Density and viscosity of aqueous mixtures of N-methyldiethanolamines (MDEA), piperazine (PZ) and ionic liquids

C. K. Foo; C. Y. Leo; R. Aramesh; M. K. Aroua; N. Aghamohammadi; M. S. Shafeeyan; A. Shamiri

doi:10.1016/j.molliq.2015.05.041

Density and viscosity of aqueous mixtures of N-methyldiethanolamines (MDEA), piperazine (PZ) and ionic liquids

C. K. Foo
, C. Y. Leo
, R. Aramesh
, M. K. Aroua
, N. Aghamohammadi
, M. S. Shafeeyan
, A. Shamiri^*

^*Corresponding author for this work

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

The density and viscosity measurements of aqueous mixtures of N-methyldiethanolamine (MDEA), piperazine (PZ) and the ionic liquids (ILs) 1-n-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF₄]), 1-butyl-3-methylimidazolium dicyanamide ([bmim][DCA]), and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([emim][OTf]) were conducted in this work. It was found that an increase in IL concentration resulted in an increase in the densities and viscosities of the aqueous mixtures. The density and viscosity equations for MDEA, PZ and IL aqueous mixtures as a function of temperature and concentration of ILs were derived as well. The density and viscosity equations obtained adequate accuracies with less than 0.34% and 4.013% of deviation from experimental data respectively.

Original language	English
Pages (from-to)	596-602
Number of pages	7
Journal	Journal of Molecular Liquids
Volume	209
DOIs	https://doi.org/10.1016/j.molliq.2015.05.041
State	Published - 20 Jun 2015

Bibliographical note

Publisher Copyright:
© 2015 Elsevier B.V. All rights reserved.

Keywords

Density
Ionic liquids
N-methyldiethanolamines (MDEA)
Piperazine (PZ)
Viscosity

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry

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10.1016/j.molliq.2015.05.041

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@article{f940479384cc4f04902764761a8defd9,

title = "Density and viscosity of aqueous mixtures of N-methyldiethanolamines (MDEA), piperazine (PZ) and ionic liquids",

abstract = "The density and viscosity measurements of aqueous mixtures of N-methyldiethanolamine (MDEA), piperazine (PZ) and the ionic liquids (ILs) 1-n-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]), 1-butyl-3-methylimidazolium dicyanamide ([bmim][DCA]), and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([emim][OTf]) were conducted in this work. It was found that an increase in IL concentration resulted in an increase in the densities and viscosities of the aqueous mixtures. The density and viscosity equations for MDEA, PZ and IL aqueous mixtures as a function of temperature and concentration of ILs were derived as well. The density and viscosity equations obtained adequate accuracies with less than 0.34\% and 4.013\% of deviation from experimental data respectively.",

keywords = "Density, Ionic liquids, N-methyldiethanolamines (MDEA), Piperazine (PZ), Viscosity",

author = "Foo, \{C. K.\} and Leo, \{C. Y.\} and R. Aramesh and Aroua, \{M. K.\} and N. Aghamohammadi and Shafeeyan, \{M. S.\} and A. Shamiri",

year = "2015",

month = jun,

day = "20",

doi = "10.1016/j.molliq.2015.05.041",

language = "English",

volume = "209",

pages = "596--602",

journal = "Journal of Molecular Liquids",

issn = "0167-7322",

publisher = "Elsevier BV",

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TY - JOUR

T1 - Density and viscosity of aqueous mixtures of N-methyldiethanolamines (MDEA), piperazine (PZ) and ionic liquids

AU - Foo, C. K.

AU - Leo, C. Y.

AU - Aramesh, R.

AU - Aroua, M. K.

AU - Aghamohammadi, N.

AU - Shafeeyan, M. S.

AU - Shamiri, A.

PY - 2015/6/20

Y1 - 2015/6/20

N2 - The density and viscosity measurements of aqueous mixtures of N-methyldiethanolamine (MDEA), piperazine (PZ) and the ionic liquids (ILs) 1-n-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]), 1-butyl-3-methylimidazolium dicyanamide ([bmim][DCA]), and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([emim][OTf]) were conducted in this work. It was found that an increase in IL concentration resulted in an increase in the densities and viscosities of the aqueous mixtures. The density and viscosity equations for MDEA, PZ and IL aqueous mixtures as a function of temperature and concentration of ILs were derived as well. The density and viscosity equations obtained adequate accuracies with less than 0.34% and 4.013% of deviation from experimental data respectively.

AB - The density and viscosity measurements of aqueous mixtures of N-methyldiethanolamine (MDEA), piperazine (PZ) and the ionic liquids (ILs) 1-n-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]), 1-butyl-3-methylimidazolium dicyanamide ([bmim][DCA]), and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([emim][OTf]) were conducted in this work. It was found that an increase in IL concentration resulted in an increase in the densities and viscosities of the aqueous mixtures. The density and viscosity equations for MDEA, PZ and IL aqueous mixtures as a function of temperature and concentration of ILs were derived as well. The density and viscosity equations obtained adequate accuracies with less than 0.34% and 4.013% of deviation from experimental data respectively.

KW - Density

KW - Ionic liquids

KW - N-methyldiethanolamines (MDEA)

KW - Piperazine (PZ)

KW - Viscosity

UR - https://www.scopus.com/pages/publications/84934976150

U2 - 10.1016/j.molliq.2015.05.041

DO - 10.1016/j.molliq.2015.05.041

M3 - Article

AN - SCOPUS:84934976150

SN - 0167-7322

VL - 209

SP - 596

EP - 602

JO - Journal of Molecular Liquids

JF - Journal of Molecular Liquids

ER -

Density and viscosity of aqueous mixtures of N-methyldiethanolamines (MDEA), piperazine (PZ) and ionic liquids

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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