Covalent organic frameworks as promising adsorbent paradigm for environmental pollutants from aqueous matrices: Perspective and challenges

Covalent organic frameworks (COFs) are an emerging class of new porous crystalline polymers materials having robust framework, outstanding structural regularity, highly ordered aperture size, inherent porosity, and chemical stability with designer properties, making them an ideal material for adsorbing a variety of contaminants from water bodies. Presented study focusses on the current advances and progress of pristine COFs as well as COFs based composites as an emerging substitute for the adsorption and removal of a variety of pollutants including water desalination technique, heavy metals, pharmaceuticals, dyes and organic pollutants. The absorption capabilities of COFs-derived architecture are evaluated and equated with those of other commonly used adsorbents. The interaction between sorption ability and structural property as well as some regularly utilized ways to improve the adsorption performance of COFs-based materials are also reviewed. Finally, perspective and a summary about the challenges and opportunities of COFs and COFs-derived materials are discussed to deliver some exciting data for fabricating and designing of COFs and COFs-derived materials for remediation of environmental pollutants.