An eco-friendly low-temperature synthetic approach towards micro-pebble-structured GO@SrTiO3 nanocomposites for the detection of 2,4,6-trichlorophenol in environmental samples

Muthumariappan Akilarasan; Elayappan Tamilalagan; Shen Ming Chen; Selvarasu Maheshwaran; Tse Wei Chen; Amal M. Al-Mohaimeed; Wedad A. Al-Onazi; Mohamed Soliman Elshikh

doi:10.1007/s00604-021-04729-w

An eco-friendly low-temperature synthetic approach towards micro-pebble-structured GO@SrTiO₃ nanocomposites for the detection of 2,4,6-trichlorophenol in environmental samples

Muthumariappan Akilarasan
, Elayappan Tamilalagan
, Shen Ming Chen^*
, Selvarasu Maheshwaran
, Tse Wei Chen
, Amal M. Al-Mohaimeed
, Wedad A. Al-Onazi
, Mohamed Soliman Elshikh

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

The low-temperature synthesis of the graphene oxide–wrapped perovskite-type strontium titanate nanocomposites (GO@SrTiO₃-NC) is reported for the electrochemical sensing of organochlorine pesticide 2,4,6-trichlorophenol (TCP) detection. The as-prepared GO@SrTiO₃ nanocomposites provide a large surface area, excellent conductivity, and active sites, which are more favorable to the catalysis of TCP. The synergistic effect between the GO and the perovskite SrTiO₃ results in the extended working range of 0.01 to 1.47 and 1.47 to 434.4 μM with a very low detection limit of 3.21 nM towards TCP detection. Moreover, the prepared sensor possessed good selectivity and long-term stability. Finally, the practical applicability of the sensor was tested in environmental samples of river water and soil, exhibiting adequate recovery values. Graphical abstract: [Figure not available: see fulltext.]

Original language	English
Article number	72
Journal	Microchimica Acta
Volume	188
Issue number	3
DOIs	https://doi.org/10.1007/s00604-021-04729-w
State	Published - Mar 2021
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH, AT part of Springer Nature.

Keywords

Electrochemical sensor
Environmental samples
GO@SrTiO nanocomposites
Organochlorine pesticides
TCP detection

ASJC Scopus subject areas

Analytical Chemistry

Access to Document

10.1007/s00604-021-04729-w

Cite this

Akilarasan, M., Tamilalagan, E., Chen, S. M., Maheshwaran, S., Chen, T. W., Al-Mohaimeed, A. M., Al-Onazi, W. A., & Elshikh, M. S. (2021). An eco-friendly low-temperature synthetic approach towards micro-pebble-structured GO@SrTiO₃ nanocomposites for the detection of 2,4,6-trichlorophenol in environmental samples. Microchimica Acta, 188(3), Article 72. https://doi.org/10.1007/s00604-021-04729-w

@article{7aacc56b8a214abc92c53d773846a148,

title = "An eco-friendly low-temperature synthetic approach towards micro-pebble-structured GO@SrTiO3 nanocomposites for the detection of 2,4,6-trichlorophenol in environmental samples",

abstract = "The low-temperature synthesis of the graphene oxide–wrapped perovskite-type strontium titanate nanocomposites (GO@SrTiO3-NC) is reported for the electrochemical sensing of organochlorine pesticide 2,4,6-trichlorophenol (TCP) detection. The as-prepared GO@SrTiO3 nanocomposites provide a large surface area, excellent conductivity, and active sites, which are more favorable to the catalysis of TCP. The synergistic effect between the GO and the perovskite SrTiO3 results in the extended working range of 0.01 to 1.47 and 1.47 to 434.4 μM with a very low detection limit of 3.21 nM towards TCP detection. Moreover, the prepared sensor possessed good selectivity and long-term stability. Finally, the practical applicability of the sensor was tested in environmental samples of river water and soil, exhibiting adequate recovery values. Graphical abstract: [Figure not available: see fulltext.]",

keywords = "Electrochemical sensor, Environmental samples, GO@SrTiO nanocomposites, Organochlorine pesticides, TCP detection",

author = "Muthumariappan Akilarasan and Elayappan Tamilalagan and Chen, \{Shen Ming\} and Selvarasu Maheshwaran and Chen, \{Tse Wei\} and Al-Mohaimeed, \{Amal M.\} and Al-Onazi, \{Wedad A.\} and Elshikh, \{Mohamed Soliman\}",

note = "Publisher Copyright: {\textcopyright} 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH, AT part of Springer Nature.",

year = "2021",

month = mar,

doi = "10.1007/s00604-021-04729-w",

language = "English",

volume = "188",

journal = "Microchimica Acta",

issn = "0026-3672",

publisher = "Springer-Verlag Wien",

number = "3",

}

Akilarasan, M, Tamilalagan, E, Chen, SM, Maheshwaran, S, Chen, TW, Al-Mohaimeed, AM, Al-Onazi, WA & Elshikh, MS 2021, 'An eco-friendly low-temperature synthetic approach towards micro-pebble-structured GO@SrTiO₃ nanocomposites for the detection of 2,4,6-trichlorophenol in environmental samples', Microchimica Acta, vol. 188, no. 3, 72. https://doi.org/10.1007/s00604-021-04729-w

An eco-friendly low-temperature synthetic approach towards micro-pebble-structured GO@SrTiO₃ nanocomposites for the detection of 2,4,6-trichlorophenol in environmental samples. / Akilarasan, Muthumariappan; Tamilalagan, Elayappan; Chen, Shen Ming et al.
In: Microchimica Acta, Vol. 188, No. 3, 72, 03.2021.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - An eco-friendly low-temperature synthetic approach towards micro-pebble-structured GO@SrTiO3 nanocomposites for the detection of 2,4,6-trichlorophenol in environmental samples

AU - Akilarasan, Muthumariappan

AU - Tamilalagan, Elayappan

AU - Chen, Shen Ming

AU - Maheshwaran, Selvarasu

AU - Chen, Tse Wei

AU - Al-Mohaimeed, Amal M.

AU - Al-Onazi, Wedad A.

AU - Elshikh, Mohamed Soliman

PY - 2021/3

Y1 - 2021/3

N2 - The low-temperature synthesis of the graphene oxide–wrapped perovskite-type strontium titanate nanocomposites (GO@SrTiO3-NC) is reported for the electrochemical sensing of organochlorine pesticide 2,4,6-trichlorophenol (TCP) detection. The as-prepared GO@SrTiO3 nanocomposites provide a large surface area, excellent conductivity, and active sites, which are more favorable to the catalysis of TCP. The synergistic effect between the GO and the perovskite SrTiO3 results in the extended working range of 0.01 to 1.47 and 1.47 to 434.4 μM with a very low detection limit of 3.21 nM towards TCP detection. Moreover, the prepared sensor possessed good selectivity and long-term stability. Finally, the practical applicability of the sensor was tested in environmental samples of river water and soil, exhibiting adequate recovery values. Graphical abstract: [Figure not available: see fulltext.]

AB - The low-temperature synthesis of the graphene oxide–wrapped perovskite-type strontium titanate nanocomposites (GO@SrTiO3-NC) is reported for the electrochemical sensing of organochlorine pesticide 2,4,6-trichlorophenol (TCP) detection. The as-prepared GO@SrTiO3 nanocomposites provide a large surface area, excellent conductivity, and active sites, which are more favorable to the catalysis of TCP. The synergistic effect between the GO and the perovskite SrTiO3 results in the extended working range of 0.01 to 1.47 and 1.47 to 434.4 μM with a very low detection limit of 3.21 nM towards TCP detection. Moreover, the prepared sensor possessed good selectivity and long-term stability. Finally, the practical applicability of the sensor was tested in environmental samples of river water and soil, exhibiting adequate recovery values. Graphical abstract: [Figure not available: see fulltext.]

KW - Electrochemical sensor

KW - Environmental samples

KW - GO@SrTiO nanocomposites

KW - Organochlorine pesticides

KW - TCP detection

UR - https://www.scopus.com/pages/publications/85100613705

U2 - 10.1007/s00604-021-04729-w

DO - 10.1007/s00604-021-04729-w

M3 - Article

C2 - 33550432

AN - SCOPUS:85100613705

SN - 0026-3672

VL - 188

JO - Microchimica Acta

JF - Microchimica Acta

IS - 3

M1 - 72

ER -