Conversion of carbon dioxide into methanol with silanes over n-heterocyclic carbene catalysts

Siti Nurhanna Riduan; Yugen Zhang; Jackie Y. Ying

doi:10.1002/anie.200806058

Conversion of carbon dioxide into methanol with silanes over n-heterocyclic carbene catalysts

Siti Nurhanna Riduan
, Yugen Zhang^*
, Jackie Y. Ying

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

552 Scopus citations

Abstract

Activate and reduce: Carbon dioxide was reduced with silane using a stable N-heterocyclic carbene organocatalyst to provide methanol under very mild conditions. Dry air can serve as the feedstock, and the organocatalyst is much more efficient than transition-metal catalysts for this reaction. This approach offers a very promising protocol for chemical CO ₂ activation and fixation.

Original language	English
Pages (from-to)	3322-3325
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	18
DOIs	https://doi.org/10.1002/anie.200806058
State	Published - 20 Apr 2009
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 13 Climate Action

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200806058

Cite this

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title = "Conversion of carbon dioxide into methanol with silanes over n-heterocyclic carbene catalysts",

abstract = "Activate and reduce: Carbon dioxide was reduced with silane using a stable N-heterocyclic carbene organocatalyst to provide methanol under very mild conditions. Dry air can serve as the feedstock, and the organocatalyst is much more efficient than transition-metal catalysts for this reaction. This approach offers a very promising protocol for chemical CO 2 activation and fixation.",

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AU - Ying, Jackie Y.

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AB - Activate and reduce: Carbon dioxide was reduced with silane using a stable N-heterocyclic carbene organocatalyst to provide methanol under very mild conditions. Dry air can serve as the feedstock, and the organocatalyst is much more efficient than transition-metal catalysts for this reaction. This approach offers a very promising protocol for chemical CO 2 activation and fixation.

UR - https://www.scopus.com/pages/publications/70349854454

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DO - 10.1002/anie.200806058

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IS - 18

ER -

Conversion of carbon dioxide into methanol with silanes over n-heterocyclic carbene catalysts

Abstract

UN SDGs

ASJC Scopus subject areas

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