Abstract
The quaternary ammonium salt 1,1-diallyl-4-fonmylpiperazinium chloride (7) was synthesized in good yields. The monomer (7) on cyclopolymerization in the presence of ammonium persulfate in water solution at 90°C afforded water-soluble polymer (8) having excellent rheological properties. The synthesis of the polymer (8) paves the way for the preparation of a novel class of polymers: dicationic polyelectrolytes (9) and cationic polymer (10) with a basic nitrogen as well as a quaternary nitrogen. Effects of monomer, initiator, and additives concentration were studied. Cyclopolymerization of (7) with 1,1,4,4-tetraallylpiperazinium dichloride (12) gave ion-exchange resins with excellent swelling coefficients.
| Original language | English |
|---|---|
| Pages (from-to) | 1077-1085 |
| Number of pages | 9 |
| Journal | Journal of Applied Polymer Science |
| Volume | 61 |
| Issue number | 7 |
| DOIs | |
| State | Published - 15 Aug 1996 |
ASJC Scopus subject areas
- General Chemistry
- Surfaces, Coatings and Films
- Polymers and Plastics
- Materials Chemistry
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