Azulene based metal-organic frameworks for strong adsorption of H 2

Samir Barman; Hiroyasu Furukawa; Olivier Blacque; Koushik Venkatesan; Omar M. Yaghi; Heinz Berke

doi:10.1039/c0cc02589e

Azulene based metal-organic frameworks for strong adsorption of H ₂

Samir Barman, Hiroyasu Furukawa^*, Olivier Blacque, Koushik Venkatesan, Omar M. Yaghi, Heinz Berke

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H₂ interactions (7.8-6.8 kJ mol^-1), which revealed the significant impact of internally polarized azulene backbone to stabilized H₂ molecules in the framework.

Original language	English
Pages (from-to)	7981-7983
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	42
DOIs	https://doi.org/10.1039/c0cc02589e
State	Published - 14 Nov 2010
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c0cc02589e

Cite this

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abstract = "Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H2 interactions (7.8-6.8 kJ mol-1), which revealed the significant impact of internally polarized azulene backbone to stabilized H2 molecules in the framework.",

author = "Samir Barman and Hiroyasu Furukawa and Olivier Blacque and Koushik Venkatesan and Yaghi, {Omar M.} and Heinz Berke",

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AU - Barman, Samir

AU - Furukawa, Hiroyasu

AU - Blacque, Olivier

AU - Venkatesan, Koushik

AU - Yaghi, Omar M.

AU - Berke, Heinz

PY - 2010/11/14

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N2 - Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H2 interactions (7.8-6.8 kJ mol-1), which revealed the significant impact of internally polarized azulene backbone to stabilized H2 molecules in the framework.

AB - Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H2 interactions (7.8-6.8 kJ mol-1), which revealed the significant impact of internally polarized azulene backbone to stabilized H2 molecules in the framework.

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JO - Chemical Communications

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