Aging of low-density polyethylene in natural weather, underground soil aging and sea water: Effect of a starch-based prodegradant additive

M. Elanmugilan, P. A. Sreekumar*, N. K. Singha, Mamdouh A. Al-Harthi, S. K. De

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

This article reports the results of studies on the degradation of the blend of low-density polyethylene (LDPE) with a starch based prodegradant additive, named commercially as Polystarch plus H and abbreviated as PSH, under natural weather, underground soil aging, and sea water aging in Dhahran, Saudi Arabia. The work includes measurements of tensile properties, thermal behavior, and scanning electron microscopic (SEM) studies on the unaged and aged LDPE and the LDPE/PSH blend having 25% (w/w) of PSH. Results of the preliminary experiments showed that changes in properties are not prominent at lower loadings of PSH. In the case of the blend, incorporation of the additive PSH caused a reduction in elongation at break, which is accentuated under aging. The effectiveness of the prodegradant additive in the degradation behavior follows the order, natural aging > underground soil aging > sea water aging. It is believed that the prodegradant additive is effective in chain scission in sunlight under natural weathering conditions, in contrast to underground soil aging and sea water.

Original languageEnglish
Pages (from-to)2389-2397
Number of pages9
JournalPolymer Engineering and Science
Volume53
Issue number11
DOIs
StatePublished - Nov 2013

ASJC Scopus subject areas

  • General Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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