Chloro(N-ethyl-1,3-imidazolidine-2-thione)gold(I): Spectroscopic studies and x-ray structure

M. Sakhawat Hussain; Anvarhusein A. Isab

doi:10.1007/BF00637028

Chloro(N-ethyl-1,3-imidazolidine-2-thione)gold(I): Spectroscopic studies and x-ray structure

M. Sakhawat Hussain^*
, Anvarhusein A. Isab

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

Chloro(N-ethyl-1,3-imidazolidine-2-thione)gold(II) crystallizes in the triclinic space group P-I with cell dimensions:a=7.213(2)Å, b=7.857(7)Å, c=9.056(3)Å, α=108.54°, β=100.06(3)°, γ=107.27(4)° and Z=2.,The structure was refined by a least squares method to a conventional R factor of 7.3%, using 2157 reflections. The metal atom is bonded through the sulfur atom of the ligand which is consistent with the¹³C n.m.r. spectra of the complexes in d₆-acetone. The structure of the complex and coordination around metal are compared with other linear gold(I) complexes.

Original language	English
Pages (from-to)	398-401
Number of pages	4
Journal	Transition Metal Chemistry
Volume	9
Issue number	10
DOIs	https://doi.org/10.1007/BF00637028
State	Published - Oct 1984

ASJC Scopus subject areas

Inorganic Chemistry
Metals and Alloys
Materials Chemistry

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@article{7e36d7585c694c90826f79a66c17df69,

title = "Chloro(N-ethyl-1,3-imidazolidine-2-thione)gold(I): Spectroscopic studies and x-ray structure",

abstract = "Chloro(N-ethyl-1,3-imidazolidine-2-thione)gold(II) crystallizes in the triclinic space group P-I with cell dimensions:a=7.213(2){\AA}, b=7.857(7){\AA}, c=9.056(3){\AA}, α=108.54°, β=100.06(3)°, γ=107.27(4)° and Z=2.,The structure was refined by a least squares method to a conventional R factor of 7.3\%, using 2157 reflections. The metal atom is bonded through the sulfur atom of the ligand which is consistent with the13C n.m.r. spectra of the complexes in d6-acetone. The structure of the complex and coordination around metal are compared with other linear gold(I) complexes.",

author = "Hussain, \{M. Sakhawat\} and Isab, \{Anvarhusein A.\}",

year = "1984",

month = oct,

doi = "10.1007/BF00637028",

language = "English",

volume = "9",

pages = "398--401",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

number = "10",

}

TY - JOUR

T1 - Chloro(N-ethyl-1,3-imidazolidine-2-thione)gold(I)

T2 - Spectroscopic studies and x-ray structure

AU - Hussain, M. Sakhawat

AU - Isab, Anvarhusein A.

PY - 1984/10

Y1 - 1984/10

N2 - Chloro(N-ethyl-1,3-imidazolidine-2-thione)gold(II) crystallizes in the triclinic space group P-I with cell dimensions:a=7.213(2)Å, b=7.857(7)Å, c=9.056(3)Å, α=108.54°, β=100.06(3)°, γ=107.27(4)° and Z=2.,The structure was refined by a least squares method to a conventional R factor of 7.3%, using 2157 reflections. The metal atom is bonded through the sulfur atom of the ligand which is consistent with the13C n.m.r. spectra of the complexes in d6-acetone. The structure of the complex and coordination around metal are compared with other linear gold(I) complexes.

AB - Chloro(N-ethyl-1,3-imidazolidine-2-thione)gold(II) crystallizes in the triclinic space group P-I with cell dimensions:a=7.213(2)Å, b=7.857(7)Å, c=9.056(3)Å, α=108.54°, β=100.06(3)°, γ=107.27(4)° and Z=2.,The structure was refined by a least squares method to a conventional R factor of 7.3%, using 2157 reflections. The metal atom is bonded through the sulfur atom of the ligand which is consistent with the13C n.m.r. spectra of the complexes in d6-acetone. The structure of the complex and coordination around metal are compared with other linear gold(I) complexes.

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U2 - 10.1007/BF00637028

DO - 10.1007/BF00637028

M3 - Article

AN - SCOPUS:0021510198

SN - 0340-4285

VL - 9

SP - 398

EP - 401

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 10

ER -

Chloro(N-ethyl-1,3-imidazolidine-2-thione)gold(I): Spectroscopic studies and x-ray structure

Abstract

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