Catena-poly[[[aqua(1,10-phenanthroline-κ2N,N′)zinc] -μ-acetylenedicarboxylato-κ2O1:O2] monohydrate]

Mohammed Fettouhi

doi:10.1107/S1600536812025068

Catena-poly[[[aqua(1,10-phenanthroline-κ²N,N′)zinc] -μ-acetylenedicarboxylato-κ²O¹:O²] monohydrate]

Mohammed Fettouhi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

In the title complex, {[Zn(C₄O₄)(C₁₂H ₈N₂)(H₂O)]·H₂O}_n, the pentacoordinated Zn^II ion is bound to two N atoms of the 1,10-phenanthroline ligand, two O atoms from two bridging acetylenedicarboxylate anions and a water O atom in a distorted trigonal-bipyramidal geometry. The crystal structure is characterized by polymeric zigzag chains running parallel to [21̄0] and is stabilized by O - H⋯O hydrogen bonds.

Original language	English
Pages (from-to)	m895
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	7
DOIs	https://doi.org/10.1107/S1600536812025068
State	Published - Jul 2012

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536812025068

Cite this

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title = "Catena-poly[[[aqua(1,10-phenanthroline-κ2N,N′)zinc] -μ-acetylenedicarboxylato-κ2O1:O2] monohydrate]",

abstract = "In the title complex, {[Zn(C4O4)(C12H 8N2)(H2O)]·H2O}n, the pentacoordinated ZnII ion is bound to two N atoms of the 1,10-phenanthroline ligand, two O atoms from two bridging acetylenedicarboxylate anions and a water O atom in a distorted trigonal-bipyramidal geometry. The crystal structure is characterized by polymeric zigzag chains running parallel to [2{\=1}0] and is stabilized by O - H⋯O hydrogen bonds.",

author = "Mohammed Fettouhi",

year = "2012",

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doi = "10.1107/S1600536812025068",

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publisher = "International Union of Crystallography",

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T1 - Catena-poly[[[aqua(1,10-phenanthroline-κ2N,N′)zinc] -μ-acetylenedicarboxylato-κ2O1:O2] monohydrate]

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PY - 2012/7

Y1 - 2012/7

N2 - In the title complex, {[Zn(C4O4)(C12H 8N2)(H2O)]·H2O}n, the pentacoordinated ZnII ion is bound to two N atoms of the 1,10-phenanthroline ligand, two O atoms from two bridging acetylenedicarboxylate anions and a water O atom in a distorted trigonal-bipyramidal geometry. The crystal structure is characterized by polymeric zigzag chains running parallel to [21̄0] and is stabilized by O - H⋯O hydrogen bonds.

AB - In the title complex, {[Zn(C4O4)(C12H 8N2)(H2O)]·H2O}n, the pentacoordinated ZnII ion is bound to two N atoms of the 1,10-phenanthroline ligand, two O atoms from two bridging acetylenedicarboxylate anions and a water O atom in a distorted trigonal-bipyramidal geometry. The crystal structure is characterized by polymeric zigzag chains running parallel to [21̄0] and is stabilized by O - H⋯O hydrogen bonds.

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

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