Alkyldiamine bis(selenocyanato)cadmium(II) complexes: Synthesis, 113Cd, 77Se, 15N and 13C NMR spectroscopy and X-ray structure of a 2D metal-organic framework

Mohammed Fettouhi; Bassem A. Al-Maythalony; M. Nasiruzzaman Shaikh; Mohammed I.M. Wazeer; Anvarhusein A. Isab

doi:10.1016/j.poly.2011.02.008

Alkyldiamine bis(selenocyanato)cadmium(II) complexes: Synthesis, ¹¹³Cd, ⁷⁷Se, ¹⁵N and ¹³C NMR spectroscopy and X-ray structure of a 2D metal-organic framework

Mohammed Fettouhi
, Bassem A. Al-Maythalony
, M. Nasiruzzaman Shaikh
, Mohammed I.M. Wazeer
, Anvarhusein A. Isab

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Complexes of cadmium(II)-selenocyanate with several alkyldiamine ligands have been synthesized and characterized by IR, ¹¹³Cd, ⁷⁷Se, ¹⁵N and ¹³C NMR spectroscopy. The X-ray structure of the complex [Cd(SeCN)₂-en] reveals two non-equivalent metal ion centers, both with a distorted octahedral geometry. The combined bridging modes of selenocyanate and ethylenediamine with the blocking mode of a chelating ethylenediamine generate a 2D metal-organic framework.

Original language	English
Pages (from-to)	1262-1266
Number of pages	5
Journal	Polyhedron
Volume	30
Issue number	7
DOIs	https://doi.org/10.1016/j.poly.2011.02.008
State	Published - 27 Apr 2011

Keywords

Cadmium(II) complexes
Ethylenediamine
Selenocyanate
Solid state NMR
X-ray structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.poly.2011.02.008

Cite this

@article{455d29aafb884c66b50e6502e40b75e8,

title = "Alkyldiamine bis(selenocyanato)cadmium(II) complexes: Synthesis, 113Cd, 77Se, 15N and 13C NMR spectroscopy and X-ray structure of a 2D metal-organic framework",

abstract = "Complexes of cadmium(II)-selenocyanate with several alkyldiamine ligands have been synthesized and characterized by IR, 113Cd, 77Se, 15N and 13C NMR spectroscopy. The X-ray structure of the complex [Cd(SeCN)2-en] reveals two non-equivalent metal ion centers, both with a distorted octahedral geometry. The combined bridging modes of selenocyanate and ethylenediamine with the blocking mode of a chelating ethylenediamine generate a 2D metal-organic framework.",

keywords = "Cadmium(II) complexes, Ethylenediamine, Selenocyanate, Solid state NMR, X-ray structure",

author = "Mohammed Fettouhi and Al-Maythalony, \{Bassem A.\} and \{Nasiruzzaman Shaikh\}, M. and Wazeer, \{Mohammed I.M.\} and Isab, \{Anvarhusein A.\}",

year = "2011",

month = apr,

day = "27",

doi = "10.1016/j.poly.2011.02.008",

language = "English",

volume = "30",

pages = "1262--1266",

journal = "Polyhedron",

issn = "0277-5387",

number = "7",

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TY - JOUR

T1 - Alkyldiamine bis(selenocyanato)cadmium(II) complexes

T2 - Synthesis, 113Cd, 77Se, 15N and 13C NMR spectroscopy and X-ray structure of a 2D metal-organic framework

AU - Fettouhi, Mohammed

AU - Al-Maythalony, Bassem A.

AU - Nasiruzzaman Shaikh, M.

AU - Wazeer, Mohammed I.M.

AU - Isab, Anvarhusein A.

PY - 2011/4/27

Y1 - 2011/4/27

N2 - Complexes of cadmium(II)-selenocyanate with several alkyldiamine ligands have been synthesized and characterized by IR, 113Cd, 77Se, 15N and 13C NMR spectroscopy. The X-ray structure of the complex [Cd(SeCN)2-en] reveals two non-equivalent metal ion centers, both with a distorted octahedral geometry. The combined bridging modes of selenocyanate and ethylenediamine with the blocking mode of a chelating ethylenediamine generate a 2D metal-organic framework.

AB - Complexes of cadmium(II)-selenocyanate with several alkyldiamine ligands have been synthesized and characterized by IR, 113Cd, 77Se, 15N and 13C NMR spectroscopy. The X-ray structure of the complex [Cd(SeCN)2-en] reveals two non-equivalent metal ion centers, both with a distorted octahedral geometry. The combined bridging modes of selenocyanate and ethylenediamine with the blocking mode of a chelating ethylenediamine generate a 2D metal-organic framework.

KW - Cadmium(II) complexes

KW - Ethylenediamine

KW - Selenocyanate

KW - Solid state NMR

KW - X-ray structure

UR - https://www.scopus.com/pages/publications/79953895434

U2 - 10.1016/j.poly.2011.02.008

DO - 10.1016/j.poly.2011.02.008

M3 - Article

AN - SCOPUS:79953895434

SN - 0277-5387

VL - 30

SP - 1262

EP - 1266

JO - Polyhedron

JF - Polyhedron

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