Crystal and molecular structure of (E)-2-t-butyl-3(3′-t-butyldimethylsiloxy)propyl-2-cyanocyclobutanone

M. Sakhawat Hussain; Mazhar-Ul-Haque; M. Muqtar; A. H. Al-Husaini; Sk Asrof Ali

doi:10.1007/BF01833675

Crystal and molecular structure of (E)-2-t-butyl-3(3′-t-butyldimethylsiloxy)propyl-2-cyanocyclobutanone

M. Sakhawat Hussain^*, Mazhar-Ul-Haque, M. Muqtar, A. H. Al-Husaini, Sk Asrof Ali

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title compound crystallizes in the monoclinic space group P2₁/a, with a+12.906(9). b+11.604(2). c+14.631(9) Å, β=108.70(3)° and Z+4. The structure was solved by direct methods from diffractometer data and refined to a final R value of 0.057 for 2020 independent reflections. The structure analysis confirms the cis disposition of the bulky substituents and indicates a puckered four-membered ring with a dihedral angle of 18.5° as expected for a non-centrosymmetrically substituted cyclobutanone.

Original language	English
Pages (from-to)	171-174
Number of pages	4
Journal	Journal of Chemical Crystallography
Volume	24
Issue number	2
DOIs	https://doi.org/10.1007/BF01833675
State	Published - Feb 1994

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics

Access to Document

10.1007/BF01833675

Cite this

@article{4967eb8d88b14c30bb0b36b15b2d2ef2,

title = "Crystal and molecular structure of (E)-2-t-butyl-3(3′-t-butyldimethylsiloxy)propyl-2-cyanocyclobutanone",

abstract = "The title compound crystallizes in the monoclinic space group P21/a, with a+12.906(9). b+11.604(2). c+14.631(9) {\AA}, β=108.70(3)° and Z+4. The structure was solved by direct methods from diffractometer data and refined to a final R value of 0.057 for 2020 independent reflections. The structure analysis confirms the cis disposition of the bulky substituents and indicates a puckered four-membered ring with a dihedral angle of 18.5° as expected for a non-centrosymmetrically substituted cyclobutanone.",

author = "Hussain, \{M. Sakhawat\} and Mazhar-Ul-Haque and M. Muqtar and Al-Husaini, \{A. H.\} and Ali, \{Sk Asrof\}",

year = "1994",

month = feb,

doi = "10.1007/BF01833675",

language = "English",

volume = "24",

pages = "171--174",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

number = "2",

}

TY - JOUR

T1 - Crystal and molecular structure of (E)-2-t-butyl-3(3′-t-butyldimethylsiloxy)propyl-2-cyanocyclobutanone

AU - Hussain, M. Sakhawat

AU - Mazhar-Ul-Haque,

AU - Muqtar, M.

AU - Al-Husaini, A. H.

AU - Ali, Sk Asrof

PY - 1994/2

Y1 - 1994/2

N2 - The title compound crystallizes in the monoclinic space group P21/a, with a+12.906(9). b+11.604(2). c+14.631(9) Å, β=108.70(3)° and Z+4. The structure was solved by direct methods from diffractometer data and refined to a final R value of 0.057 for 2020 independent reflections. The structure analysis confirms the cis disposition of the bulky substituents and indicates a puckered four-membered ring with a dihedral angle of 18.5° as expected for a non-centrosymmetrically substituted cyclobutanone.

AB - The title compound crystallizes in the monoclinic space group P21/a, with a+12.906(9). b+11.604(2). c+14.631(9) Å, β=108.70(3)° and Z+4. The structure was solved by direct methods from diffractometer data and refined to a final R value of 0.057 for 2020 independent reflections. The structure analysis confirms the cis disposition of the bulky substituents and indicates a puckered four-membered ring with a dihedral angle of 18.5° as expected for a non-centrosymmetrically substituted cyclobutanone.

UR - https://www.scopus.com/pages/publications/34249769344

U2 - 10.1007/BF01833675

DO - 10.1007/BF01833675

M3 - Article

AN - SCOPUS:34249769344

SN - 1074-1542

VL - 24

SP - 171

EP - 174

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 2

ER -

Crystal and molecular structure of (E)-2-t-butyl-3(3′-t-butyldimethylsiloxy)propyl-2-cyanocyclobutanone

Abstract

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this