CO2 Conversion via Catalytic Hydrogenation to Methanol, DME and Syngas

Muhammad Usman; Mustapha D. Garba; Zonish Zeb; Muhammad  Israr; Safia  Safia; Fatima  Javed; Munzir Hamedelniel Suliman; Bandar  Alfaify; Mohammed A. Sanhoob; Naseem Iqbal; Muhammad Humayun; Aasif Helal

doi:10.1007/978-981-99-2890-3_2

CO2 Conversion via Catalytic Hydrogenation to Methanol, DME and Syngas

Muhammad Usman^*
, Mustapha D. Garba
, Zonish Zeb
, Muhammad Israr
, Safia Safia
, Fatima Javed
, Munzir Hamedelniel Suliman
, Bandar Alfaify
, Mohammed A. Sanhoob
, Naseem Iqbal
, Muhammad Humayun
, Aasif Helal

^*Corresponding author for this work

Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

This chapter introduces carbon dioxide (CO2) hydrogenation to fuel and valuable chemicals as a best approach for CO2 mitigation. Among the useful products, methanol (MeOH), dimethyl ether (DME) and syngas are highly attractive industrial feedstocks. This chapter provides an overview of the mechanism of catalytic hydrogenation of CO2 to methanol, dimethyl ether and syngas which mainly undergoes via a methanol-mediated route or modified-CO2 Fischer–Tropsch synthesis (FTS) via two-step RWGS reaction and FT synthesis. The advancement in hydrogenation catalysts for CO2 conversion to MeOH, syngas and DME is highlighted. This chapter outlines the progress toward promoters, catalyst supports, structure–performance associations and reaction conditions’ optimization for each process. In addition, this chapter describes the importance of heterogeneous catalysis and future perspectives for the design of efficient catalysts for CO2 conversion to valuable products.

Original language	American English
Title of host publication	CO2 Conversion via Catalytic Hydrogenation to Methanol, DME and Syngas
Publisher	Springer Nature
Pages	37-59
DOIs	https://doi.org/10.1007/978-981-99-2890-3_2
State	Published - 9 Jul 2023

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 3 Good Health and Well-being
SDG 7 Affordable and Clean Energy
SDG 8 Decent Work and Economic Growth
SDG 12 Responsible Consumption and Production
SDG 13 Climate Action

Keywords

CO2 reduction
Hydrogenation
Methanol
DME
Syngas
Catalysis

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10.1007/978-981-99-2890-3_2

Cite this

Usman, M., Garba, M. D., Zeb, Z., Israr, M., Safia, S., Javed, F., Suliman, M. H., Alfaify, B., Sanhoob, M. A., Iqbal, N., Humayun, M., & Helal, A. (2023). CO2 Conversion via Catalytic Hydrogenation to Methanol, DME and Syngas. In CO2 Conversion via Catalytic Hydrogenation to Methanol, DME and Syngas (pp. 37-59). Springer Nature. https://doi.org/10.1007/978-981-99-2890-3_2

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AU - Safia, Safia

AU - Javed, Fatima

AU - Suliman, Munzir Hamedelniel

AU - Alfaify, Bandar

AU - Sanhoob, Mohammed A.

AU - Iqbal, Naseem

AU - Humayun, Muhammad

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AB - This chapter introduces carbon dioxide (CO2) hydrogenation to fuel and valuable chemicals as a best approach for CO2 mitigation. Among the useful products, methanol (MeOH), dimethyl ether (DME) and syngas are highly attractive industrial feedstocks. This chapter provides an overview of the mechanism of catalytic hydrogenation of CO2 to methanol, dimethyl ether and syngas which mainly undergoes via a methanol-mediated route or modified-CO2 Fischer–Tropsch synthesis (FTS) via two-step RWGS reaction and FT synthesis. The advancement in hydrogenation catalysts for CO2 conversion to MeOH, syngas and DME is highlighted. This chapter outlines the progress toward promoters, catalyst supports, structure–performance associations and reaction conditions’ optimization for each process. In addition, this chapter describes the importance of heterogeneous catalysis and future perspectives for the design of efficient catalysts for CO2 conversion to valuable products.

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KW - Hydrogenation

KW - Methanol

KW - DME

KW - Syngas

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BT - CO2 Conversion via Catalytic Hydrogenation to Methanol, DME and Syngas

PB - Springer Nature

ER -

CO2 Conversion via Catalytic Hydrogenation to Methanol, DME and Syngas

Abstract

UN SDGs

Keywords

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