Are the approach directions of σ and π nucleophiles to the sulfur atom of thiiranium and thiirenium ions different?

Theis I. Sølling; S. Bruce Wild; Leo Radom

doi:10.1002/(SICI)1521-3765(20000218)6:4<590::AID-CHEM590>3.0.CO;2-E

Are the approach directions of σ and π nucleophiles to the sulfur atom of thiiranium and thiirenium ions different?

Theis I. Sølling
, S. Bruce Wild
, Leo Radom^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A collinear approach to the sulfur atom of thiiranium and thiirenium ions (see scheme) is predicted by theoretical calculations for both σ and π nucleophiles.

Original language	English
Pages (from-to)	590-591
Number of pages	2
Journal	Chemistry - A European Journal
Volume	6
Issue number	4
DOIs	https://doi.org/10.1002/(SICI)1521-3765(20000218)6:4<590::AID-CHEM590>3.0.CO;2-E
State	Published - 18 Feb 2000
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Access to Document

10.1002/(SICI)1521-3765(20000218)6:4<590::AID-CHEM590>3.0.CO;2-E

Cite this

@article{ecffbd210c604146a4b93441f5cb9282,

title = "Are the approach directions of σ and π nucleophiles to the sulfur atom of thiiranium and thiirenium ions different?",

abstract = "A collinear approach to the sulfur atom of thiiranium and thiirenium ions (see scheme) is predicted by theoretical calculations for both σ and π nucleophiles.",

author = "S{\o}lling, \{Theis I.\} and Wild, \{S. Bruce\} and Leo Radom",

year = "2000",

month = feb,

day = "18",

doi = "10.1002/(SICI)1521-3765(20000218)6:4<590::AID-CHEM590>3.0.CO;2-E",

language = "English",

volume = "6",

pages = "590--591",

journal = "Chemistry - A European Journal",

issn = "0947-6539",