Bis(O-n-butyl dithiocarbonato-κ 2 S,S′)bis-(pyridine- N)manganese(II)

Naveed Alam; Muhammad Ali Ehsan; Matthias Zeller; Muhammad Mazhar; Zainudin Arifin

doi:10.1107/S1600536811026523

Bis(O-n-butyl dithiocarbonato-κ ² S,S′)bis-(pyridine- N)manganese(II)

Naveed Alam
, Muhammad Ali Ehsan
, Matthias Zeller
, Muhammad Mazhar
, Zainudin Arifin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The structure of the title manganese complex, [Mn(C ₅H ₉OS ₂) ₂(C ₅H ₅N) ₂] or [Mn(S ₂CO-n-Bu) ₂(C ₅H ₅N) ₂], consists of discrete monomeric entities with Mn ²⁺ ions located on centres of inversion. The metal atom is coordinated by a six-coordinate trans-N ₂S ₄ donor set with the pyridyl N atoms located in the apical positions. The observed slight deviations from octa-hedral geometry are caused by the bite angle of the bidentate κ ²-S ₂CO-n-Bu ligands [69.48 (1)°]. The O(CH ₂) ₃(CH ₃) chains of the O-n-butyl dithio-carbonate units are disordered over two sets of sites with an occupancy ratio of 0.589 (2):0.411 (2).

Original language	English
Pages (from-to)	m1064
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	8
DOIs	https://doi.org/10.1107/S1600536811026523
State	Published - Aug 2011
Externally published	Yes

Keywords

R factor = 0.025
T = 100 K
disorder in main residue
mean σ(CC) = 0.002 Å
single-crystal X-ray study
wR factor = 0.064; data-to-parameter ratio = 19.0

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536811026523

Cite this

@article{abc9cd042df741d982188856624afe4f,

title = "Bis(O-n-butyl dithiocarbonato-κ 2 S,S′)bis-(pyridine- N)manganese(II)",

abstract = "The structure of the title manganese complex, [Mn(C 5H 9OS 2) 2(C 5H 5N) 2] or [Mn(S 2CO-n-Bu) 2(C 5H 5N) 2], consists of discrete monomeric entities with Mn 2+ ions located on centres of inversion. The metal atom is coordinated by a six-coordinate trans-N 2S 4 donor set with the pyridyl N atoms located in the apical positions. The observed slight deviations from octa-hedral geometry are caused by the bite angle of the bidentate κ 2-S 2CO-n-Bu ligands [69.48 (1)°]. The O(CH 2) 3(CH 3) chains of the O-n-butyl dithio-carbonate units are disordered over two sets of sites with an occupancy ratio of 0.589 (2):0.411 (2).",

keywords = "R factor = 0.025, T = 100 K, disorder in main residue, mean σ(CC) = 0.002 {\AA}, single-crystal X-ray study, wR factor = 0.064; data-to-parameter ratio = 19.0",

author = "Naveed Alam and Ehsan, \{Muhammad Ali\} and Matthias Zeller and Muhammad Mazhar and Zainudin Arifin",

year = "2011",

month = aug,

doi = "10.1107/S1600536811026523",

language = "English",

volume = "67",

pages = "m1064",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "8",

}

TY - JOUR

T1 - Bis(O-n-butyl dithiocarbonato-κ 2 S,S′)bis-(pyridine- N)manganese(II)

AU - Alam, Naveed

AU - Ehsan, Muhammad Ali

AU - Zeller, Matthias

AU - Mazhar, Muhammad

AU - Arifin, Zainudin

PY - 2011/8

Y1 - 2011/8

N2 - The structure of the title manganese complex, [Mn(C 5H 9OS 2) 2(C 5H 5N) 2] or [Mn(S 2CO-n-Bu) 2(C 5H 5N) 2], consists of discrete monomeric entities with Mn 2+ ions located on centres of inversion. The metal atom is coordinated by a six-coordinate trans-N 2S 4 donor set with the pyridyl N atoms located in the apical positions. The observed slight deviations from octa-hedral geometry are caused by the bite angle of the bidentate κ 2-S 2CO-n-Bu ligands [69.48 (1)°]. The O(CH 2) 3(CH 3) chains of the O-n-butyl dithio-carbonate units are disordered over two sets of sites with an occupancy ratio of 0.589 (2):0.411 (2).

AB - The structure of the title manganese complex, [Mn(C 5H 9OS 2) 2(C 5H 5N) 2] or [Mn(S 2CO-n-Bu) 2(C 5H 5N) 2], consists of discrete monomeric entities with Mn 2+ ions located on centres of inversion. The metal atom is coordinated by a six-coordinate trans-N 2S 4 donor set with the pyridyl N atoms located in the apical positions. The observed slight deviations from octa-hedral geometry are caused by the bite angle of the bidentate κ 2-S 2CO-n-Bu ligands [69.48 (1)°]. The O(CH 2) 3(CH 3) chains of the O-n-butyl dithio-carbonate units are disordered over two sets of sites with an occupancy ratio of 0.589 (2):0.411 (2).

KW - R factor = 0.025

KW - T = 100 K

KW - disorder in main residue

KW - mean σ(CC) = 0.002 Å

KW - single-crystal X-ray study

KW - wR factor = 0.064; data-to-parameter ratio = 19.0

UR - https://www.scopus.com/pages/publications/80051529681

U2 - 10.1107/S1600536811026523

DO - 10.1107/S1600536811026523

M3 - Article

AN - SCOPUS:80051529681

SN - 1600-5368

VL - 67

SP - m1064

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -