Advanced Strategies in Metal-Organic Frameworks for CO₂ Capture and Separation

The continuous carbon dioxide (CO₂) gas emissions associated with fossil fuel production, valorization, and utilization are serious challenges to the global environment. Therefore, several developments of CO₂ capture, separation, transportation, storage, and valorization have been explored. Consequently, we documented a comprehensive review of the most advanced strategies adopted in metal-organic frameworks (MOFs) for CO₂ capture and separation. The enhancements in CO₂ capture and separation are generally achieved due to the chemistry of MOFs by controlling pore window, pore size, open-metal sites, acidity, chemical doping, post or pre-synthetic modifications. The chemistry of defects engineering, breathing in MOFs, functionalization in MOFs, hydrophobicity, and topology are the salient advanced strategies, recently reported in MOFs for CO₂ capture and separation. Therefore, this review summarizes MOF materials′ advancement explaining different strategies and their role in the CO₂ mitigations. The study also provided useful insights into key areas for further investigations.