Bis(N-propyl-1,3-imidazolidine-2-thione)gold(I) chloride: Crystal and molecular structure

M. Sakhawat Hussain; Anvarhusein A. Isab

doi:10.1007/BF00620667

Bis(N-propyl-1,3-imidazolidine-2-thione)gold(I) chloride: Crystal and molecular structure

M. Sakhawat Hussain^*
, Anvarhusein A. Isab

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The crystal and molecular structures of bis(N-propyl-1,3-imidazolidine-2-thione)gold(I) chloride, [(PrImt)₂Au]Cl, has been determined from three-dimensional x-ray intensity data collected on a CAD4 diffractometer. The compound crystallizes in the monoclinic space group P2₁/n with a=7.195(7), b=15.283(3), c=15.899(6) Å, β=91.7(1) and Z = 4. Atomic parameters were refined by full-matrix least-squares methods to the R value of 6.2% for 2272 observed reflections. Gold(I) exhibits the usual linear coordination with S(1)-Au-S(10) angle of 177.7(1)°. The two [Prlmt] molecules are arranged in trans configuration which is attributed to the effects of intermolecular H-bonding between N-H and the halogen. The Au-S bond length is compared with the corresponding bond length in several known structures in order to evaluate the trans influence of phosphorus, sulfur and chloride ligands on the Au-S bond.

Original language	English
Pages (from-to)	178-181
Number of pages	4
Journal	Transition Metal Chemistry
Volume	10
Issue number	5
DOIs	https://doi.org/10.1007/BF00620667
State	Published - May 1985

ASJC Scopus subject areas

Inorganic Chemistry
Metals and Alloys
Materials Chemistry

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@article{4114202d96f641008b908c1f7170d21e,

title = "Bis(N-propyl-1,3-imidazolidine-2-thione)gold(I) chloride: Crystal and molecular structure",

abstract = "The crystal and molecular structures of bis(N-propyl-1,3-imidazolidine-2-thione)gold(I) chloride, [(PrImt)2Au]Cl, has been determined from three-dimensional x-ray intensity data collected on a CAD4 diffractometer. The compound crystallizes in the monoclinic space group P21/n with a=7.195(7), b=15.283(3), c=15.899(6) {\AA}, β=91.7(1) and Z = 4. Atomic parameters were refined by full-matrix least-squares methods to the R value of 6.2\% for 2272 observed reflections. Gold(I) exhibits the usual linear coordination with S(1)-Au-S(10) angle of 177.7(1)°. The two [Prlmt] molecules are arranged in trans configuration which is attributed to the effects of intermolecular H-bonding between N-H and the halogen. The Au-S bond length is compared with the corresponding bond length in several known structures in order to evaluate the trans influence of phosphorus, sulfur and chloride ligands on the Au-S bond.",

author = "Hussain, \{M. Sakhawat\} and Isab, \{Anvarhusein A.\}",

year = "1985",

month = may,

doi = "10.1007/BF00620667",

language = "English",

volume = "10",

pages = "178--181",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Netherlands",

number = "5",

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TY - JOUR

T1 - Bis(N-propyl-1,3-imidazolidine-2-thione)gold(I) chloride

T2 - Crystal and molecular structure

AU - Hussain, M. Sakhawat

AU - Isab, Anvarhusein A.

PY - 1985/5

Y1 - 1985/5

N2 - The crystal and molecular structures of bis(N-propyl-1,3-imidazolidine-2-thione)gold(I) chloride, [(PrImt)2Au]Cl, has been determined from three-dimensional x-ray intensity data collected on a CAD4 diffractometer. The compound crystallizes in the monoclinic space group P21/n with a=7.195(7), b=15.283(3), c=15.899(6) Å, β=91.7(1) and Z = 4. Atomic parameters were refined by full-matrix least-squares methods to the R value of 6.2% for 2272 observed reflections. Gold(I) exhibits the usual linear coordination with S(1)-Au-S(10) angle of 177.7(1)°. The two [Prlmt] molecules are arranged in trans configuration which is attributed to the effects of intermolecular H-bonding between N-H and the halogen. The Au-S bond length is compared with the corresponding bond length in several known structures in order to evaluate the trans influence of phosphorus, sulfur and chloride ligands on the Au-S bond.

AB - The crystal and molecular structures of bis(N-propyl-1,3-imidazolidine-2-thione)gold(I) chloride, [(PrImt)2Au]Cl, has been determined from three-dimensional x-ray intensity data collected on a CAD4 diffractometer. The compound crystallizes in the monoclinic space group P21/n with a=7.195(7), b=15.283(3), c=15.899(6) Å, β=91.7(1) and Z = 4. Atomic parameters were refined by full-matrix least-squares methods to the R value of 6.2% for 2272 observed reflections. Gold(I) exhibits the usual linear coordination with S(1)-Au-S(10) angle of 177.7(1)°. The two [Prlmt] molecules are arranged in trans configuration which is attributed to the effects of intermolecular H-bonding between N-H and the halogen. The Au-S bond length is compared with the corresponding bond length in several known structures in order to evaluate the trans influence of phosphorus, sulfur and chloride ligands on the Au-S bond.

UR - https://www.scopus.com/pages/publications/0039593413

U2 - 10.1007/BF00620667

DO - 10.1007/BF00620667

M3 - Article

AN - SCOPUS:0039593413

SN - 0340-4285

VL - 10

SP - 178

EP - 181

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 5

ER -

Bis(N-propyl-1,3-imidazolidine-2-thione)gold(I) chloride: Crystal and molecular structure

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