Degradation of Calmagite by dichloride (5,10,15,20tetraphenylporphyrinato)antimony hexachloridoantimonate:[Sb(TPP)Cl                         2                         ] SbCl                         6

Raoudha Soury; Mahjoub Jabli; Tawfik A. Saleh; Azhar Kechich; Frederique Loiseau; Eric Saint-Aman; Habib Nasri

doi:10.1016/j.inoche.2019.03.033

Degradation of Calmagite by dichloride (5,10,15,20tetraphenylporphyrinato)antimony hexachloridoantimonate:[Sb(TPP)Cl ₂ ] SbCl ₆

Raoudha Soury, Mahjoub Jabli, Tawfik A. Saleh^*, Azhar Kechich, Frederique Loiseau, Eric Saint-Aman, Habib Nasri

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

In this paper we reported on the spectroscopic, physicochemical and the catalytic properties of dichloride (5,10,15,20-tetraphenylporphyrinato)antimony(V) hexachloridoantimonate(V) [Sb(TPP)Cl ₂ ] SbCl ₆ (2). Optical spectroscopy data showed a red-shift of both absorption bands; the Soret and the Q, which was observed of the antimony complex compared with that free base porphyrin H ₂ TPP. The optical gap E _g-op was calculated using the Tauc plot method suggesting a semi-conductor product. The [Sb(TPP)] ⁺ and the [Sb(TPP)Cl ₂ ] ⁺ fragments were determined using the mass spectrometry. The fluorescence investigation showed a high fluorescence quantum yield with a lifetime of (2) compared to the free base porphyrin.32% of the calmagite solution was removed (C ₀ = 40 mg/L, pH = 6, mass = 3 mg) using (1). However, using the system (2)/H ₂ O ₂ (C ₀ = 40 mg/L, pH = 6, t = 240 mins), the yield value of decolourisation was found to be 94% at equilibrium.

Original language	English
Pages (from-to)	54-60
Number of pages	7
Journal	Inorganic Chemistry Communication
Volume	104
DOIs	https://doi.org/10.1016/j.inoche.2019.03.033
State	Published - Jun 2019

Bibliographical note

Publisher Copyright:
© 2019 Elsevier B.V.

Keywords

Calmagite
Catalytic;meso-tetraphenylporphyrin
Florescence spectroscopy
Inorganic coordination complex
Physicochemical

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.inoche.2019.03.033

Cite this

Soury, R., Jabli, M., Saleh, T. A., Kechich, A., Loiseau, F., Saint-Aman, E., & Nasri, H. (2019). Degradation of Calmagite by dichloride (5,10,15,20tetraphenylporphyrinato)antimony hexachloridoantimonate:[Sb(TPP)Cl ₂ ] SbCl ₆ Inorganic Chemistry Communication, 104, 54-60. https://doi.org/10.1016/j.inoche.2019.03.033

Soury, Raoudha ; Jabli, Mahjoub ; Saleh, Tawfik A. et al. / Degradation of Calmagite by dichloride (5,10,15,20tetraphenylporphyrinato)antimony hexachloridoantimonate:[Sb(TPP)Cl ₂ ] SbCl ₆ In: Inorganic Chemistry Communication. 2019 ; Vol. 104. pp. 54-60.

@article{c5c879a9705943d3b5bdab2fe4cdc025,

title = " Degradation of Calmagite by dichloride (5,10,15,20tetraphenylporphyrinato)antimony hexachloridoantimonate:[Sb(TPP)Cl 2 ] SbCl 6 ",

abstract = " In this paper we reported on the spectroscopic, physicochemical and the catalytic properties of dichloride (5,10,15,20-tetraphenylporphyrinato)antimony(V) hexachloridoantimonate(V) [Sb(TPP)Cl 2 ] SbCl 6 (2). Optical spectroscopy data showed a red-shift of both absorption bands; the Soret and the Q, which was observed of the antimony complex compared with that free base porphyrin H 2 TPP. The optical gap E g-op was calculated using the Tauc plot method suggesting a semi-conductor product. The [Sb(TPP)] + and the [Sb(TPP)Cl 2 ] + fragments were determined using the mass spectrometry. The fluorescence investigation showed a high fluorescence quantum yield with a lifetime of (2) compared to the free base porphyrin.32\% of the calmagite solution was removed (C 0 = 40 mg/L, pH = 6, mass = 3 mg) using (1). However, using the system (2)/H 2 O 2 (C 0 = 40 mg/L, pH = 6, t = 240 mins), the yield value of decolourisation was found to be 94\% at equilibrium.",

keywords = "Calmagite, Catalytic;meso-tetraphenylporphyrin, Florescence spectroscopy, Inorganic coordination complex, Physicochemical",

author = "Raoudha Soury and Mahjoub Jabli and Saleh, \{Tawfik A.\} and Azhar Kechich and Frederique Loiseau and Eric Saint-Aman and Habib Nasri",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",

year = "2019",

month = jun,

doi = "10.1016/j.inoche.2019.03.033",

language = "English",

volume = "104",

pages = "54--60",

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Soury, R, Jabli, M, Saleh, TA, Kechich, A, Loiseau, F, Saint-Aman, E & Nasri, H 2019, ' Degradation of Calmagite by dichloride (5,10,15,20tetraphenylporphyrinato)antimony hexachloridoantimonate:[Sb(TPP)Cl ₂ ] SbCl ₆ ', Inorganic Chemistry Communication, vol. 104, pp. 54-60. https://doi.org/10.1016/j.inoche.2019.03.033

Degradation of Calmagite by dichloride (5,10,15,20tetraphenylporphyrinato)antimony hexachloridoantimonate:[Sb(TPP)Cl ₂ ] SbCl ₆ . / Soury, Raoudha; Jabli, Mahjoub; Saleh, Tawfik A. et al.
In: Inorganic Chemistry Communication, Vol. 104, 06.2019, p. 54-60.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Degradation of Calmagite by dichloride (5,10,15,20tetraphenylporphyrinato)antimony hexachloridoantimonate:[Sb(TPP)Cl 2 ] SbCl 6

AU - Soury, Raoudha

AU - Jabli, Mahjoub

AU - Saleh, Tawfik A.

AU - Kechich, Azhar

AU - Loiseau, Frederique

AU - Saint-Aman, Eric

AU - Nasri, Habib

PY - 2019/6

Y1 - 2019/6

N2 - In this paper we reported on the spectroscopic, physicochemical and the catalytic properties of dichloride (5,10,15,20-tetraphenylporphyrinato)antimony(V) hexachloridoantimonate(V) [Sb(TPP)Cl 2 ] SbCl 6 (2). Optical spectroscopy data showed a red-shift of both absorption bands; the Soret and the Q, which was observed of the antimony complex compared with that free base porphyrin H 2 TPP. The optical gap E g-op was calculated using the Tauc plot method suggesting a semi-conductor product. The [Sb(TPP)] + and the [Sb(TPP)Cl 2 ] + fragments were determined using the mass spectrometry. The fluorescence investigation showed a high fluorescence quantum yield with a lifetime of (2) compared to the free base porphyrin.32% of the calmagite solution was removed (C 0 = 40 mg/L, pH = 6, mass = 3 mg) using (1). However, using the system (2)/H 2 O 2 (C 0 = 40 mg/L, pH = 6, t = 240 mins), the yield value of decolourisation was found to be 94% at equilibrium.

AB - In this paper we reported on the spectroscopic, physicochemical and the catalytic properties of dichloride (5,10,15,20-tetraphenylporphyrinato)antimony(V) hexachloridoantimonate(V) [Sb(TPP)Cl 2 ] SbCl 6 (2). Optical spectroscopy data showed a red-shift of both absorption bands; the Soret and the Q, which was observed of the antimony complex compared with that free base porphyrin H 2 TPP. The optical gap E g-op was calculated using the Tauc plot method suggesting a semi-conductor product. The [Sb(TPP)] + and the [Sb(TPP)Cl 2 ] + fragments were determined using the mass spectrometry. The fluorescence investigation showed a high fluorescence quantum yield with a lifetime of (2) compared to the free base porphyrin.32% of the calmagite solution was removed (C 0 = 40 mg/L, pH = 6, mass = 3 mg) using (1). However, using the system (2)/H 2 O 2 (C 0 = 40 mg/L, pH = 6, t = 240 mins), the yield value of decolourisation was found to be 94% at equilibrium.

KW - Calmagite

KW - Catalytic;meso-tetraphenylporphyrin

KW - Florescence spectroscopy

KW - Inorganic coordination complex

KW - Physicochemical

UR - https://www.scopus.com/pages/publications/85063720650

U2 - 10.1016/j.inoche.2019.03.033

DO - 10.1016/j.inoche.2019.03.033

M3 - Article

AN - SCOPUS:85063720650

SN - 1387-7003

VL - 104

SP - 54

EP - 60

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

ER -

Soury R, Jabli M, Saleh TA, Kechich A, Loiseau F, Saint-Aman E et al. Degradation of Calmagite by dichloride (5,10,15,20tetraphenylporphyrinato)antimony hexachloridoantimonate:[Sb(TPP)Cl ₂ ] SbCl ₆ Inorganic Chemistry Communication. 2019 Jun;104:54-60. doi: 10.1016/j.inoche.2019.03.033

Degradation of Calmagite by dichloride (5,10,15,20tetraphenylporphyrinato)antimony hexachloridoantimonate:[Sb(TPP)Cl 2 ] SbCl 6