Carbon dioxide capture in the presence of water by an amine-based crosslinked porous polymer

Mahmoud M. Abdelnaby; Ahmed M. Alloush; Naef A.A. Qasem; Bassem A. Al-Maythalony; Rached B. Mansour; Kyle E. Cordova; Othman Charles S. Al Hamouz

doi:10.1039/c8ta00012c

Carbon dioxide capture in the presence of water by an amine-based crosslinked porous polymer

Mahmoud M. Abdelnaby, Ahmed M. Alloush, Naef A.A. Qasem, Bassem A. Al-Maythalony, Rached B. Mansour, Kyle E. Cordova, Othman Charles S. Al Hamouz^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

An amine-functionalized, crosslinked porous polymer is synthesized by linking 1,4-benzenediamine and pyrrole with p-formaldehyde in the presence of hydrochloric acid catalyst. The resulting polymer was structurally characterized and proven permanently porous with a surface area of 305 m² g^-1. The high concentration of amines (-NH- and -NH₂) within the backbone of the polymer result in exceptional selectivity (141) for CO₂ over N₂ and dynamic capacity (15.1 cm³ g^-1) in the presence of water (20 : 80 v/v CO₂ : N₂, 91% relative humidity, 1 bar, and 298 K). The performance of this polymer is maintained over 45 cycles without loss of selectivity, capacity, nor recyclability at room temperature; making it stand out among all porous organic materials used for carbon capture.

Original language	English
Pages (from-to)	6455-6462
Number of pages	8
Journal	Journal of Materials Chemistry A
Volume	6
Issue number	15
DOIs	https://doi.org/10.1039/c8ta00012c
State	Published - 2018

Bibliographical note

Publisher Copyright:
© 2018 The Royal Society of Chemistry.

ASJC Scopus subject areas

General Chemistry
Renewable Energy, Sustainability and the Environment
General Materials Science

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10.1039/c8ta00012c

Cite this

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title = "Carbon dioxide capture in the presence of water by an amine-based crosslinked porous polymer",

abstract = "An amine-functionalized, crosslinked porous polymer is synthesized by linking 1,4-benzenediamine and pyrrole with p-formaldehyde in the presence of hydrochloric acid catalyst. The resulting polymer was structurally characterized and proven permanently porous with a surface area of 305 m2 g-1. The high concentration of amines (-NH- and -NH2) within the backbone of the polymer result in exceptional selectivity (141) for CO2 over N2 and dynamic capacity (15.1 cm3 g-1) in the presence of water (20 : 80 v/v CO2 : N2, 91% relative humidity, 1 bar, and 298 K). The performance of this polymer is maintained over 45 cycles without loss of selectivity, capacity, nor recyclability at room temperature; making it stand out among all porous organic materials used for carbon capture.",

author = "Abdelnaby, {Mahmoud M.} and Alloush, {Ahmed M.} and Qasem, {Naef A.A.} and Al-Maythalony, {Bassem A.} and Mansour, {Rached B.} and Cordova, {Kyle E.} and {Al Hamouz}, {Othman Charles S.}",

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year = "2018",

doi = "10.1039/c8ta00012c",

language = "English",

volume = "6",

pages = "6455--6462",

journal = "Journal of Materials Chemistry A",

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T1 - Carbon dioxide capture in the presence of water by an amine-based crosslinked porous polymer

AU - Abdelnaby, Mahmoud M.

AU - Alloush, Ahmed M.

AU - Qasem, Naef A.A.

AU - Al-Maythalony, Bassem A.

AU - Mansour, Rached B.

AU - Cordova, Kyle E.

AU - Al Hamouz, Othman Charles S.

PY - 2018

Y1 - 2018

N2 - An amine-functionalized, crosslinked porous polymer is synthesized by linking 1,4-benzenediamine and pyrrole with p-formaldehyde in the presence of hydrochloric acid catalyst. The resulting polymer was structurally characterized and proven permanently porous with a surface area of 305 m2 g-1. The high concentration of amines (-NH- and -NH2) within the backbone of the polymer result in exceptional selectivity (141) for CO2 over N2 and dynamic capacity (15.1 cm3 g-1) in the presence of water (20 : 80 v/v CO2 : N2, 91% relative humidity, 1 bar, and 298 K). The performance of this polymer is maintained over 45 cycles without loss of selectivity, capacity, nor recyclability at room temperature; making it stand out among all porous organic materials used for carbon capture.

AB - An amine-functionalized, crosslinked porous polymer is synthesized by linking 1,4-benzenediamine and pyrrole with p-formaldehyde in the presence of hydrochloric acid catalyst. The resulting polymer was structurally characterized and proven permanently porous with a surface area of 305 m2 g-1. The high concentration of amines (-NH- and -NH2) within the backbone of the polymer result in exceptional selectivity (141) for CO2 over N2 and dynamic capacity (15.1 cm3 g-1) in the presence of water (20 : 80 v/v CO2 : N2, 91% relative humidity, 1 bar, and 298 K). The performance of this polymer is maintained over 45 cycles without loss of selectivity, capacity, nor recyclability at room temperature; making it stand out among all porous organic materials used for carbon capture.

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DO - 10.1039/c8ta00012c

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JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 15

ER -

Carbon dioxide capture in the presence of water by an amine-based crosslinked porous polymer

Abstract

Bibliographical note

ASJC Scopus subject areas

UN SDGs

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