Cationic photopolymerization of cyclohexene oxide

Ideisan I. Abu-Abdoun; Aale-Ali

doi:10.1016/0014-3057(92)90239-X

Cationic photopolymerization of cyclohexene oxide

Ideisan I. Abu-Abdoun^*
, Aale-Ali

^*Corresponding author for this work

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Phenacyltriphenyl phosphonium salts containing the anions SbF₆^- and PF₆^- are useful photoinitiators for cationic polymerization of cyclohexene oxide; photosensitization by the addition of pyrene and N-methylphenothiazine enhances the rate of polymerization. Experimental results are presented to show the effects of photolysis time, photosensitization, initiator concentration and the anion on the rate of polymerization in dichloromethane at 25°.

Original language	English
Pages (from-to)	73-78
Number of pages	6
Journal	European Polymer Journal
Volume	28
Issue number	1
DOIs	https://doi.org/10.1016/0014-3057(92)90239-X
State	Published - Jan 1992

Bibliographical note

Funding Information:
Acknowledgement--We thank the King Fahd University of Petroleum and Minerals for financial support and for the research facilities provided for this work.

ASJC Scopus subject areas

General Physics and Astronomy
Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1016/0014-3057(92)90239-X

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title = "Cationic photopolymerization of cyclohexene oxide",

abstract = "Phenacyltriphenyl phosphonium salts containing the anions SbF6- and PF6- are useful photoinitiators for cationic polymerization of cyclohexene oxide; photosensitization by the addition of pyrene and N-methylphenothiazine enhances the rate of polymerization. Experimental results are presented to show the effects of photolysis time, photosensitization, initiator concentration and the anion on the rate of polymerization in dichloromethane at 25°.",

author = "Abu-Abdoun, \{Ideisan I.\} and Aale-Ali",

note = "Funding Information: Acknowledgement--We thank the King Fahd University of Petroleum and Minerals for financial support and for the research facilities provided for this work.",

year = "1992",

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doi = "10.1016/0014-3057(92)90239-X",

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T1 - Cationic photopolymerization of cyclohexene oxide

AU - Abu-Abdoun, Ideisan I.

AU - Aale-Ali,

N1 - Funding Information: Acknowledgement--We thank the King Fahd University of Petroleum and Minerals for financial support and for the research facilities provided for this work.

PY - 1992/1

Y1 - 1992/1

N2 - Phenacyltriphenyl phosphonium salts containing the anions SbF6- and PF6- are useful photoinitiators for cationic polymerization of cyclohexene oxide; photosensitization by the addition of pyrene and N-methylphenothiazine enhances the rate of polymerization. Experimental results are presented to show the effects of photolysis time, photosensitization, initiator concentration and the anion on the rate of polymerization in dichloromethane at 25°.

AB - Phenacyltriphenyl phosphonium salts containing the anions SbF6- and PF6- are useful photoinitiators for cationic polymerization of cyclohexene oxide; photosensitization by the addition of pyrene and N-methylphenothiazine enhances the rate of polymerization. Experimental results are presented to show the effects of photolysis time, photosensitization, initiator concentration and the anion on the rate of polymerization in dichloromethane at 25°.

UR - https://www.scopus.com/pages/publications/0026771595

U2 - 10.1016/0014-3057(92)90239-X

DO - 10.1016/0014-3057(92)90239-X

M3 - Article

AN - SCOPUS:0026771595

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JO - European Polymer Journal

JF - European Polymer Journal

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Cationic photopolymerization of cyclohexene oxide

Abstract

Bibliographical note

ASJC Scopus subject areas

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