Crystal chemistry, single crystal X-ray structure and magnetism of nickel manganese pyrophosphate

K. Benkhouja; M. Zahir; A. Sadel; A. Handizi; A. Boukhari; E. M. Holt; J. Aride; M. Drillon

doi:10.1016/0025-5408(94)00106-5

Crystal chemistry, single crystal X-ray structure and magnetism of nickel manganese pyrophosphate

K. Benkhouja^*, M. Zahir, A. Sadel, A. Handizi, A. Boukhari, E. M. Holt, J. Aride, M. Drillon

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A study of the crystal chemistry of the Ni_{2 - x}Mn_xP₂O₇ systems in powder form, 0 ≤ x ≤ 2, has revealed the existence of three solid solutions. When x < 0.10, the solution is isostructural with low temperature form, α-Ni₂P₂O₇. When 0.10 ≤ x ≤ 0.40, the structure of the solid solution is similar to that of σ-Ni₂P₂O₇. When 0.60 ≤ x ≤ 2, a form similar to β-Ni₂P₂O₇ (or Mn₂P₂O₇) is seen. The single crystal structure of material corresponding to x = 0.816 has been determined in monoclinic space group Cm, a = 6.557(3), b = 8.738(5), c = 4.498(3), β = 103.24(1) °, V = 240.6(2)Å³, Z = 2, R R_w = 3.8 5.3% and shows a structural deformation of the parent lattice. The system shows antiferromagnetic interactions at low temperature.

Original language	English
Pages (from-to)	49-55
Number of pages	7
Journal	Materials Research Bulletin
Volume	30
Issue number	1
DOIs	https://doi.org/10.1016/0025-5408(94)00106-5
State	Published - Jan 1995
Externally published	Yes

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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10.1016/0025-5408(94)00106-5

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@article{2d200f6cece1483881d1fff5c778a0c7,

title = "Crystal chemistry, single crystal X-ray structure and magnetism of nickel manganese pyrophosphate",

abstract = "A study of the crystal chemistry of the Ni2 - xMnxP2O7 systems in powder form, 0 ≤ x ≤ 2, has revealed the existence of three solid solutions. When x < 0.10, the solution is isostructural with low temperature form, α-Ni2P2O7. When 0.10 ≤ x ≤ 0.40, the structure of the solid solution is similar to that of σ-Ni2P2O7. When 0.60 ≤ x ≤ 2, a form similar to β-Ni2P2O7 (or Mn2P2O7) is seen. The single crystal structure of material corresponding to x = 0.816 has been determined in monoclinic space group Cm, a = 6.557(3), b = 8.738(5), c = 4.498(3), β = 103.24(1) °, V = 240.6(2){\AA}3, Z = 2, R Rw = 3.8 5.3\% and shows a structural deformation of the parent lattice. The system shows antiferromagnetic interactions at low temperature.",

author = "K. Benkhouja and M. Zahir and A. Sadel and A. Handizi and A. Boukhari and Holt, \{E. M.\} and J. Aride and M. Drillon",

year = "1995",

month = jan,

doi = "10.1016/0025-5408(94)00106-5",

language = "English",

volume = "30",

pages = "49--55",

journal = "Materials Research Bulletin",

issn = "0025-5408",

publisher = "Elsevier Ltd.",

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TY - JOUR

T1 - Crystal chemistry, single crystal X-ray structure and magnetism of nickel manganese pyrophosphate

AU - Benkhouja, K.

AU - Zahir, M.

AU - Sadel, A.

AU - Handizi, A.

AU - Boukhari, A.

AU - Holt, E. M.

AU - Aride, J.

AU - Drillon, M.

PY - 1995/1

Y1 - 1995/1

N2 - A study of the crystal chemistry of the Ni2 - xMnxP2O7 systems in powder form, 0 ≤ x ≤ 2, has revealed the existence of three solid solutions. When x < 0.10, the solution is isostructural with low temperature form, α-Ni2P2O7. When 0.10 ≤ x ≤ 0.40, the structure of the solid solution is similar to that of σ-Ni2P2O7. When 0.60 ≤ x ≤ 2, a form similar to β-Ni2P2O7 (or Mn2P2O7) is seen. The single crystal structure of material corresponding to x = 0.816 has been determined in monoclinic space group Cm, a = 6.557(3), b = 8.738(5), c = 4.498(3), β = 103.24(1) °, V = 240.6(2)Å3, Z = 2, R Rw = 3.8 5.3% and shows a structural deformation of the parent lattice. The system shows antiferromagnetic interactions at low temperature.

AB - A study of the crystal chemistry of the Ni2 - xMnxP2O7 systems in powder form, 0 ≤ x ≤ 2, has revealed the existence of three solid solutions. When x < 0.10, the solution is isostructural with low temperature form, α-Ni2P2O7. When 0.10 ≤ x ≤ 0.40, the structure of the solid solution is similar to that of σ-Ni2P2O7. When 0.60 ≤ x ≤ 2, a form similar to β-Ni2P2O7 (or Mn2P2O7) is seen. The single crystal structure of material corresponding to x = 0.816 has been determined in monoclinic space group Cm, a = 6.557(3), b = 8.738(5), c = 4.498(3), β = 103.24(1) °, V = 240.6(2)Å3, Z = 2, R Rw = 3.8 5.3% and shows a structural deformation of the parent lattice. The system shows antiferromagnetic interactions at low temperature.

UR - https://www.scopus.com/pages/publications/0029232843

U2 - 10.1016/0025-5408(94)00106-5

DO - 10.1016/0025-5408(94)00106-5

M3 - Article

AN - SCOPUS:0029232843

SN - 0025-5408

VL - 30

SP - 49

EP - 55

JO - Materials Research Bulletin

JF - Materials Research Bulletin

IS - 1

ER -

Crystal chemistry, single crystal X-ray structure and magnetism of nickel manganese pyrophosphate

Abstract

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