Abstract
Preconcentration of aluminum Al3+ was carried out by a novel deep eutectic solvent based ultrasound-assisted liquid phase microextraction (DES-UALPME) method. The deep eutectic solvents (DESs), a green solvent was first time used for enrichment and quantification of very low concentration of Al3+ in water and food samples, prior to analysed by electrothermal atomic absorption spectrometry (ETAAS). In present method it was observed that % recovery of Al-8-hydroxyquinoline chelates efficiently extracted by DES solvent. Pre-enrichment factor and limit of detection were observed to be 50, and 0.032 μg L−1, respectively. Developed procedure was validated with the CRM (SLRS-5 river water) of Al and a good agreement was observed in results of measured value to the certified value. The RSD was calculated as 3.3%. The presented procedure was successfully carried out to different water and food samples.
Original language | English |
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Pages (from-to) | 588-593 |
Number of pages | 6 |
Journal | Talanta |
Volume | 178 |
DOIs | |
State | Published - 1 Feb 2018 |
Bibliographical note
Publisher Copyright:© 2017 Elsevier B.V.
Keywords
- Aluminum
- Deep eutectic solvent
- Dispersive liquid microextraction
- Electrothermal atomic absorption spectrometry
- Ultrasonication
ASJC Scopus subject areas
- Analytical Chemistry