Corrosion properties of duplex treated Ti-6Al-4V alloy in chloride media using electrochemical and positron annihilation spectroscopy techniques

M. M. Khaled; B. S. Yilbas; I. Y. Al-Qaradawi; P. G. Coleman; D. Abdulmalik; Z. S. Seddigi; A. Abulkibash; B. F. Abu-Sharkh; M. M. Emad

doi:10.1016/j.surfcoat.2006.01.019

Corrosion properties of duplex treated Ti-6Al-4V alloy in chloride media using electrochemical and positron annihilation spectroscopy techniques

M. M. Khaled^*
, B. S. Yilbas
, I. Y. Al-Qaradawi
, P. G. Coleman
, D. Abdulmalik
, Z. S. Seddigi
, A. Abulkibash
, B. F. Abu-Sharkh
, M. M. Emad

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The corrosion properties of duplex-treated and nitrided Ti-6Al-4V have been investigated in 0.025, 0.25 and 2.5 M NaCl using electrochemical techniques, Positron Annihilation Spectroscopy (PAS), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and Energy Dispersive Spectrometry (EDS). The electrochemical results showed a three-fold increase in corrosion rate for every ten-fold increase in chloride concentration. The morphology and surface composition studied by XRD showed the presence of TiN and Ti₂N layers. SEM and EDS showed the presence of pitting and the presence of oxide and chloride products. At the lowest concentration of NaCl no aluminum was detected in the surface layers while at the highest concentration no chloride byproducts were detected. PAS indicated that the damage caused by the NaCl changes in nature and becomes shallower as the concentration increases.

Original language	English
Pages (from-to)	932-937
Number of pages	6
Journal	Surface and Coatings Technology
Volume	201
Issue number	3-4
DOIs	https://doi.org/10.1016/j.surfcoat.2006.01.019
State	Published - 5 Oct 2006

Keywords

Coating
Corrosion
Duplex
Laser
Ti-6Al-4V
TiN

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
Surfaces and Interfaces
Surfaces, Coatings and Films
Materials Chemistry

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10.1016/j.surfcoat.2006.01.019

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Khaled, M. M., Yilbas, B. S., Al-Qaradawi, I. Y., Coleman, P. G., Abdulmalik, D., Seddigi, Z. S., Abulkibash, A., Abu-Sharkh, B. F., & Emad, M. M. (2006). Corrosion properties of duplex treated Ti-6Al-4V alloy in chloride media using electrochemical and positron annihilation spectroscopy techniques. Surface and Coatings Technology, 201(3-4), 932-937. https://doi.org/10.1016/j.surfcoat.2006.01.019

@article{965569e86bd24227a98b72e40c9671f3,

title = "Corrosion properties of duplex treated Ti-6Al-4V alloy in chloride media using electrochemical and positron annihilation spectroscopy techniques",

abstract = "The corrosion properties of duplex-treated and nitrided Ti-6Al-4V have been investigated in 0.025, 0.25 and 2.5 M NaCl using electrochemical techniques, Positron Annihilation Spectroscopy (PAS), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and Energy Dispersive Spectrometry (EDS). The electrochemical results showed a three-fold increase in corrosion rate for every ten-fold increase in chloride concentration. The morphology and surface composition studied by XRD showed the presence of TiN and Ti2N layers. SEM and EDS showed the presence of pitting and the presence of oxide and chloride products. At the lowest concentration of NaCl no aluminum was detected in the surface layers while at the highest concentration no chloride byproducts were detected. PAS indicated that the damage caused by the NaCl changes in nature and becomes shallower as the concentration increases.",

keywords = "Coating, Corrosion, Duplex, Laser, Ti-6Al-4V, TiN",

author = "Khaled, \{M. M.\} and Yilbas, \{B. S.\} and Al-Qaradawi, \{I. Y.\} and Coleman, \{P. G.\} and D. Abdulmalik and Seddigi, \{Z. S.\} and A. Abulkibash and Abu-Sharkh, \{B. F.\} and Emad, \{M. M.\}",

year = "2006",

month = oct,

day = "5",

doi = "10.1016/j.surfcoat.2006.01.019",

language = "English",

volume = "201",

pages = "932--937",

journal = "Surface and Coatings Technology",

issn = "0257-8972",

publisher = "Elsevier BV",

number = "3-4",

}

Khaled, MM, Yilbas, BS, Al-Qaradawi, IY, Coleman, PG, Abdulmalik, D, Seddigi, ZS, Abulkibash, A, Abu-Sharkh, BF & Emad, MM 2006, 'Corrosion properties of duplex treated Ti-6Al-4V alloy in chloride media using electrochemical and positron annihilation spectroscopy techniques', Surface and Coatings Technology, vol. 201, no. 3-4, pp. 932-937. https://doi.org/10.1016/j.surfcoat.2006.01.019

TY - JOUR

T1 - Corrosion properties of duplex treated Ti-6Al-4V alloy in chloride media using electrochemical and positron annihilation spectroscopy techniques

AU - Khaled, M. M.

AU - Yilbas, B. S.

AU - Al-Qaradawi, I. Y.

AU - Coleman, P. G.

AU - Abdulmalik, D.

AU - Seddigi, Z. S.

AU - Abulkibash, A.

AU - Abu-Sharkh, B. F.

AU - Emad, M. M.

PY - 2006/10/5

Y1 - 2006/10/5

N2 - The corrosion properties of duplex-treated and nitrided Ti-6Al-4V have been investigated in 0.025, 0.25 and 2.5 M NaCl using electrochemical techniques, Positron Annihilation Spectroscopy (PAS), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and Energy Dispersive Spectrometry (EDS). The electrochemical results showed a three-fold increase in corrosion rate for every ten-fold increase in chloride concentration. The morphology and surface composition studied by XRD showed the presence of TiN and Ti2N layers. SEM and EDS showed the presence of pitting and the presence of oxide and chloride products. At the lowest concentration of NaCl no aluminum was detected in the surface layers while at the highest concentration no chloride byproducts were detected. PAS indicated that the damage caused by the NaCl changes in nature and becomes shallower as the concentration increases.

AB - The corrosion properties of duplex-treated and nitrided Ti-6Al-4V have been investigated in 0.025, 0.25 and 2.5 M NaCl using electrochemical techniques, Positron Annihilation Spectroscopy (PAS), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and Energy Dispersive Spectrometry (EDS). The electrochemical results showed a three-fold increase in corrosion rate for every ten-fold increase in chloride concentration. The morphology and surface composition studied by XRD showed the presence of TiN and Ti2N layers. SEM and EDS showed the presence of pitting and the presence of oxide and chloride products. At the lowest concentration of NaCl no aluminum was detected in the surface layers while at the highest concentration no chloride byproducts were detected. PAS indicated that the damage caused by the NaCl changes in nature and becomes shallower as the concentration increases.

KW - Coating

KW - Corrosion

KW - Duplex

KW - Laser

KW - Ti-6Al-4V

KW - TiN

UR - https://www.scopus.com/pages/publications/33748425104

U2 - 10.1016/j.surfcoat.2006.01.019

DO - 10.1016/j.surfcoat.2006.01.019

M3 - Article

AN - SCOPUS:33748425104

SN - 0257-8972

VL - 201

SP - 932

EP - 937

JO - Surface and Coatings Technology

JF - Surface and Coatings Technology

IS - 3-4

ER -

Corrosion properties of duplex treated Ti-6Al-4V alloy in chloride media using electrochemical and positron annihilation spectroscopy techniques

Abstract

Keywords

ASJC Scopus subject areas

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