Coprecipitation of gold(III), palladium(II) and lead(II) for their flame atomic absorption spectrometric determinations

Mustafa Soylak; Mustafa Tuzen

doi:10.1016/j.jhazmat.2007.07.027

Coprecipitation of gold(III), palladium(II) and lead(II) for their flame atomic absorption spectrometric determinations

Mustafa Soylak^*
, Mustafa Tuzen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

172 Scopus citations

Abstract

An enrichment-separation procedure based on the coprecipitation of gold(III), palladium(II) and lead(II) ions with nickel(II)-5-methyl-4-(2-thiazolylazo) resorcinol complex has been developed. The analytical parameters including pH, amounts of 5-methyl-4-(2-thiazolylazo) resorcinol, sample volume, etc. was investigated for quantitative recoveries of Au(III), Pd(II) and Pb(II). Interference due to various cations and anions has also been investigated. The detection limits for analyte ions by 3σ were 2.6 μg L^-1 for lead, 1.5 μg L^-1 for gold, 2.1 μg L^-1 for palladium. The accuracy of the method was evaluated by the analysis of certified reference materials (NIST SRM 2711 Montana soil, GBW 07309 Stream sediment). The proposed procedure was successfully applied to environmental samples for the determinations of analytes.

Original language	English
Pages (from-to)	656-661
Number of pages	6
Journal	Journal of Hazardous Materials
Volume	152
Issue number	2
DOIs	https://doi.org/10.1016/j.jhazmat.2007.07.027
State	Published - 1 Apr 2008
Externally published	Yes

Bibliographical note

Funding Information:
The authors are grateful for the financial support of the Unit of the Scientific Research Project of Erciyes University (project no: EUBAP-FBT 04-07) and the Unit of the Scientific Research Projects of Gaziosmanpasa University.

Keywords

5-Methyl-4-(2-thiazolylazo) resorcinol
Coprecipitation
Flame atomic absorption spectrometry
Metal
Preconcentration

ASJC Scopus subject areas

Environmental Engineering
Environmental Chemistry
Waste Management and Disposal
Pollution
Health, Toxicology and Mutagenesis

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10.1016/j.jhazmat.2007.07.027

Cite this

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title = "Coprecipitation of gold(III), palladium(II) and lead(II) for their flame atomic absorption spectrometric determinations",

abstract = "An enrichment-separation procedure based on the coprecipitation of gold(III), palladium(II) and lead(II) ions with nickel(II)-5-methyl-4-(2-thiazolylazo) resorcinol complex has been developed. The analytical parameters including pH, amounts of 5-methyl-4-(2-thiazolylazo) resorcinol, sample volume, etc. was investigated for quantitative recoveries of Au(III), Pd(II) and Pb(II). Interference due to various cations and anions has also been investigated. The detection limits for analyte ions by 3σ were 2.6 μg L-1 for lead, 1.5 μg L-1 for gold, 2.1 μg L-1 for palladium. The accuracy of the method was evaluated by the analysis of certified reference materials (NIST SRM 2711 Montana soil, GBW 07309 Stream sediment). The proposed procedure was successfully applied to environmental samples for the determinations of analytes.",

keywords = "5-Methyl-4-(2-thiazolylazo) resorcinol, Coprecipitation, Flame atomic absorption spectrometry, Metal, Preconcentration",

author = "Mustafa Soylak and Mustafa Tuzen",

note = "Funding Information: The authors are grateful for the financial support of the Unit of the Scientific Research Project of Erciyes University (project no: EUBAP-FBT 04-07) and the Unit of the Scientific Research Projects of Gaziosmanpasa University.",

year = "2008",

month = apr,

day = "1",

doi = "10.1016/j.jhazmat.2007.07.027",

language = "English",

volume = "152",

pages = "656--661",

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AU - Soylak, Mustafa

AU - Tuzen, Mustafa

N1 - Funding Information: The authors are grateful for the financial support of the Unit of the Scientific Research Project of Erciyes University (project no: EUBAP-FBT 04-07) and the Unit of the Scientific Research Projects of Gaziosmanpasa University.

PY - 2008/4/1

Y1 - 2008/4/1

N2 - An enrichment-separation procedure based on the coprecipitation of gold(III), palladium(II) and lead(II) ions with nickel(II)-5-methyl-4-(2-thiazolylazo) resorcinol complex has been developed. The analytical parameters including pH, amounts of 5-methyl-4-(2-thiazolylazo) resorcinol, sample volume, etc. was investigated for quantitative recoveries of Au(III), Pd(II) and Pb(II). Interference due to various cations and anions has also been investigated. The detection limits for analyte ions by 3σ were 2.6 μg L-1 for lead, 1.5 μg L-1 for gold, 2.1 μg L-1 for palladium. The accuracy of the method was evaluated by the analysis of certified reference materials (NIST SRM 2711 Montana soil, GBW 07309 Stream sediment). The proposed procedure was successfully applied to environmental samples for the determinations of analytes.

AB - An enrichment-separation procedure based on the coprecipitation of gold(III), palladium(II) and lead(II) ions with nickel(II)-5-methyl-4-(2-thiazolylazo) resorcinol complex has been developed. The analytical parameters including pH, amounts of 5-methyl-4-(2-thiazolylazo) resorcinol, sample volume, etc. was investigated for quantitative recoveries of Au(III), Pd(II) and Pb(II). Interference due to various cations and anions has also been investigated. The detection limits for analyte ions by 3σ were 2.6 μg L-1 for lead, 1.5 μg L-1 for gold, 2.1 μg L-1 for palladium. The accuracy of the method was evaluated by the analysis of certified reference materials (NIST SRM 2711 Montana soil, GBW 07309 Stream sediment). The proposed procedure was successfully applied to environmental samples for the determinations of analytes.

KW - 5-Methyl-4-(2-thiazolylazo) resorcinol

KW - Coprecipitation

KW - Flame atomic absorption spectrometry

KW - Metal

KW - Preconcentration

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DO - 10.1016/j.jhazmat.2007.07.027

M3 - Article

C2 - 17703875

AN - SCOPUS:39849110894

SN - 0304-3894

VL - 152

SP - 656

EP - 661

JO - Journal of Hazardous Materials

JF - Journal of Hazardous Materials

IS - 2

ER -

Coprecipitation of gold(III), palladium(II) and lead(II) for their flame atomic absorption spectrometric determinations

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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