Determination of zirconium in water, dental materials and artificial saliva after surfactant assisted dispersive ionic liquid based microextraction

Esra Baʇda; Mustafa Tüzen

doi:10.1039/c5ra21267g

Determination of zirconium in water, dental materials and artificial saliva after surfactant assisted dispersive ionic liquid based microextraction

Esra Baʇda^*, Mustafa Tüzen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

In this study, an extractive spectrophotometric method is proposed for the determination of trace amounts of zirconium. The method is based on the complex formation between zirconium and 2-(5-bromo-2-pyridylazo)-5-(diethylamino) phenol. Then, the formed complex is concentrated in an ionic liquid (1-hexyl-3-methylimidazolium hexafluorophosphate) phase. The parameters were optimized and analytical figures of merit were obtained. The tolerance limits for diverse ions were calculated. The enhancement factor (EF) and limit of detection (LOD) were found to be 156 and 0.012 μg L^-1, respectively. The relative standard deviation (RSD) was found to be lower than 6%. The proposed method has been successfully applied to water and environmental materials.

Original language	English
Pages (from-to)	107872-107879
Number of pages	8
Journal	RSC Advances
Volume	5
Issue number	130
DOIs	https://doi.org/10.1039/c5ra21267g
State	Published - 10 Dec 2015
Externally published	Yes

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry 2015.

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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title = "Determination of zirconium in water, dental materials and artificial saliva after surfactant assisted dispersive ionic liquid based microextraction",

abstract = "In this study, an extractive spectrophotometric method is proposed for the determination of trace amounts of zirconium. The method is based on the complex formation between zirconium and 2-(5-bromo-2-pyridylazo)-5-(diethylamino) phenol. Then, the formed complex is concentrated in an ionic liquid (1-hexyl-3-methylimidazolium hexafluorophosphate) phase. The parameters were optimized and analytical figures of merit were obtained. The tolerance limits for diverse ions were calculated. The enhancement factor (EF) and limit of detection (LOD) were found to be 156 and 0.012 μg L-1, respectively. The relative standard deviation (RSD) was found to be lower than 6\%. The proposed method has been successfully applied to water and environmental materials.",

author = "Esra Baʇda and Mustafa T{\"u}zen",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

month = dec,

day = "10",

doi = "10.1039/c5ra21267g",

language = "English",

volume = "5",

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TY - JOUR

T1 - Determination of zirconium in water, dental materials and artificial saliva after surfactant assisted dispersive ionic liquid based microextraction

AU - Baʇda, Esra

AU - Tüzen, Mustafa

PY - 2015/12/10

Y1 - 2015/12/10

N2 - In this study, an extractive spectrophotometric method is proposed for the determination of trace amounts of zirconium. The method is based on the complex formation between zirconium and 2-(5-bromo-2-pyridylazo)-5-(diethylamino) phenol. Then, the formed complex is concentrated in an ionic liquid (1-hexyl-3-methylimidazolium hexafluorophosphate) phase. The parameters were optimized and analytical figures of merit were obtained. The tolerance limits for diverse ions were calculated. The enhancement factor (EF) and limit of detection (LOD) were found to be 156 and 0.012 μg L-1, respectively. The relative standard deviation (RSD) was found to be lower than 6%. The proposed method has been successfully applied to water and environmental materials.

AB - In this study, an extractive spectrophotometric method is proposed for the determination of trace amounts of zirconium. The method is based on the complex formation between zirconium and 2-(5-bromo-2-pyridylazo)-5-(diethylamino) phenol. Then, the formed complex is concentrated in an ionic liquid (1-hexyl-3-methylimidazolium hexafluorophosphate) phase. The parameters were optimized and analytical figures of merit were obtained. The tolerance limits for diverse ions were calculated. The enhancement factor (EF) and limit of detection (LOD) were found to be 156 and 0.012 μg L-1, respectively. The relative standard deviation (RSD) was found to be lower than 6%. The proposed method has been successfully applied to water and environmental materials.

UR - https://www.scopus.com/pages/publications/84952333982

U2 - 10.1039/c5ra21267g

DO - 10.1039/c5ra21267g

M3 - Article

AN - SCOPUS:84952333982

SN - 2046-2069

VL - 5

SP - 107872

EP - 107879

JO - RSC Advances

JF - RSC Advances

IS - 130

ER -

Determination of zirconium in water, dental materials and artificial saliva after surfactant assisted dispersive ionic liquid based microextraction

Abstract

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