Date palm ash-MgAl-layered double hydroxide composite: sustainable adsorbent for effective removal of methyl orange and eriochrome black-T from aqueous phase

Nawaf I. Blaisi; Mukarram Zubair; Ihsanullah; Sadaqat Ali; Taye Saheed Kazeem; Mohammad Saood Manzar; Walid Al-Kutti; Mamdouh A. Al Harthi

doi:10.1007/s11356-018-3367-2

Date palm ash-MgAl-layered double hydroxide composite: sustainable adsorbent for effective removal of methyl orange and eriochrome black-T from aqueous phase

Nawaf I. Blaisi, Mukarram Zubair^*, Ihsanullah, Sadaqat Ali, Taye Saheed Kazeem, Mohammad Saood Manzar, Walid Al-Kutti, Mamdouh A. Al Harthi

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

94 Scopus citations

Abstract

Date palm ash (DPA) and MgAl-layered double hydroxide (LDH) composites were synthesized by the co-precipitation method and characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), X-ray diffraction (XRD), and Brunauer–Emmett–Teller (BET). The DPA-MgAl-LDH (DPA/MgAl) composites were employed for the removal of methyl orange (MO) and eriochrome black-T (EBT) from aqueous phase. Incorporation of 33.33% (w/w) DPA into the layers of MgAl increased the surface area from 44.46 to 140.65 m ² /g, which leads to the improved adsorption performance. The maximum adsorption capacity of DPA/MgAl (1:2) at 298 K was 242.98 and 425.16 (mg/g) for MO and EBT, respectively. The adsorption data of dyes were adequately fitted by a pseudo-second-order and Langmuir isotherm model. The composite showed excellent reusability performance up to three cycles. Addition of DPA into MgAl-LDH resulted in an effective low-cost adsorbent for decontamination of dyes from wastewater.

Original language	English
Pages (from-to)	34319-34331
Number of pages	13
Journal	Environmental Science and Pollution Research
Volume	25
Issue number	34
DOIs	https://doi.org/10.1007/s11356-018-3367-2
State	Published - 1 Dec 2018

Bibliographical note

Publisher Copyright:
© 2018, Springer-Verlag GmbH Germany, part of Springer Nature.

Keywords

Adsorption
Date palm ash
Dyes
Layered double hydroxide
Sustainable material

ASJC Scopus subject areas

Environmental Chemistry
Pollution
Health, Toxicology and Mutagenesis

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1007/s11356-018-3367-2

Cite this

Blaisi, N. I., Zubair, M., Ihsanullah, Ali, S., Kazeem, T. S., Manzar, M. S., Al-Kutti, W., & Al Harthi, M. A. (2018). Date palm ash-MgAl-layered double hydroxide composite: sustainable adsorbent for effective removal of methyl orange and eriochrome black-T from aqueous phase. Environmental Science and Pollution Research, 25(34), 34319-34331. https://doi.org/10.1007/s11356-018-3367-2

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title = "Date palm ash-MgAl-layered double hydroxide composite: sustainable adsorbent for effective removal of methyl orange and eriochrome black-T from aqueous phase",

abstract = " Date palm ash (DPA) and MgAl-layered double hydroxide (LDH) composites were synthesized by the co-precipitation method and characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), X-ray diffraction (XRD), and Brunauer–Emmett–Teller (BET). The DPA-MgAl-LDH (DPA/MgAl) composites were employed for the removal of methyl orange (MO) and eriochrome black-T (EBT) from aqueous phase. Incorporation of 33.33\% (w/w) DPA into the layers of MgAl increased the surface area from 44.46 to 140.65 m 2 /g, which leads to the improved adsorption performance. The maximum adsorption capacity of DPA/MgAl (1:2) at 298 K was 242.98 and 425.16 (mg/g) for MO and EBT, respectively. The adsorption data of dyes were adequately fitted by a pseudo-second-order and Langmuir isotherm model. The composite showed excellent reusability performance up to three cycles. Addition of DPA into MgAl-LDH resulted in an effective low-cost adsorbent for decontamination of dyes from wastewater.",

keywords = "Adsorption, Date palm ash, Dyes, Layered double hydroxide, Sustainable material",

author = "Blaisi, \{Nawaf I.\} and Mukarram Zubair and Ihsanullah and Sadaqat Ali and Kazeem, \{Taye Saheed\} and Manzar, \{Mohammad Saood\} and Walid Al-Kutti and \{Al Harthi\}, \{Mamdouh A.\}",

note = "Publisher Copyright: {\textcopyright} 2018, Springer-Verlag GmbH Germany, part of Springer Nature.",

year = "2018",

month = dec,

day = "1",

doi = "10.1007/s11356-018-3367-2",

language = "English",

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Blaisi, NI, Zubair, M, Ihsanullah, Ali, S, Kazeem, TS, Manzar, MS, Al-Kutti, W & Al Harthi, MA 2018, 'Date palm ash-MgAl-layered double hydroxide composite: sustainable adsorbent for effective removal of methyl orange and eriochrome black-T from aqueous phase', Environmental Science and Pollution Research, vol. 25, no. 34, pp. 34319-34331. https://doi.org/10.1007/s11356-018-3367-2

Date palm ash-MgAl-layered double hydroxide composite: sustainable adsorbent for effective removal of methyl orange and eriochrome black-T from aqueous phase. / Blaisi, Nawaf I.; Zubair, Mukarram; Ihsanullah et al.
In: Environmental Science and Pollution Research, Vol. 25, No. 34, 01.12.2018, p. 34319-34331.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Date palm ash-MgAl-layered double hydroxide composite

T2 - sustainable adsorbent for effective removal of methyl orange and eriochrome black-T from aqueous phase

AU - Blaisi, Nawaf I.

AU - Zubair, Mukarram

AU - Ihsanullah,

AU - Ali, Sadaqat

AU - Kazeem, Taye Saheed

AU - Manzar, Mohammad Saood

AU - Al-Kutti, Walid

AU - Al Harthi, Mamdouh A.

PY - 2018/12/1

Y1 - 2018/12/1

N2 - Date palm ash (DPA) and MgAl-layered double hydroxide (LDH) composites were synthesized by the co-precipitation method and characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), X-ray diffraction (XRD), and Brunauer–Emmett–Teller (BET). The DPA-MgAl-LDH (DPA/MgAl) composites were employed for the removal of methyl orange (MO) and eriochrome black-T (EBT) from aqueous phase. Incorporation of 33.33% (w/w) DPA into the layers of MgAl increased the surface area from 44.46 to 140.65 m 2 /g, which leads to the improved adsorption performance. The maximum adsorption capacity of DPA/MgAl (1:2) at 298 K was 242.98 and 425.16 (mg/g) for MO and EBT, respectively. The adsorption data of dyes were adequately fitted by a pseudo-second-order and Langmuir isotherm model. The composite showed excellent reusability performance up to three cycles. Addition of DPA into MgAl-LDH resulted in an effective low-cost adsorbent for decontamination of dyes from wastewater.

AB - Date palm ash (DPA) and MgAl-layered double hydroxide (LDH) composites were synthesized by the co-precipitation method and characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), X-ray diffraction (XRD), and Brunauer–Emmett–Teller (BET). The DPA-MgAl-LDH (DPA/MgAl) composites were employed for the removal of methyl orange (MO) and eriochrome black-T (EBT) from aqueous phase. Incorporation of 33.33% (w/w) DPA into the layers of MgAl increased the surface area from 44.46 to 140.65 m 2 /g, which leads to the improved adsorption performance. The maximum adsorption capacity of DPA/MgAl (1:2) at 298 K was 242.98 and 425.16 (mg/g) for MO and EBT, respectively. The adsorption data of dyes were adequately fitted by a pseudo-second-order and Langmuir isotherm model. The composite showed excellent reusability performance up to three cycles. Addition of DPA into MgAl-LDH resulted in an effective low-cost adsorbent for decontamination of dyes from wastewater.

KW - Adsorption

KW - Date palm ash

KW - Dyes

KW - Layered double hydroxide

KW - Sustainable material

UR - https://www.scopus.com/pages/publications/85055043167

U2 - 10.1007/s11356-018-3367-2

DO - 10.1007/s11356-018-3367-2

M3 - Article

C2 - 30298353

AN - SCOPUS:85055043167

SN - 0944-1344

VL - 25

SP - 34319

EP - 34331

JO - Environmental Science and Pollution Research

JF - Environmental Science and Pollution Research

IS - 34

ER -

Date palm ash-MgAl-layered double hydroxide composite: sustainable adsorbent for effective removal of methyl orange and eriochrome black-T from aqueous phase

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

UN SDGs

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