Design and synthesis of a novel class of inhibitors for mild steel corrosion in acidic and carbon dioxide-saturated saline media

Mohammad A.J. Mazumder; Hasan A. Al-Muallem; Mohamed Faiz; Shaikh A. Ali

doi:10.1016/j.corsci.2014.06.026

Design and synthesis of a novel class of inhibitors for mild steel corrosion in acidic and carbon dioxide-saturated saline media

Mohammad A.J. Mazumder
, Hasan A. Al-Muallem
, Mohamed Faiz
, Shaikh A. Ali^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

118 Scopus citations

Abstract

p-(9-(2-Methylisoxazolidin-5-yl)nonyloxy)benzaldehyde I, prepared using a cycloaddition protocol, was elaborated into its cinnamaldehyde derivative II which upon quarternization with propargyl chloride afforded III bearing an interesting blend of structural traits suitable for imparting inhibition of mild steel corrosion. Novel compounds I-III showed efficient inhibition against mild steel corrosion in CO₂-0.5M NaCl (40°C, 1atm; 120°C, 10bar), 1, 4, 7.7M HCl, and 0.5M H₂SO₄ at 60°C as determined by gravimetry and electrochemical methods. The presence of carbonaceous surface and nitrogen, as revealed by XPS study, indicated the formation of a film covering the metal surface, which imparted corrosion inhibition.

Original language	English
Pages (from-to)	187-198
Number of pages	12
Journal	Corrosion Science
Volume	87
DOIs	https://doi.org/10.1016/j.corsci.2014.06.026
State	Published - Oct 2014

Bibliographical note

Funding Information:
Facilities provided by King Fahd University of Petroleum and Minerals and financial assistance by King Abdulaziz City of Science and Technology (KACST) (under the Grant: AR-26-26 ) and Deanship of Scientific Research, KFUPM (Startup Grant: IN121036 ) are gratefully acknowledged.

Keywords

A. Mild steel
B. Polarization
B. Weight loss
C. Acid corrosion
C. Interfaces
C. Thermodynamic diagrams

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
General Materials Science

Access to Document

10.1016/j.corsci.2014.06.026

Cite this

@article{5a8eaffea2824a9b91fb023dea94f26a,

title = "Design and synthesis of a novel class of inhibitors for mild steel corrosion in acidic and carbon dioxide-saturated saline media",

abstract = "p-(9-(2-Methylisoxazolidin-5-yl)nonyloxy)benzaldehyde I, prepared using a cycloaddition protocol, was elaborated into its cinnamaldehyde derivative II which upon quarternization with propargyl chloride afforded III bearing an interesting blend of structural traits suitable for imparting inhibition of mild steel corrosion. Novel compounds I-III showed efficient inhibition against mild steel corrosion in CO2-0.5M NaCl (40°C, 1atm; 120°C, 10bar), 1, 4, 7.7M HCl, and 0.5M H2SO4 at 60°C as determined by gravimetry and electrochemical methods. The presence of carbonaceous surface and nitrogen, as revealed by XPS study, indicated the formation of a film covering the metal surface, which imparted corrosion inhibition.",

keywords = "A. Mild steel, B. Polarization, B. Weight loss, C. Acid corrosion, C. Interfaces, C. Thermodynamic diagrams",

author = "Mazumder, \{Mohammad A.J.\} and Al-Muallem, \{Hasan A.\} and Mohamed Faiz and Ali, \{Shaikh A.\}",

note = "Funding Information: Facilities provided by King Fahd University of Petroleum and Minerals and financial assistance by King Abdulaziz City of Science and Technology (KACST) (under the Grant: AR-26-26 ) and Deanship of Scientific Research, KFUPM (Startup Grant: IN121036 ) are gratefully acknowledged. ",

year = "2014",

month = oct,

doi = "10.1016/j.corsci.2014.06.026",

language = "English",

volume = "87",

pages = "187--198",

journal = "Corrosion Science",

issn = "0010-938X",

publisher = "Elsevier Ltd.",

}

TY - JOUR

T1 - Design and synthesis of a novel class of inhibitors for mild steel corrosion in acidic and carbon dioxide-saturated saline media

AU - Mazumder, Mohammad A.J.

AU - Al-Muallem, Hasan A.

AU - Faiz, Mohamed

AU - Ali, Shaikh A.

N1 - Funding Information: Facilities provided by King Fahd University of Petroleum and Minerals and financial assistance by King Abdulaziz City of Science and Technology (KACST) (under the Grant: AR-26-26 ) and Deanship of Scientific Research, KFUPM (Startup Grant: IN121036 ) are gratefully acknowledged.

PY - 2014/10

Y1 - 2014/10

N2 - p-(9-(2-Methylisoxazolidin-5-yl)nonyloxy)benzaldehyde I, prepared using a cycloaddition protocol, was elaborated into its cinnamaldehyde derivative II which upon quarternization with propargyl chloride afforded III bearing an interesting blend of structural traits suitable for imparting inhibition of mild steel corrosion. Novel compounds I-III showed efficient inhibition against mild steel corrosion in CO2-0.5M NaCl (40°C, 1atm; 120°C, 10bar), 1, 4, 7.7M HCl, and 0.5M H2SO4 at 60°C as determined by gravimetry and electrochemical methods. The presence of carbonaceous surface and nitrogen, as revealed by XPS study, indicated the formation of a film covering the metal surface, which imparted corrosion inhibition.

AB - p-(9-(2-Methylisoxazolidin-5-yl)nonyloxy)benzaldehyde I, prepared using a cycloaddition protocol, was elaborated into its cinnamaldehyde derivative II which upon quarternization with propargyl chloride afforded III bearing an interesting blend of structural traits suitable for imparting inhibition of mild steel corrosion. Novel compounds I-III showed efficient inhibition against mild steel corrosion in CO2-0.5M NaCl (40°C, 1atm; 120°C, 10bar), 1, 4, 7.7M HCl, and 0.5M H2SO4 at 60°C as determined by gravimetry and electrochemical methods. The presence of carbonaceous surface and nitrogen, as revealed by XPS study, indicated the formation of a film covering the metal surface, which imparted corrosion inhibition.

KW - A. Mild steel

KW - B. Polarization

KW - B. Weight loss

KW - C. Acid corrosion

KW - C. Interfaces

KW - C. Thermodynamic diagrams

UR - https://www.scopus.com/pages/publications/84905366064

U2 - 10.1016/j.corsci.2014.06.026

DO - 10.1016/j.corsci.2014.06.026

M3 - Article

AN - SCOPUS:84905366064

SN - 0010-938X

VL - 87

SP - 187

EP - 198

JO - Corrosion Science

JF - Corrosion Science

ER -

Design and synthesis of a novel class of inhibitors for mild steel corrosion in acidic and carbon dioxide-saturated saline media

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this