Charge-induced facial-selectivity in the formation of new cationic planar chiral iridacycles derived from aniline

Jean Pierre Djukic; Wissam Iali; Michel Pfeffer; Xavier Frédéric Le Goff

doi:10.1039/c0cc05711h

Charge-induced facial-selectivity in the formation of new cationic planar chiral iridacycles derived from aniline

Jean Pierre Djukic^*
, Wissam Iali
, Michel Pfeffer
, Xavier Frédéric Le Goff

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The reaction of chiral chlorido-iridacyclic 2-(4-N, N-dimethylaminophenyl)pyridines with solvato-type [Cp*M(S)₃]^q+ (M = Ru, S = MeCN, q = 1; M = Ir, S = MeC(O)Me, q = 2) complexes produces new cationic racemic planar chiral iridacycles in an efficient and diastereospecific way.

Original language	English
Pages (from-to)	3631-3633
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	12
DOIs	https://doi.org/10.1039/c0cc05711h
State	Published - 8 Mar 2011
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c0cc05711h

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title = "Charge-induced facial-selectivity in the formation of new cationic planar chiral iridacycles derived from aniline",

abstract = "The reaction of chiral chlorido-iridacyclic 2-(4-N, N-dimethylaminophenyl)pyridines with solvato-type [Cp*M(S)3]q+ (M = Ru, S = MeCN, q = 1; M = Ir, S = MeC(O)Me, q = 2) complexes produces new cationic racemic planar chiral iridacycles in an efficient and diastereospecific way.",

author = "Djukic, \{Jean Pierre\} and Wissam Iali and Michel Pfeffer and Goff, \{Xavier Fr{\'e}d{\'e}ric Le\}",

year = "2011",

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doi = "10.1039/c0cc05711h",

language = "English",

volume = "47",

pages = "3631--3633",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Charge-induced facial-selectivity in the formation of new cationic planar chiral iridacycles derived from aniline

AU - Djukic, Jean Pierre

AU - Iali, Wissam

AU - Pfeffer, Michel

AU - Goff, Xavier Frédéric Le

PY - 2011/3/8

Y1 - 2011/3/8

N2 - The reaction of chiral chlorido-iridacyclic 2-(4-N, N-dimethylaminophenyl)pyridines with solvato-type [Cp*M(S)3]q+ (M = Ru, S = MeCN, q = 1; M = Ir, S = MeC(O)Me, q = 2) complexes produces new cationic racemic planar chiral iridacycles in an efficient and diastereospecific way.

AB - The reaction of chiral chlorido-iridacyclic 2-(4-N, N-dimethylaminophenyl)pyridines with solvato-type [Cp*M(S)3]q+ (M = Ru, S = MeCN, q = 1; M = Ir, S = MeC(O)Me, q = 2) complexes produces new cationic racemic planar chiral iridacycles in an efficient and diastereospecific way.

UR - https://www.scopus.com/pages/publications/79952420451

U2 - 10.1039/c0cc05711h

DO - 10.1039/c0cc05711h

M3 - Article

AN - SCOPUS:79952420451

SN - 1359-7345

VL - 47

SP - 3631

EP - 3633

JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

Charge-induced facial-selectivity in the formation of new cationic planar chiral iridacycles derived from aniline

Abstract

ASJC Scopus subject areas

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