Cr(VI) and Cr(III) speciation on Bacillus sphaericus loaded diaion SP-850 resin

Mustafa Tuzen; Ozgur Dogan Uluozlu; Mustafa Soylak

doi:10.1016/j.jhazmat.2006.10.069

Cr(VI) and Cr(III) speciation on Bacillus sphaericus loaded diaion SP-850 resin

Mustafa Tuzen
, Ozgur Dogan Uluozlu
, Mustafa Soylak^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

A speciation procedure for chromium(III) and chromium(VI) in the environmental samples has been established in the presented work. The procedure presented based on quantitative biosorption of chromium(III) on Bacillus sphaericus loaded Diaion SP-850 at pH 5. The Cr(VI) recoveries at pH 5 were below 5% on the biosorbent. After reduction of Cr(VI) by concentrated H₂SO₄ and ethanol, the system was applied to the total chromium. Cr(VI) was calculated as the difference between the total chromium content and the Cr(III) content. Optimal analytical conditions including pH, amounts of biosorbent, etc. for Cr(III) recoveries were investigated. The influences of the some alkaline and earth alkaline ions and some transition metals on the recoveries were also investigated. The capacity of biosorbent for chromium(III) was 6.95 mg g^-1. The detection limit (3 sigma) of the reagent blank for chromium(III) was 0.50 μg L^-1. The procedure was successfully applied to the speciation of chromium(III) and chromium(VI) in natural water samples (R.S.D. lower than 5%, recoveries greater than 95%).

Original language	English
Pages (from-to)	549-555
Number of pages	7
Journal	Journal of Hazardous Materials
Volume	144
Issue number	1-2
DOIs	https://doi.org/10.1016/j.jhazmat.2006.10.069
State	Published - 6 May 2007
Externally published	Yes

Bibliographical note

Funding Information:
The authors are grateful for the financial support of the Unit of the Scientific Research Projects of Gaziosmanpasa University and the Unit of the Scientific Research Projects of Erciyes University. The authors also thank to Dr. C. Usta for her helps.

Keywords

Atomic absorption spectrometry
Bacillus sphaericus
Biosorption
Chromium
Diaion SP-850
Speciation

ASJC Scopus subject areas

Environmental Engineering
Environmental Chemistry
Waste Management and Disposal
Pollution
Health, Toxicology and Mutagenesis

Access to Document

10.1016/j.jhazmat.2006.10.069

Cite this

@article{8ed3fb62c4634009bbe84fdfccbf8cb1,

title = "Cr(VI) and Cr(III) speciation on Bacillus sphaericus loaded diaion SP-850 resin",

abstract = "A speciation procedure for chromium(III) and chromium(VI) in the environmental samples has been established in the presented work. The procedure presented based on quantitative biosorption of chromium(III) on Bacillus sphaericus loaded Diaion SP-850 at pH 5. The Cr(VI) recoveries at pH 5 were below 5\% on the biosorbent. After reduction of Cr(VI) by concentrated H2SO4 and ethanol, the system was applied to the total chromium. Cr(VI) was calculated as the difference between the total chromium content and the Cr(III) content. Optimal analytical conditions including pH, amounts of biosorbent, etc. for Cr(III) recoveries were investigated. The influences of the some alkaline and earth alkaline ions and some transition metals on the recoveries were also investigated. The capacity of biosorbent for chromium(III) was 6.95 mg g-1. The detection limit (3 sigma) of the reagent blank for chromium(III) was 0.50 μg L-1. The procedure was successfully applied to the speciation of chromium(III) and chromium(VI) in natural water samples (R.S.D. lower than 5\%, recoveries greater than 95\%).",

keywords = "Atomic absorption spectrometry, Bacillus sphaericus, Biosorption, Chromium, Diaion SP-850, Speciation",

author = "Mustafa Tuzen and Uluozlu, \{Ozgur Dogan\} and Mustafa Soylak",

note = "Funding Information: The authors are grateful for the financial support of the Unit of the Scientific Research Projects of Gaziosmanpasa University and the Unit of the Scientific Research Projects of Erciyes University. The authors also thank to Dr. C. Usta for her helps.",

year = "2007",

month = may,

day = "6",

doi = "10.1016/j.jhazmat.2006.10.069",

language = "English",

volume = "144",

pages = "549--555",

journal = "Journal of Hazardous Materials",

issn = "0304-3894",

publisher = "Elsevier BV",

number = "1-2",

}

TY - JOUR

T1 - Cr(VI) and Cr(III) speciation on Bacillus sphaericus loaded diaion SP-850 resin

AU - Tuzen, Mustafa

AU - Uluozlu, Ozgur Dogan

AU - Soylak, Mustafa

N1 - Funding Information: The authors are grateful for the financial support of the Unit of the Scientific Research Projects of Gaziosmanpasa University and the Unit of the Scientific Research Projects of Erciyes University. The authors also thank to Dr. C. Usta for her helps.

PY - 2007/5/6

Y1 - 2007/5/6

N2 - A speciation procedure for chromium(III) and chromium(VI) in the environmental samples has been established in the presented work. The procedure presented based on quantitative biosorption of chromium(III) on Bacillus sphaericus loaded Diaion SP-850 at pH 5. The Cr(VI) recoveries at pH 5 were below 5% on the biosorbent. After reduction of Cr(VI) by concentrated H2SO4 and ethanol, the system was applied to the total chromium. Cr(VI) was calculated as the difference between the total chromium content and the Cr(III) content. Optimal analytical conditions including pH, amounts of biosorbent, etc. for Cr(III) recoveries were investigated. The influences of the some alkaline and earth alkaline ions and some transition metals on the recoveries were also investigated. The capacity of biosorbent for chromium(III) was 6.95 mg g-1. The detection limit (3 sigma) of the reagent blank for chromium(III) was 0.50 μg L-1. The procedure was successfully applied to the speciation of chromium(III) and chromium(VI) in natural water samples (R.S.D. lower than 5%, recoveries greater than 95%).

AB - A speciation procedure for chromium(III) and chromium(VI) in the environmental samples has been established in the presented work. The procedure presented based on quantitative biosorption of chromium(III) on Bacillus sphaericus loaded Diaion SP-850 at pH 5. The Cr(VI) recoveries at pH 5 were below 5% on the biosorbent. After reduction of Cr(VI) by concentrated H2SO4 and ethanol, the system was applied to the total chromium. Cr(VI) was calculated as the difference between the total chromium content and the Cr(III) content. Optimal analytical conditions including pH, amounts of biosorbent, etc. for Cr(III) recoveries were investigated. The influences of the some alkaline and earth alkaline ions and some transition metals on the recoveries were also investigated. The capacity of biosorbent for chromium(III) was 6.95 mg g-1. The detection limit (3 sigma) of the reagent blank for chromium(III) was 0.50 μg L-1. The procedure was successfully applied to the speciation of chromium(III) and chromium(VI) in natural water samples (R.S.D. lower than 5%, recoveries greater than 95%).

KW - Atomic absorption spectrometry

KW - Bacillus sphaericus

KW - Biosorption

KW - Chromium

KW - Diaion SP-850

KW - Speciation

UR - https://www.scopus.com/pages/publications/34248199369

U2 - 10.1016/j.jhazmat.2006.10.069

DO - 10.1016/j.jhazmat.2006.10.069

M3 - Article

C2 - 17126998

AN - SCOPUS:34248199369

SN - 0304-3894

VL - 144

SP - 549

EP - 555

JO - Journal of Hazardous Materials

JF - Journal of Hazardous Materials

IS - 1-2

ER -

Cr(VI) and Cr(III) speciation on Bacillus sphaericus loaded diaion SP-850 resin

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this