Cobalt(III) and chromium(III) complexes of thiosemicarbazide: the crystal structure of Λ-cis-tris(thiosemicarbazide)cobalt(III) chloride trihydrate

Mazhar-ul-Haque; M. Sakhawat Hussain

doi:10.1007/BF00166278

Cobalt(III) and chromium(III) complexes of thiosemicarbazide: the crystal structure of Λ-cis-tris(thiosemicarbazide)cobalt(III) chloride trihydrate

Mazhar-ul-Haque^*, M. Sakhawat Hussain

^*Corresponding author for this work

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Cobalt(III) and chromium(III) complexes of thiosemicarbazide (Htsc) were prepared and the structure of [Co(Htsc)₃]Cl₃·3H₂O was determined by X-ray crystallography. The structure was solved by direct methods and refined by full matrix least squares to R = 0.035 for 2266 observed reflections. The metal has octahedral geometry with a cis arrangement of Htsc ligands. The [Co(Htsc)₃]³⁺ cations within the unit cell are strongly hydrogen bonded through H₂O molecules with the hydrogen bonding nitrogen-oxygen distances between 2.807-2.937 Å.

Original language	English
Pages (from-to)	95-98
Number of pages	4
Journal	Transition Metal Chemistry
Volume	19
Issue number	1
DOIs	https://doi.org/10.1007/BF00166278
State	Published - Feb 1994

ASJC Scopus subject areas

Inorganic Chemistry
Metals and Alloys
Materials Chemistry

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title = "Cobalt(III) and chromium(III) complexes of thiosemicarbazide: the crystal structure of Λ-cis-tris(thiosemicarbazide)cobalt(III) chloride trihydrate",

abstract = "Cobalt(III) and chromium(III) complexes of thiosemicarbazide (Htsc) were prepared and the structure of [Co(Htsc)3]Cl3·3H2O was determined by X-ray crystallography. The structure was solved by direct methods and refined by full matrix least squares to R = 0.035 for 2266 observed reflections. The metal has octahedral geometry with a cis arrangement of Htsc ligands. The [Co(Htsc)3]3+ cations within the unit cell are strongly hydrogen bonded through H2O molecules with the hydrogen bonding nitrogen-oxygen distances between 2.807-2.937 {\AA}.",

author = "Mazhar-ul-Haque and Hussain, \{M. Sakhawat\}",

year = "1994",

month = feb,

doi = "10.1007/BF00166278",

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volume = "19",

pages = "95--98",

journal = "Transition Metal Chemistry",

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T1 - Cobalt(III) and chromium(III) complexes of thiosemicarbazide

T2 - the crystal structure of Λ-cis-tris(thiosemicarbazide)cobalt(III) chloride trihydrate

AU - Mazhar-ul-Haque,

AU - Hussain, M. Sakhawat

PY - 1994/2

Y1 - 1994/2

N2 - Cobalt(III) and chromium(III) complexes of thiosemicarbazide (Htsc) were prepared and the structure of [Co(Htsc)3]Cl3·3H2O was determined by X-ray crystallography. The structure was solved by direct methods and refined by full matrix least squares to R = 0.035 for 2266 observed reflections. The metal has octahedral geometry with a cis arrangement of Htsc ligands. The [Co(Htsc)3]3+ cations within the unit cell are strongly hydrogen bonded through H2O molecules with the hydrogen bonding nitrogen-oxygen distances between 2.807-2.937 Å.

AB - Cobalt(III) and chromium(III) complexes of thiosemicarbazide (Htsc) were prepared and the structure of [Co(Htsc)3]Cl3·3H2O was determined by X-ray crystallography. The structure was solved by direct methods and refined by full matrix least squares to R = 0.035 for 2266 observed reflections. The metal has octahedral geometry with a cis arrangement of Htsc ligands. The [Co(Htsc)3]3+ cations within the unit cell are strongly hydrogen bonded through H2O molecules with the hydrogen bonding nitrogen-oxygen distances between 2.807-2.937 Å.

UR - https://www.scopus.com/pages/publications/0346331870

U2 - 10.1007/BF00166278

DO - 10.1007/BF00166278

M3 - Article

AN - SCOPUS:0346331870

SN - 0340-4285

VL - 19

SP - 95

EP - 98

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 1

ER -

Cobalt(III) and chromium(III) complexes of thiosemicarbazide: the crystal structure of Λ-cis-tris(thiosemicarbazide)cobalt(III) chloride trihydrate

Abstract

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