SRM 1640a Trace elements in natural water”, and “DOLT: 5 Dogfish Liver”. There was a good agreement between the certified and found values at the 95% confidence level. This method was applied successfully for the determination of Cd in drinking water and some fish tissue samples (liver, muscle, and gill) obtained from Muğla province.

Original language	English
Pages (from-to)	7063-7069
Number of pages	7
Journal	ACS Omega
Volume	8
Issue number	7
DOIs	https://doi.org/10.1021/acsomega.2c07926
State	Published - 21 Feb 2023
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2023 The Authors. Published by American Chemical Society.

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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10.1021/acsomega.2c07926

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title = "Development of a Sensitive Method for Cadmium Determination in Fish Tissue and Drinking Water Samples by FAAS Using SQT In Situ Atom Trapping",

abstract = "A sensitive and robust trap method was developed for the determination of cadmium (Cd) by using a slotted quartz tube. Using this method at a sample suction rate of 7.4 mL/min for 4.0 min collection, a 1467-fold increase in sensitivity was obtained compared to the flame atomic absorption spectrometry method. Under the optimized conditions, a limit of detection of 0.075 ng mL-1 was obtained for the trap method. The interference effects of hydride-forming elements, transition metals, and some anions on the Cd signal were investigated. The developed method was evaluated by analyzing “Sewage Sludge-industrial origin (BCR no: 146R)”, “NIST SRM 1640a Trace elements in natural water”, and “DOLT: 5 Dogfish Liver”. There was a good agreement between the certified and found values at the 95\% confidence level. This method was applied successfully for the determination of Cd in drinking water and some fish tissue samples (liver, muscle, and gill) obtained from Muğla province.",

author = "H{\"u}seyin Karababa and Muhammet Atasoy and Dilek Yildiz and İbrahim Kula and Mustafa Tuzen",

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T1 - Development of a Sensitive Method for Cadmium Determination in Fish Tissue and Drinking Water Samples by FAAS Using SQT In Situ Atom Trapping

AU - Karababa, Hüseyin

AU - Atasoy, Muhammet

AU - Yildiz, Dilek

AU - Kula, İbrahim

AU - Tuzen, Mustafa

PY - 2023/2/21

Y1 - 2023/2/21

N2 - A sensitive and robust trap method was developed for the determination of cadmium (Cd) by using a slotted quartz tube. Using this method at a sample suction rate of 7.4 mL/min for 4.0 min collection, a 1467-fold increase in sensitivity was obtained compared to the flame atomic absorption spectrometry method. Under the optimized conditions, a limit of detection of 0.075 ng mL-1 was obtained for the trap method. The interference effects of hydride-forming elements, transition metals, and some anions on the Cd signal were investigated. The developed method was evaluated by analyzing “Sewage Sludge-industrial origin (BCR no: 146R)”, “NIST SRM 1640a Trace elements in natural water”, and “DOLT: 5 Dogfish Liver”. There was a good agreement between the certified and found values at the 95% confidence level. This method was applied successfully for the determination of Cd in drinking water and some fish tissue samples (liver, muscle, and gill) obtained from Muğla province.

AB - A sensitive and robust trap method was developed for the determination of cadmium (Cd) by using a slotted quartz tube. Using this method at a sample suction rate of 7.4 mL/min for 4.0 min collection, a 1467-fold increase in sensitivity was obtained compared to the flame atomic absorption spectrometry method. Under the optimized conditions, a limit of detection of 0.075 ng mL-1 was obtained for the trap method. The interference effects of hydride-forming elements, transition metals, and some anions on the Cd signal were investigated. The developed method was evaluated by analyzing “Sewage Sludge-industrial origin (BCR no: 146R)”, “NIST SRM 1640a Trace elements in natural water”, and “DOLT: 5 Dogfish Liver”. There was a good agreement between the certified and found values at the 95% confidence level. This method was applied successfully for the determination of Cd in drinking water and some fish tissue samples (liver, muscle, and gill) obtained from Muğla province.

UR - https://www.scopus.com/pages/publications/85148431703

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JO - ACS Omega

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IS - 7

ER -

Development of a Sensitive Method for Cadmium Determination in Fish Tissue and Drinking Water Samples by FAAS Using SQT In Situ Atom Trapping

Abstract

Bibliographical note

ASJC Scopus subject areas

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