Carbonate salts-activated carbon

  • Syed Shaheen Shah
  • , Md Abdul Aziz*
  • , Laiq Zada
  • , Haroon Ur Rahman
  • , Falak Niaz
  • , Khizar Hayat
  • *Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

5 Scopus citations

Abstract

Due to its advantageous chemical stability, low cost, and extensive porosity, activated carbons (AC) are a crucial material in many industries. The AC precursors, synthetic pathways, activating agents, and synthesis parameters are crucial elements for the best synthesis of AC. Using waste biomass as a precursor for AC has recently increased since it is cheap, readily available, and is a method to fight agricultural waste disposal problems. Physical, chemical, and microwave-induced activation methods and circumstances are reported for producing biomass-derived AC. Recent publications show that biomass-derived AC can be employed as supercapacitor electrodes. Under optimal conditions, active carbons with superior specific capacitance and longer cyclic stability have been reported. The enormous surface area and porous structure of the AC-based electrode materials make them intriguing for supercapacitors, fuel cells, and batteries. Based on the electrolyte ions adsorption at the electrode interface, carbonaceous materials display behavior similar to that of electric double-layer capacitors. Changes in surface chemistry, and introducing certain surface functionalities on ACs, impacted electrochemical qualities more than physiochemical properties. For the purpose of creating high-quality AC for supercapacitor electrodes, carbonate salts have been frequently used. Carbonate salts have various advantages, including being industrial byproducts; they are low-cost and widely available worldwide. Activation with carbonate salts allows special morphologies like hierarchical and composed of micro-, meso-, and macropores for easy penetration of the electrolyte, which shorten the path length and exhibit oxygen functional groups. The development of AC from numerous biomass using carbonate salts as activation agents and their utilization as supercapacitor electrodes are summarized in this chapter.

Original languageEnglish
Title of host publicationBiomass-Based Supercapacitors
Subtitle of host publicationDesign, Fabrication and Sustainability
Publisherwiley
Pages143-160
Number of pages18
ISBN (Electronic)9781119866435
ISBN (Print)9781119866404
StatePublished - 20 Jul 2023

Bibliographical note

Publisher Copyright:
© 2023 John Wiley and Sons Ltd. All rights reserved.

Keywords

  • Activated carbon
  • Activation agents
  • Biomass
  • Carbonate salts
  • EDLC
  • High surface area porous carbon
  • Supercapacitors

ASJC Scopus subject areas

  • General Chemistry
  • General Chemical Engineering

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