Bimetallic nanosized solids with acid and redox properties for catalytic activation of C-C and C-H bonds

JR Cabrero-Antonino; M Tejeda-Serrano; M Quesada; JA Vidal-Moya; A Leyva-Perez; Avelino Corma Canos

Bimetallic nanosized solids with acid and redox properties for catalytic activation of C-C and C-H bonds

JR Cabrero-Antonino, M Tejeda-Serrano, M Quesada, JA Vidal-Moya, A Leyva-Perez, Avelino Corma Canos

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

Abstract

A new approach is presented to form self-supported bimetallic nanosized solids with acid and redox catalytic properties. They are water-, air- and H-2-stable, and are able to activate demanding C-C and C-H reactions. A detailed mechanistic study on the formation of the Ag-Fe bimetallic system shows that a rapid redox-coupled sequence between Ag+, O-2 (air) and Fe2+ occurs, giving monodisperse Ag nanoparticles supported by O-bridged diatomic Fe3+ triflimides. The system can be expanded to Ag nanoparticles embedded within a matrix of Cu2+, Bi3+ and Yb3+ triflimide.

Original language	English
Journal	Chemical Science
State	Published - 2017

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title = "Bimetallic nanosized solids with acid and redox properties for catalytic activation of C-C and C-H bonds",

abstract = "A new approach is presented to form self-supported bimetallic nanosized solids with acid and redox catalytic properties. They are water-, air- and H-2-stable, and are able to activate demanding C-C and C-H reactions. A detailed mechanistic study on the formation of the Ag-Fe bimetallic system shows that a rapid redox-coupled sequence between Ag+, O-2 (air) and Fe2+ occurs, giving monodisperse Ag nanoparticles supported by O-bridged diatomic Fe3+ triflimides. The system can be expanded to Ag nanoparticles embedded within a matrix of Cu2+, Bi3+ and Yb3+ triflimide.",

author = "JR Cabrero-Antonino and M Tejeda-Serrano and M Quesada and JA Vidal-Moya and A Leyva-Perez and Canos, \{Avelino Corma\}",

year = "2017",

language = "English",

}

TY - JOUR

T1 - Bimetallic nanosized solids with acid and redox properties for catalytic activation of C-C and C-H bonds

AU - Cabrero-Antonino, JR

AU - Tejeda-Serrano, M

AU - Quesada, M

AU - Vidal-Moya, JA

AU - Leyva-Perez, A

AU - Canos, Avelino Corma

PY - 2017

Y1 - 2017

N2 - A new approach is presented to form self-supported bimetallic nanosized solids with acid and redox catalytic properties. They are water-, air- and H-2-stable, and are able to activate demanding C-C and C-H reactions. A detailed mechanistic study on the formation of the Ag-Fe bimetallic system shows that a rapid redox-coupled sequence between Ag+, O-2 (air) and Fe2+ occurs, giving monodisperse Ag nanoparticles supported by O-bridged diatomic Fe3+ triflimides. The system can be expanded to Ag nanoparticles embedded within a matrix of Cu2+, Bi3+ and Yb3+ triflimide.

AB - A new approach is presented to form self-supported bimetallic nanosized solids with acid and redox catalytic properties. They are water-, air- and H-2-stable, and are able to activate demanding C-C and C-H reactions. A detailed mechanistic study on the formation of the Ag-Fe bimetallic system shows that a rapid redox-coupled sequence between Ag+, O-2 (air) and Fe2+ occurs, giving monodisperse Ag nanoparticles supported by O-bridged diatomic Fe3+ triflimides. The system can be expanded to Ag nanoparticles embedded within a matrix of Cu2+, Bi3+ and Yb3+ triflimide.

M3 - Article

SN - 2041-6520

JO - Chemical Science

JF - Chemical Science

ER -

Bimetallic nanosized solids with acid and redox properties for catalytic activation of C-C and C-H bonds

Abstract

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