ADSORPTION OF HYDROGEN SULFIDE ON SHALE RETORTED IN AN INERT ATMOSPHERE.

E. Pedram*, M. A. Hasanain, A. L. Hines, J. J. Duvall

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

The adsorption of hydrogen sulfide on retorted oil shale was studied at 10, 25, an 60 degree C using a packed bed method. Equilibrium isotherms were calculated from the adsorption data and were modeled by the Langmuir, Freundlich, and Polanyi equations. The isosteric heat of adsorption was calculated at three adsorbent loadings and was found to increase with increased loading. A calculated heat of adsorption less than the heat of condensation indicated that the adsorption was primarily due to van der Waals' forces. Adsorption capacities were also found as a function of oil shale retorting temperature with the maximum uptake occurring on shale that was retorted at 750 degree C.

Original languageEnglish
Pages (from-to)331-352
Number of pages22
JournalIn Situ
Volume3
Issue number4
StatePublished - 1979
Externally publishedYes

ASJC Scopus subject areas

  • General Chemical Engineering
  • Fuel Technology
  • Geotechnical Engineering and Engineering Geology
  • Energy Engineering and Power Technology

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