C-C bond formation via C-H activation and C-N bond formation via oxidative amination catalyzed by palladium- polyoxometalate nanomaterials using dioxygen as the terminal oxidant

Leng Leng Chng; Jie Zhang; Jinhua Yang; Makhlouf Amoura; Jackie Y. Ying

doi:10.1002/adsc.201100362

C-C bond formation via C-H activation and C-N bond formation via oxidative amination catalyzed by palladium- polyoxometalate nanomaterials using dioxygen as the terminal oxidant

Leng Leng Chng
, Jie Zhang
, Jinhua Yang
, Makhlouf Amoura
, Jackie Y. Ying^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

65 Scopus citations

Abstract

An efficient heterogeneous palladium-polyoxometalate catalyst with the formula Pd-H₆PV₃Mo₉O₄₀/C has been successfully developed for carbon-carbon (C-C) bond formation via carbon-hydrogen (C-H) activation and carbon-nitrogen (C-N) bond formation via oxidative amination using oxygen as the terminal oxidant. The coupling processes are simple, and use relatively mild conditions to form the desired products. In addition, less waste is generated as no additional reagents such as organic/inorganic oxidants are required, and water is the only by-product generated.

Original language	English
Pages (from-to)	2988-2998
Number of pages	11
Journal	Advanced Synthesis and Catalysis
Volume	353
Issue number	16
DOIs	https://doi.org/10.1002/adsc.201100362
State	Published - Nov 2011
Externally published	Yes

Keywords

C-H activation
heterogeneous catalysis
nanomaterials
palladium
polyoxometalates

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/adsc.201100362

Cite this

@article{f70cdb7779a64103b48132a2fafaa7df,

title = "C-C bond formation via C-H activation and C-N bond formation via oxidative amination catalyzed by palladium- polyoxometalate nanomaterials using dioxygen as the terminal oxidant",

abstract = "An efficient heterogeneous palladium-polyoxometalate catalyst with the formula Pd-H6PV3Mo9O40/C has been successfully developed for carbon-carbon (C-C) bond formation via carbon-hydrogen (C-H) activation and carbon-nitrogen (C-N) bond formation via oxidative amination using oxygen as the terminal oxidant. The coupling processes are simple, and use relatively mild conditions to form the desired products. In addition, less waste is generated as no additional reagents such as organic/inorganic oxidants are required, and water is the only by-product generated.",

keywords = "C-H activation, heterogeneous catalysis, nanomaterials, palladium, polyoxometalates",

author = "Chng, \{Leng Leng\} and Jie Zhang and Jinhua Yang and Makhlouf Amoura and Ying, \{Jackie Y.\}",

year = "2011",

month = nov,

doi = "10.1002/adsc.201100362",

language = "English",

volume = "353",

pages = "2988--2998",

number = "16",

}

C-C bond formation via C-H activation and C-N bond formation via oxidative amination catalyzed by palladium- polyoxometalate nanomaterials using dioxygen as the terminal oxidant. / Chng, Leng Leng; Zhang, Jie; Yang, Jinhua et al.
In: Advanced Synthesis and Catalysis, Vol. 353, No. 16, 11.2011, p. 2988-2998.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - C-C bond formation via C-H activation and C-N bond formation via oxidative amination catalyzed by palladium- polyoxometalate nanomaterials using dioxygen as the terminal oxidant

AU - Chng, Leng Leng

AU - Zhang, Jie

AU - Yang, Jinhua

AU - Amoura, Makhlouf

AU - Ying, Jackie Y.

PY - 2011/11

Y1 - 2011/11

N2 - An efficient heterogeneous palladium-polyoxometalate catalyst with the formula Pd-H6PV3Mo9O40/C has been successfully developed for carbon-carbon (C-C) bond formation via carbon-hydrogen (C-H) activation and carbon-nitrogen (C-N) bond formation via oxidative amination using oxygen as the terminal oxidant. The coupling processes are simple, and use relatively mild conditions to form the desired products. In addition, less waste is generated as no additional reagents such as organic/inorganic oxidants are required, and water is the only by-product generated.

AB - An efficient heterogeneous palladium-polyoxometalate catalyst with the formula Pd-H6PV3Mo9O40/C has been successfully developed for carbon-carbon (C-C) bond formation via carbon-hydrogen (C-H) activation and carbon-nitrogen (C-N) bond formation via oxidative amination using oxygen as the terminal oxidant. The coupling processes are simple, and use relatively mild conditions to form the desired products. In addition, less waste is generated as no additional reagents such as organic/inorganic oxidants are required, and water is the only by-product generated.

KW - C-H activation

KW - heterogeneous catalysis

KW - nanomaterials

KW - palladium

KW - polyoxometalates

UR - https://www.scopus.com/pages/publications/81555195324

U2 - 10.1002/adsc.201100362

DO - 10.1002/adsc.201100362

M3 - Article

AN - SCOPUS:81555195324

SN - 1615-4150

VL - 353

SP - 2988

EP - 2998

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 16

ER -

C-C bond formation via C-H activation and C-N bond formation via oxidative amination catalyzed by palladium- polyoxometalate nanomaterials using dioxygen as the terminal oxidant

Abstract

Keywords

ASJC Scopus subject areas

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