Ammonia vapor sensing properties of polyaniline-titanium(IV)phosphate cation exchange nanocomposite

  • Asif Ali Khan*
  • , Umair Baig
  • , Mohd Khalid
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

46 Scopus citations

Abstract

In this study, the electrically conducting polyaniline-titanium(IV)phosphate (PANI-TiP) cation exchange nanocomposite was synthesized by sol-gel method. The cation exchange nanocomposite based sensor for detection of ammonia vapors was developed at room temperature. It was revealed that the sensor showed good reversible response towards ammonia vapors ranging from 3 to 6%. It was found that the sensor with p-toluene sulphonic acid ( p-TSA) doped exhibited higher sensing response than hydrochloric acid doped. This sensor has detection limit ≤1% ammonia. The response of resistivity changes of the cation exchange nanocomposite on exposure to different concentrations of ammonia vapors shows its utility as a sensing material. These studies suggest that the cation exchange nanocomposite could be a good material for ammonia sensor at room temperature.

Original languageEnglish
Pages (from-to)2037-2042
Number of pages6
JournalJournal of Hazardous Materials
Volume186
Issue number2-3
DOIs
StatePublished - 28 Feb 2011
Externally publishedYes

Bibliographical note

Funding Information:
Authors are thankful to the Ministry of Environment and Forests of India (project grant no. 19-36/2007-RE ) and Department of Applied Chemistry for providing financial support and research facilities.

Keywords

  • Ammonia sensor
  • Cation exchanger
  • Composite
  • Electrical conductivity
  • Polymer

ASJC Scopus subject areas

  • Environmental Engineering
  • Environmental Chemistry
  • Waste Management and Disposal
  • Pollution
  • Health, Toxicology and Mutagenesis

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