Chloro-diorganotin(IV) complexes of 4-methyl-1-piperidine carbodithioic acid: Synthesis, X-ray crystal structures, spectral properties and antimicrobial studies

Saira Shahzadi; Saqib Ali; Moazzam H. Bhatti; Mohammmad Fettouhi; Muhammad Athar

doi:10.1016/j.jorganchem.2005.12.004

Chloro-diorganotin(IV) complexes of 4-methyl-1-piperidine carbodithioic acid: Synthesis, X-ray crystal structures, spectral properties and antimicrobial studies

Saira Shahzadi
, Saqib Ali^*
, Moazzam H. Bhatti
, Mohammmad Fettouhi
, Muhammad Athar

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

68 Scopus citations

Abstract

Chloro-diorganotin(IV) complexes of 4-methyl-1-piperidine carbodithioic acid (4-MePCDTA) have been synthesized by the reaction with diorganotin dichloride in 1:1 molar ratio in anhydrous toluene. These newly synthesized complexes have been characterized by elemental, IR, multinuclear NMR ( ¹H and ¹³C) and mass spectrometric studies. The crystal structures of complex 1 [Me₂SnCl(4-MePCDT)] and 3 [Ph ₂SnCl(4-MePCDT)] have been determined by X-ray single crystal analysis, which show trigonal bipyramid geometry. These complexes were tested for their antimicrobial activity against six different plant and human pathogens. The screening results show that the complexes exhibit higher antibacterial and antifungal activity than the free ligand.

Original language	English
Pages (from-to)	1797-1802
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	691
Issue number	8
DOIs	https://doi.org/10.1016/j.jorganchem.2005.12.004
State	Published - 1 Apr 2006

Bibliographical note

Funding Information:
Saqib Ali is thankful to Quaid-i-Azam University, Islamabad for financial support.

Keywords

Antimicrobial study
Chloro-organotin complexes
Dithiocarbamates
Mass
NMR
X-ray structures

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.jorganchem.2005.12.004

Cite this

@article{a599de56918844ddb6d60bf046c4a9d9,

title = "Chloro-diorganotin(IV) complexes of 4-methyl-1-piperidine carbodithioic acid: Synthesis, X-ray crystal structures, spectral properties and antimicrobial studies",

abstract = "Chloro-diorganotin(IV) complexes of 4-methyl-1-piperidine carbodithioic acid (4-MePCDTA) have been synthesized by the reaction with diorganotin dichloride in 1:1 molar ratio in anhydrous toluene. These newly synthesized complexes have been characterized by elemental, IR, multinuclear NMR ( 1H and 13C) and mass spectrometric studies. The crystal structures of complex 1 [Me2SnCl(4-MePCDT)] and 3 [Ph 2SnCl(4-MePCDT)] have been determined by X-ray single crystal analysis, which show trigonal bipyramid geometry. These complexes were tested for their antimicrobial activity against six different plant and human pathogens. The screening results show that the complexes exhibit higher antibacterial and antifungal activity than the free ligand.",

keywords = "Antimicrobial study, Chloro-organotin complexes, Dithiocarbamates, Mass, NMR, X-ray structures",

author = "Saira Shahzadi and Saqib Ali and Bhatti, \{Moazzam H.\} and Mohammmad Fettouhi and Muhammad Athar",

note = "Funding Information: Saqib Ali is thankful to Quaid-i-Azam University, Islamabad for financial support.",

year = "2006",

month = apr,

day = "1",

doi = "10.1016/j.jorganchem.2005.12.004",

language = "English",

volume = "691",

pages = "1797--1802",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

number = "8",

}

Chloro-diorganotin(IV) complexes of 4-methyl-1-piperidine carbodithioic acid: Synthesis, X-ray crystal structures, spectral properties and antimicrobial studies. / Shahzadi, Saira; Ali, Saqib; Bhatti, Moazzam H. et al.
In: Journal of Organometallic Chemistry, Vol. 691, No. 8, 01.04.2006, p. 1797-1802.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Chloro-diorganotin(IV) complexes of 4-methyl-1-piperidine carbodithioic acid

T2 - Synthesis, X-ray crystal structures, spectral properties and antimicrobial studies

AU - Shahzadi, Saira

AU - Ali, Saqib

AU - Bhatti, Moazzam H.

AU - Fettouhi, Mohammmad

AU - Athar, Muhammad

N1 - Funding Information: Saqib Ali is thankful to Quaid-i-Azam University, Islamabad for financial support.

PY - 2006/4/1

Y1 - 2006/4/1

N2 - Chloro-diorganotin(IV) complexes of 4-methyl-1-piperidine carbodithioic acid (4-MePCDTA) have been synthesized by the reaction with diorganotin dichloride in 1:1 molar ratio in anhydrous toluene. These newly synthesized complexes have been characterized by elemental, IR, multinuclear NMR ( 1H and 13C) and mass spectrometric studies. The crystal structures of complex 1 [Me2SnCl(4-MePCDT)] and 3 [Ph 2SnCl(4-MePCDT)] have been determined by X-ray single crystal analysis, which show trigonal bipyramid geometry. These complexes were tested for their antimicrobial activity against six different plant and human pathogens. The screening results show that the complexes exhibit higher antibacterial and antifungal activity than the free ligand.

AB - Chloro-diorganotin(IV) complexes of 4-methyl-1-piperidine carbodithioic acid (4-MePCDTA) have been synthesized by the reaction with diorganotin dichloride in 1:1 molar ratio in anhydrous toluene. These newly synthesized complexes have been characterized by elemental, IR, multinuclear NMR ( 1H and 13C) and mass spectrometric studies. The crystal structures of complex 1 [Me2SnCl(4-MePCDT)] and 3 [Ph 2SnCl(4-MePCDT)] have been determined by X-ray single crystal analysis, which show trigonal bipyramid geometry. These complexes were tested for their antimicrobial activity against six different plant and human pathogens. The screening results show that the complexes exhibit higher antibacterial and antifungal activity than the free ligand.

KW - Antimicrobial study

KW - Chloro-organotin complexes

KW - Dithiocarbamates

KW - Mass

KW - NMR

KW - X-ray structures

UR - https://www.scopus.com/pages/publications/33644885008

U2 - 10.1016/j.jorganchem.2005.12.004

DO - 10.1016/j.jorganchem.2005.12.004

M3 - Article

AN - SCOPUS:33644885008

SN - 0022-328X

VL - 691

SP - 1797

EP - 1802

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 8

ER -

Chloro-diorganotin(IV) complexes of 4-methyl-1-piperidine carbodithioic acid: Synthesis, X-ray crystal structures, spectral properties and antimicrobial studies

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this